(R)-VAPOL

Reactions

Product Name: (R)-VAPOL
CAS No.: 147702-15-6
Chemical Name: (R)-VAPOL
Synonyms: (R)-VAPOL;(S)-VAPOL;(S)-VAPOL 97%;(S)-VAPOL,99%e.e.;(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL);(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL);(3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol;(3S)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol;(3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol;(3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
CBNumber: CB1450750
Molecular Formula: C40H26O2
Formula Weight: 538.63
MOL File: 147702-15-6.mol

More

Less

(R)-VAPOL Property

Melting point:: 185-191 °C
alpha: +125.0° (c 1.0, THF)
Boiling point:: 712.2±60.0 °C(Predicted)
Density: 1.286±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: Powder
pka: 8.37±0.30(Predicted)
color: white to pale yellow
optical activity: [α]20/D 128°, c = 1 in chloroform
InChIKey: FXFOHEGGSYVOKR-UHFFFAOYSA-N
CAS DataBase Reference: 147702-15-6

More

Less

Safety

Hazard Codes: Xn
Risk Statements: 37/38-40-41
Safety Statements: 26-36/37/39-36/37-24/25-23
WGK Germany: 3

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 675334
Product name: (S)-VAPOL
Purity: 97%
Packaging: 100mg
Price: $84
Updated: 2024/03/01

Sigma-Aldrich

Product number: 675334
Product name: (S)-VAPOL
Purity: 97%
Packaging: 500mg
Price: $400.2
Updated: 2024/03/01

Strem Chemicals

Product number: 08-1706
Product name: (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (S)-VAPOL
Packaging: 100mg
Price: $255
Updated: 2024/03/01

Strem Chemicals

Product number: 08-1706
Product name: (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (S)-VAPOL
Packaging: 500mg
Price: $1021
Updated: 2024/03/01

Ambeed

Product number: A929782
Product name: (3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol
Purity: 98%99%ee
Packaging: 1g
Price: $970
Updated: 2021/12/16

More

Less

(R)-VAPOL Chemical Properties,Usage,Production

Reactions

Chiral ligand in asymmetric autoinduction of Diels-Alder reactions.
Chiral ligand used in catalytic asymmetric aziridination.
Chiral ligand used in catalytic asymmetric imino aldol reaction.
Chiral ligand used in catalytic asymmetric Petasis reaction.

Uses

VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(R)-VAPOL Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

(R)-VAPOL Suppliers

China 27 Germany 1 Switzerland 1 United States 3 Global 32

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

Daicel Chiral Technologies (China)CO.,LTD

Tel: 021-50460086-9 15921403865
Fax: +86-21-50462321
Email: han_yajun@dctc.daicel.com
Country: China
ProdList: 7195
Advantage: 65

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-400-6206333 18521732826
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41462
Advantage: 60

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51456
Advantage: 80

Shanghai Chiral bio-compound co., Ltd.

Tel: 021-5068 3667/17749785980/1029026415; 17749785980
Fax: 021-50683667
Email: 1029026415@qq.com
Country: China
ProdList: 3013
Advantage: 58

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2409
Advantage: 58

Greenherbs Science and Technology Development Co., Ltd.

Tel: 010-61136123
Fax: +86 (10) 8857-9127
Email: pub02@greenherbs.com.cn
Country: China
ProdList: 4049
Advantage: 58

Aikon International Limited

Tel: 025-66113011 13155353615
Fax: (7)02557626880
Email: qzhang@aikonchem.com
Country: China
ProdList: 15394
Advantage: 58

Shanghai Anyinuo Biomedical Technology Co., Ltd.

Tel: 021-34625901
Email: 420970979@qq.com
Country: China
ProdList: 5783
Advantage: 58

Zhengzhou Acme Chemical Co., Ltd.

Tel: 0371-63315541 13323832564
Fax: QQ:3001332135
Email: 3001332135@qq.com
Country: China
ProdList: 10066
Advantage: 58

Henan Weituxi Chemical Technology Co., Ltd.

Tel: 0371-63284658 18135795563
Fax: QQ:2885349392
Email: 2885349392@qq.com
Country: China
ProdList: 10003
Advantage: 58

Shanghai Kaiwei Chemical Technology Co., Ltd.

Tel: 021-58461859 15821823057
Email: service@aiviche.com
Country: China
ProdList: 49312
Advantage: 58

Beijing Jin Ming Biotechnology Co., Ltd.

Tel: 010-60605840 15801484223;
Email: psaitong@jm-bio.com
Country: China
ProdList: 29774
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 39995
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-6005915
Email: sales@picasso-e.com
Country: China
ProdList: 39653
Advantage: 58

Shanghai Maclean Biochemical Technology Co., LTD

Tel: 021-50706066 15221275939
Email: shenlinxing@macklin.cn
Country: China
ProdList: 29902
Advantage: 58

Beijing Solarbio Science & Tecnology Co., Ltd.

Tel: 010-50973130 17801761073
Email: Gsiyu@solarbio.com
Country: China
ProdList: 50464
Advantage: 58

Nantong Hanfang Biotechnology Co. , Ltd.

Tel: 18616537568
Email: hanfangpharma@126.com
Country: China
ProdList: 29971
Advantage: 58

Shanghai Hansi Chemical Industry Co., Ltd.

Tel: 17717618050
Email: zllg@gh-reagent.com
Country: China
ProdList: 10422
Advantage: 58

Guangzhou CATO Research Chemicals Inc.

Tel: +86-020-81960175-617 +8615602392859
Email: Intermediate@cato-chem.com
Country: China
ProdList: 8047
Advantage: 58

Shanghai Likang New Materials Co., Limited

Tel: +86-16631818819 +86-17736933208
Email: 3684455296@qq.com
Country: China
ProdList: 9300
Advantage: 58

LEAPCHEM CO., LTD.

Tel: +86-852-30606658
Email: market18@leapchem.com
Country: China
ProdList: 43340
Advantage: 58

Hebei Weibang Biotechnology Co., Ltd

Tel: +8617732866630
Email: bess@weibangbio.com
Country: China
ProdList: 18150
Advantage: 58

Shanghai Hao Zhun Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: info@zzsrm.com
Country: CHINA
ProdList: 6650
Advantage: 58

147702-15-6, (R)-VAPOLRelated Search:

(R)-VAPOL Dichloromethane (S)-VANOL o-Quaterphenyl (R)-VAPOL 2,2'-binaphthalene o-Terphenyl

(3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT

(3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT

(R)-VAPOL

(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL)

(S)-VAPOL

(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL)

(3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-dioldichloromethaneadduct,min.98%(S)-VAPOL

(3S)-(+)-2,2''-DIPHENYL-[3,3''-BIPHENANTHRENE]-4,4''-DIOL DICHLOROMETHANE ADDUCT (S)-VAPOL

(3S)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol

(S)-VAPOL 97%

(S)-VAPOL,99%e.e.

dichloromethane:3-(4-hydroxy-2-phenylphenanthren-3-yl)-2-phenylphenanthren-4-ol

3,3'-Biphenanthrene]-4,4'-diol, 2,2'-diphenyl-, (3S)-

(3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol

(3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol

(3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol

147702-15-6

C40H26O2

BINOL Series

Chiral Oxygen