(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE

Reaction

Product Name: (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
CAS No.: 164858-78-0
Chemical Name: (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
Synonyms: (R)-iPr-Phox;(R)-(+)-2-[2-(Diphenylphosphino;(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazol;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;(R)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYL-OXAZOLE;(R)-(+)-2-[2-(Diphenylphosphino)Phenyl]-4-(1-Methyl)-4,5-Dihydrooxazole;(4R)-(+)-4,5-DIHYDRO-2-(2'-(DIPHENYLPHOSPHINO)PHENYL)-4-ISOPROPYLOXAZOLE;(4R)-(+)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE
CBNumber: CB1442988
Molecular Formula: C24H24NOP
Formula Weight: 373.43
MOL File: 164858-78-0.mol

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(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Property

Melting point:: 85-90 °C
alpha: +44° (c 1.4, CHCl3)
Boiling point:: 492.7±28.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 4.31±0.70(Predicted)
form: Powder
color: white
optical activity: [α]20/D +48±3°, c = 1.4% in chloroform
Sensitive: air sensitive
BRN: 8156604
InChIKey: OUQSAXROROGQEE-QFIPXVFZSA-N
CAS DataBase Reference: 164858-78-0

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 37/39-26-24/25
WGK Germany: 3
F: 10-23
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 72575
Product name: (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline
Purity: ≥97.0% (CHN)
Packaging: 100mg
Price: $87
Updated: 2024/03/01

Sigma-Aldrich

Product number: 72575
Product name: (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline
Purity: ≥97.0% (CHN)
Packaging: 500mg
Price: $413
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1821
Product name: (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (R)-iPr-PHOX
Packaging: 50mg
Price: $101
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1821
Product name: (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (R)-iPr-PHOX
Packaging: 250mg
Price: $356
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1821
Product name: (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (R)-iPr-PHOX
Packaging: 1g
Price: $1068
Updated: 2024/03/01

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(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Chemical Properties,Usage,Production

Reaction

Chiral ligand used in the asymmetric reduction of highly substituted olefins.
Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
Decarboxylative allylic alkylation.

Chemical Properties

White crystalline powder

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Suppliers

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View Lastest Price from (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE 164858-78-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-12-04

Hebei Mojin Biotechnology Co., Ltd

Product: 3-CHLORO-5-FLUOROPHENYLACETIC ACID 164858-78-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-14

Career Henan Chemical Co

Product: (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE 164858-78-0
Price: US $3.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-10

164858-78-0, (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLERelated Search:

Phenethyl alcohol R(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-PHENYL-2-OXAZOLINE (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97% R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE (R)-DM-BINAP (R)-(+)-TolBINAP (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE 500MG

(R)-(+)-2-[2-(Diphenylphosphino)Phenyl]-4-(1-Methyl)-4,5-Dihydrooxazole

(4R)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)oxazole,99%e.e.

(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline >=97.0% (CHN)

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYL-OXAZOLE

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE

(4R)-(+)-4,5-DIHYDRO-2-(2'-(DIPHENYLPHOSPHINO)PHENYL)-4-ISOPROPYLOXAZOLE

(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole,98%

(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazol

(4R)-(+)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole,98%

(R)-(+)-2-[2-(Diphenylphosphino

(R)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole

(4R)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-Oxazole

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE,98%(R)-IPR-PHOX

diphenyl-[2-[(4R)-4-propan-2-yl-4,5-dihydro-1,3-oxazol-2-yl]phenyl]phosphane

Oxazole, 2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)-, (4R)-

iphenyl-[2-[(4R)-4-propan-2-yl-4,5-dihydro-1,3-oxazol-2-yl]phenyl]phosphane

(R)-iPr-Phox

(4R)-(+)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole

164858-78-0

PHOX

Privileged Ligands

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

organophosphine ligand

PHOX Series

Chiral Phosphine