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2-Methylene-1,3-dioxepane

Product Name
2-Methylene-1,3-dioxepane
CAS No.
69814-56-8
Chemical Name
2-Methylene-1,3-dioxepane
Synonyms
3-METHYLENE-1,3-DIOXEPANE;2-METHYLENE-1,3-DIOXEPANE;1,3-Dioxepane, 2-Methylene-;2-methylidene-1,3-dioxepane;2-Methylene-1,3-dioxepane?New;2-Methylene-1,3-dioxepane (MDO);2-Methylene-4,5,6,7-tetrahydro-1,3-dioxepin
CBNumber
CB1447862
Molecular Formula
C6H10O2
Formula Weight
114.14
MOL File
69814-56-8.mol
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2-Methylene-1,3-dioxepane Property

Boiling point:
172.8±20.0 °C(Predicted)
Density 
0.97±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
liquid
color 
Clear, almost colourless
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Safety

RIDADR 
1993
HazardClass 
3
PackingGroup 
HS Code 
2932990090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
M336445
Product name
2-Methylene-1,3-dioxepane
Packaging
100mg
Price
$70
Updated
2021/12/16
AK Scientific
Product number
1718BA
Product name
2-Methylene-1,3-dioxepane
Packaging
100mg
Price
$142
Updated
2021/12/16
Apolloscientific
Product number
OR200162
Product name
2-Methylene-1,3-dioxepane
Packaging
1g
Price
$424
Updated
2021/12/16
SynQuest Laboratories
Product number
2H10-1-71
Product name
2-Methylene-1,3-dioxepane
Packaging
1g
Price
$468
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0311538
Product name
2-METHYLENE-1,3-DIOXEPANE
Purity
95.00%
Packaging
5MG
Price
$502.1
Updated
2021/12/16
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2-Methylene-1,3-dioxepane Chemical Properties,Usage,Production

Uses

2-Methylene-1,3-dioxepane is used in the synthesis of functional 2-methylene-1,3-dioxepane terpolymer which functions as a building block for the construction of biodegradable pH sensitive polymeric prodrug for intracellular drug delivery.

Definition

2-Methylene-1,3-dioxepane (MDO), which is also called cyclic ketene acetals (CKAs), can undergo radical addition on their carbon–carbon double bond, which then subsequently leads to propagation, either by ring opening or ring retaining or by a combination of both, which depends especially on their structure. This monomer provides a novel and alternative synthetic route for the synthesis of polycaprolactone, and it imparts degradability to conventional vinyl monomers by introducing ester linkages into the backbone. Thereby, the structure of the polyester material can be greatly expanded, and the polyester material can be applied to a wider range of fields. Its same repeat unit with poly(ε-caprolactone) (PCL). On the same time, the PCL synthesis through rROP offered new characteristic properties, such as totally amorphous instead of semicrystalline, versatile functionalization abilities by copolymerization with different vinyl monomers[1-2].    

References

[1] Xu P, et al. Hyperbranched Polycaprolactone through RAFT Polymerization of 2-Methylene-1,3-dioxepane. Polymers, 2019; 11: 318.
[2] Ding D, et al. Degradable Copolymer of 2-Methylene-1,3-dioxepane and Vinyl Acetate by Photo-induced Cobalt-Mediated Radical Polymerization. Polymer Chemistry, 2016; 7: 5258-5264.

2-Methylene-1,3-dioxepane Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Methylene-1,3-dioxepane Suppliers

Shanghai Gugang New Materials Technology Co. Ltd.
Tel
021-51317962
Fax
021-51317962
Email
296935822@qq.com
Country
China
ProdList
974
Advantage
58
Nanjing Habo Medical Technology Co., Ltd.
Tel
025-85760892 13376090521
Fax
025-85766769
Email
sales@habotech.com
Country
China
ProdList
979
Advantage
60
Chengdu Forest Science and Technology Development Co., Ltd.
Tel
18030648795 18030648795
Fax
028-61777050
Email
sales@cdforestchem.com
Country
China
ProdList
1976
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66099280 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19915
Advantage
55
EnliPharma Technology Co., Ltd
Tel
0551-66399836 18955197623
Email
sales@enlipharma.com
Country
China
ProdList
1874
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41462
Advantage
60
Finetech Industry Limited
Tel
027-87465837 19945049750
Fax
027-8777-2287
Email
sales@finetechnology-ind.com
Country
China
ProdList
9648
Advantage
58
Shanghai HuanChuan Industry Co.,Ltd.
Tel
021-61478794
Fax
021-61478794
Email
sales@hcshhai.com
Country
China
ProdList
9793
Advantage
50
Nanjing Chalf-Pharm Technology Co., Ltd.
Tel
025-57018978 18251899859
Fax
025-57018008
Email
sales@chalf-pharm.com
Country
China
ProdList
5806
Advantage
50
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
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View Lastest Price from 2-Methylene-1,3-dioxepane manufacturers

Career Henan Chemical Co
Product
2-METHYLENE-1,3-DIOXEPANE 69814-56-8
Price
US $1.00/g
Min. Order
1g
Purity
99.0%
Supply Ability
100kg
Release date
2020-01-09

69814-56-8, 2-Methylene-1,3-dioxepaneRelated Search:


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  • 1,3-Dioxepane, 2-Methylene-
  • 2-Methylene-1,3-dioxepane (MDO)
  • 2-methylidene-1,3-dioxepane
  • 2-Methylene-1,3-dioxepane?New
  • 69814-56-8