ChemicalBook > CAS DataBase List > 2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE

2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE

Product Name
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
CAS No.
24720-64-7
Chemical Name
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
Synonyms
2-(TRIPHENYLPHOSPHOR;2-(triphenylphosphoranylidene);2-(Triphenylphosphoranylidene)propanal;1-Formylethylidenetriphenylphosphorane;Propanal,2-(triphenylphosphoranylidene)-;2-(triphenyl-l5-phosphanylidene)propanal;2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE;2-(Triphenylphosphoranylidene)propionaldehyde 98%;2-(triphenylphosphoranylidene)propionaldehyde, 98 %
CBNumber
CB1450644
Molecular Formula
C21H19OP
Formula Weight
318.35
MOL File
24720-64-7.mol
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2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Property

Melting point:
219-221 °C (lit.)
Boiling point:
478.5±28.0 °C(Predicted)
Density 
1.14±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
form 
Low Melting Solid
color 
White to pink to brown
CAS DataBase Reference
24720-64-7
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Safety

Risk Statements 
22-36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
374377
Product name
2-(Triphenylphosphoranylidene)propionaldehyde
Purity
98%
Packaging
10g
Price
$254
Updated
2024/03/01
Sigma-Aldrich
Product number
374377
Product name
2-(Triphenylphosphoranylidene)propionaldehyde
Purity
98%
Packaging
1g
Price
$57.2
Updated
2023/06/20
TRC
Product number
T808956
Product name
2-(Triphenylphosphoranylidene)propionaldehyde
Packaging
2.5g
Price
$275
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0005873
Product name
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
Purity
95.00%
Packaging
1G
Price
$436
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0005873
Product name
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
Purity
95.00%
Packaging
10G
Price
$580
Updated
2021/12/16
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2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Chemical Properties,Usage,Production

Chemical Properties

White to light beige crystalline powder

Uses

Reactant for:• ;Preparation of acitretin analogs with antitumor activity1• ;Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration2• ;Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination3• ;Wittig reactions4• ;Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents5• ;Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors

Uses

2-(Triphenylphosphoranylidene)propionaldehyde is a reagent used in the asymmetric synthesis of hispidanin A via oxidative alkoxylation and stereoselective Diels-Alder reaction. Also acts as a reagent in the stereoselective synthesis of 10-epi-tirandamycin E.

Uses

Reactant for:

  • Preparation of acitretin analogs with antitumor activity
  • Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration
  • Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination
  • Wittig reactions
  • Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents
  • Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH

2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Suppliers

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View Lastest Price from 2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
2-(Triphenylphosphoranylidene)propionaldehyde 24720-64-7
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50 tons
Release date
2020-01-17
Career Henan Chemical Co
Product
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE 24720-64-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2020-01-09

24720-64-7, 2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDERelated Search:

Ethyl 2-(triphenylphosphoranylidene)propionate 2-(TRIPHENYLPHOSPHORANYLIDENE)SUCCINIC ANHYDRIDE 2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE 2-(TRIPHENYLPHOSPHORANYLIDENE)BUTYRALDEHYDE 1-METHOXYCARBONYLETHYLIDENETRIPHENYLPHOSPHORANE ETHYL 4,4,4-TRIFLUORO-2-(TRIPHENYLPHOSPHORANYLIDENE)ACETOACETATE METHYL 2-[5-(4-CHLOROPHENYL)-2-HYDROXY-3-OXO-2,3-DIHYDROFURAN-2-YL]-2-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)ACETATE 2-[2-(4-CHLOROPHENYL)-2-OXO-1-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)ETHYL]-2-HYDROXY-5-PHENYL-2,3-DIHYDROFURAN-3-ONE ETHYL 2,4-DIOXO-3-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)PENTANOATE SPECS AE-848/33625045 METHYL 2-(2-HYDROXY-3-OXO-5-PHENYL-2,3-DIHYDROFURAN-2-YL)-2-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)ACETATE METHYL 3-OXO-3-[3-(TRIFLUOROMETHYL)PHENYL]-2-(TRIPHENYLPHOSPHORANYLIDENE)PROPANOATE AURORA KA-1174 AURORA KA-1073 SALOR-INT L150010-1EA SALOR-INT L151815-1EA 4-[(4-BROMOPHENYL)(DIPHENYL)PHOSPHORANYLIDENE]-5-METHYL-2-PHENYL-2,4-DIHYDRO-3H-PYRAZOL-3-ONE AURORA KA-1180

  • 2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
  • 2-(triphenylphosphoranylidene)propionaldehyde, 98 %
  • 2-(triphenylphosphoranylidene)
  • 2-(TRIPHENYLPHOSPHOR
  • 1-Formylethylidenetriphenylphosphorane
  • 2-(Triphenylphosphoranylidene)propanal
  • 2-(triphenyl-l5-phosphanylidene)propanal
  • 2-(Triphenylphosphoranylidene)propionaldehyde 98%
  • Propanal,2-(triphenylphosphoranylidene)-
  • 24720-64-7
  • C6H53PCCH3CHO
  • C-C Bond Formation
  • Olefination
  • Synthetic Reagents
  • Wittig Reagents
  • Aldehydes
  • Building Blocks
  • C13-C60
  • Carbonyl Compounds
  • C-C Bond Formation
  • Chemical Synthesis
  • Organic Building Blocks
  • Synthetic Reagents
  • Wittig Reagents
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents