ChemicalBook > CAS DataBase List > (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
Reaction- Product Name
- (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
- CAS No.
- 164858-78-0
- Chemical Name
- (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
- Synonyms
- (R)-iPr-Phox;(R)-(+)-2-[2-(Diphenylphosphino;(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazol;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;(R)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYL-OXAZOLE;(R)-(+)-2-[2-(Diphenylphosphino)Phenyl]-4-(1-Methyl)-4,5-Dihydrooxazole;(4R)-(+)-4,5-DIHYDRO-2-(2'-(DIPHENYLPHOSPHINO)PHENYL)-4-ISOPROPYLOXAZOLE;(4R)-(+)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE
- CBNumber
- CB1442988
- Molecular Formula
- C24H24NOP
- Formula Weight
- 373.43
- MOL File
- 164858-78-0.mol
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(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Property
- Melting point:
- 85-90 °C
- alpha
- +44° (c 1.4, CHCl3)
- Boiling point:
- 492.7±28.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 4.31±0.70(Predicted)
- form
- Powder
- color
- white
- optical activity
- [α]20/D +48±3°, c = 1.4% in chloroform
- Sensitive
- air sensitive
- BRN
- 8156604
- InChIKey
- OUQSAXROROGQEE-QFIPXVFZSA-N
- CAS DataBase Reference
- 164858-78-0
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 37/39-26-24/25
- WGK Germany
- 3
- F
- 10-23
- HS Code
- 29349990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 72575
- Product name
- (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline
- Purity
- ≥97.0% (CHN)
- Packaging
- 100mg
- Price
- $87
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 72575
- Product name
- (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline
- Purity
- ≥97.0% (CHN)
- Packaging
- 500mg
- Price
- $413
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1821
- Product name
- (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (R)-iPr-PHOX
- Packaging
- 50mg
- Price
- $101
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1821
- Product name
- (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (R)-iPr-PHOX
- Packaging
- 250mg
- Price
- $356
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1821
- Product name
- (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (R)-iPr-PHOX
- Packaging
- 1g
- Price
- $1068
- Updated
- 2024/03/01
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(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Chemical Properties,Usage,Production
Reaction
Chiral ligand used in the asymmetric reduction of highly substituted olefins.
Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
Decarboxylative allylic alkylation.
Chemical Properties
White crystalline powder
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Preparation Products And Raw materials
Raw materials
Preparation Products
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(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Suppliers
- Tel
- --
- Fax
- --
- info@dalchem.nnov.ru
- Country
- Russia
- ProdList
- 705
- Advantage
- 64
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View Lastest Price from (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE manufacturers
Hebei Weibang Biotechnology Co., Ltd
- Product
- (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE 164858-78-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2023-01-12
Hebei Mojin Biotechnology Co., Ltd
- Product
- 3-CHLORO-5-FLUOROPHENYLACETIC ACID 164858-78-0
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-08-14
Career Henan Chemical Co
- Product
- (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE 164858-78-0
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-10
164858-78-0, (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLERelated Search:
Phenethyl alcohol
R(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-PHENYL-2-OXAZOLINE
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
(S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97%
R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE
(R)-DM-BINAP
(R)-(+)-TolBINAP
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE