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ChemicalBook > CAS DataBase List > (R)-VAPOL

(R)-VAPOL

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Product Name
(R)-VAPOL
CAS No.
147702-15-6
Chemical Name
(R)-VAPOL
Synonyms
(R)-VAPOL;(S)-VAPOL;(S)-VAPOL 97%;(S)-VAPOL,99%e.e.;(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL);(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL);(3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol;(3S)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol;(3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol;(3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
CBNumber
CB1450750
Molecular Formula
C40H26O2
Formula Weight
538.63
MOL File
147702-15-6.mol
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(R)-VAPOL Property

Melting point:
185-191 °C
alpha 
+125.0° (c 1.0, THF)
Boiling point:
712.2±60.0 °C(Predicted)
Density 
1.286±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
pka
8.37±0.30(Predicted)
color 
white to pale yellow
optical activity
[α]20/D 128°, c = 1 in chloroform
InChIKey
FXFOHEGGSYVOKR-UHFFFAOYSA-N
CAS DataBase Reference
147702-15-6
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Safety

Hazard Codes 
Xn
Risk Statements 
37/38-40-41
Safety Statements 
26-36/37/39-36/37-24/25-23
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
675334
Product name
(S)-VAPOL
Purity
97%
Packaging
100mg
Price
$84
Updated
2024/03/01
Sigma-Aldrich
Product number
675334
Product name
(S)-VAPOL
Purity
97%
Packaging
500mg
Price
$400.2
Updated
2024/03/01
Strem Chemicals
Product number
08-1706
Product name
(3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (S)-VAPOL
Packaging
100mg
Price
$255
Updated
2024/03/01
Strem Chemicals
Product number
08-1706
Product name
(3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (S)-VAPOL
Packaging
500mg
Price
$1021
Updated
2024/03/01
Ambeed
Product number
A929782
Product name
(3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol
Purity
98%99%ee
Packaging
1g
Price
$970
Updated
2021/12/16
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(R)-VAPOL Chemical Properties,Usage,Production

Reactions

  1. Chiral ligand in asymmetric autoinduction of Diels-Alder reactions.
  2. Chiral ligand used in catalytic asymmetric aziridination.
  3. Chiral ligand used in catalytic asymmetric imino aldol reaction.
  4. Chiral ligand used in catalytic asymmetric Petasis reaction. 

Uses

VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(R)-VAPOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-VAPOL Suppliers

SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
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147702-15-6, (R)-VAPOLRelated Search:


  • (3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
  • (3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
  • (R)-VAPOL
  • (S)-2,2'-DIPHENYL-(4-BIPHENANTHROL)
  • (S)-VAPOL
  • (R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL)
  • (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-dioldichloromethaneadduct,min.98%(S)-VAPOL
  • (3S)-(+)-2,2''-DIPHENYL-[3,3''-BIPHENANTHRENE]-4,4''-DIOL DICHLOROMETHANE ADDUCT (S)-VAPOL
  • (3S)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol
  • (S)-VAPOL 97%
  • (S)-VAPOL,99%e.e.
  • dichloromethane:3-(4-hydroxy-2-phenylphenanthren-3-yl)-2-phenylphenanthren-4-ol
  • 3,3'-Biphenanthrene]-4,4'-diol, 2,2'-diphenyl-, (3S)-
  • (3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
  • (3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol
  • (3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
  • 147702-15-6
  • C40H26O2
  • BINOL Series
  • Chiral Oxygen