ChemicalBook > CAS DataBase List > (R)-VAPOL
(R)-VAPOL
Reactions- Product Name
- (R)-VAPOL
- CAS No.
- 147702-15-6
- Chemical Name
- (R)-VAPOL
- Synonyms
- (R)-VAPOL;(S)-VAPOL;(S)-VAPOL 97%;(S)-VAPOL,99%e.e.;(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL);(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL);(3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol;(3S)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol;(3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol;(3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
- CBNumber
- CB1450750
- Molecular Formula
- C40H26O2
- Formula Weight
- 538.63
- MOL File
- 147702-15-6.mol
More
Less
(R)-VAPOL Property
- Melting point:
- 185-191 °C
- alpha
- +125.0° (c 1.0, THF)
- Boiling point:
- 712.2±60.0 °C(Predicted)
- Density
- 1.286±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- Powder
- pka
- 8.37±0.30(Predicted)
- color
- white to pale yellow
- optical activity
- [α]20/D 128°, c = 1 in chloroform
- InChIKey
- FXFOHEGGSYVOKR-UHFFFAOYSA-N
- CAS DataBase Reference
- 147702-15-6
More
Less
Safety
- Hazard Codes
- Xn
- Risk Statements
- 37/38-40-41
- Safety Statements
- 26-36/37/39-36/37-24/25-23
- WGK Germany
- 3
More
Less
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H351Suspected of causing cancer
- Precautionary statements
-
P201Obtain special instructions before use.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313IF exposed or concerned: Get medical advice/attention.
More
Less
N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 675334
- Product name
- (S)-VAPOL
- Purity
- 97%
- Packaging
- 100mg
- Price
- $84
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 675334
- Product name
- (S)-VAPOL
- Purity
- 97%
- Packaging
- 500mg
- Price
- $400.2
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 08-1706
- Product name
- (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (S)-VAPOL
- Packaging
- 100mg
- Price
- $255
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 08-1706
- Product name
- (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (S)-VAPOL
- Packaging
- 500mg
- Price
- $1021
- Updated
- 2024/03/01
Ambeed
- Product number
- A929782
- Product name
- (3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol
- Purity
- 98%99%ee
- Packaging
- 1g
- Price
- $970
- Updated
- 2021/12/16
More
Less
(R)-VAPOL Chemical Properties,Usage,Production
Reactions
- Chiral ligand in asymmetric autoinduction of Diels-Alder reactions.
- Chiral ligand used in catalytic asymmetric aziridination.
- Chiral ligand used in catalytic asymmetric imino aldol reaction.
- Chiral ligand used in catalytic asymmetric Petasis reaction.
Uses
VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
(R)-VAPOL Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
(R)-VAPOL Suppliers
- Tel
- --
- Fax
- --
- Country
- Switzerland
- ProdList
- 6896
- Advantage
- 91