1-(2-Aminoethyl)imidazolidin-2-one
- Product Name
- 1-(2-Aminoethyl)imidazolidin-2-one
- CAS No.
- 6281-42-1
- Chemical Name
- 1-(2-Aminoethyl)imidazolidin-2-one
- Synonyms
- BUTTPARK 52\06-90;CHEMBRDG-BB 4005390;1-(2-aminoethyl)-2-imidazolone;1-(2-AMINOETHYL)-2-IMIDAZOLIDONE;1-(2-Aminoethyl)-imidazolidinone;1-(2-aminoethyl)-2-imidazolidinon;1-(2-AMINOETHYL)-2-IMIDAZOLIDINONE;1-(2-AMINOETHYL)IMIDAZOLIDIN-2-ONE;1-(BETA-AMINOETHYL)-2-IMIDAZOLIDONE;1-(2-Aminoethyl)-2-oxoimidazolidine
- CBNumber
- CB1452532
- Molecular Formula
- C5H11N3O
- Formula Weight
- 129.16
- MOL File
- 6281-42-1.mol
1-(2-Aminoethyl)imidazolidin-2-one Property
- Boiling point:
- 138-140/0.11mm
- Density
- 1.137±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- viscous oil
- pka
- 14.42±0.20(Predicted)
- color
- Orange
- InChI
- InChI=1S/C5H11N3O/c6-1-3-8-4-2-7-5(8)9/h1-4,6H2,(H,7,9)
- InChIKey
- PODSUMUEKRUDEI-UHFFFAOYSA-N
- SMILES
- C1(=O)N(CCN)CCN1
- CAS DataBase Reference
- 6281-42-1(CAS DataBase Reference)
- EPA Substance Registry System
- 2-Imidazolidinone, 1-(2-aminoethyl)- (6281-42-1)
Safety
- Hazard Codes
- Xi,C
- Risk Statements
- 34
- Safety Statements
- 22-26-36/37/39-45
- RIDADR
- 3259
- Hazard Note
- Irritant
- HazardClass
- 8
- HS Code
- 29332900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- A3472
- Product name
- 1-(2-Aminoethyl)imidazolidin-2-one
- Purity
- min. 95.0 %
- Packaging
- 1G
- Price
- $65
- Updated
- 2025/07/31
- Product number
- A3472
- Product name
- 1-(2-Aminoethyl)imidazolidin-2-one
- Purity
- min. 95.0 %
- Packaging
- 5G
- Price
- $195
- Updated
- 2025/07/31
- Product number
- J55195
- Product name
- 1-(2-Aminoethyl)-2-imidazolidinone
- Packaging
- 10g
- Price
- $185
- Updated
- 2021/12/16
- Product number
- JK102188
- Product name
- 1-(2-Aminoethyl)imidazolidin-2-one
- Purity
- 96%
- Packaging
- 5g
- Price
- $332
- Updated
- 2021/12/16
- Product number
- FA106342
- Product name
- 1-(2-Aminoethyl)-2-imidazolidone
- Packaging
- 10g
- Price
- $410
- Updated
- 2021/12/16
1-(2-Aminoethyl)imidazolidin-2-one Chemical Properties,Usage,Production
Chemical Properties
Colorless to off-white liquid
Uses
1-(2-Aminoethyl)-2-imidazolidone is a useful research chemical compound used in the preparation of alkyl and aryl azides by chemoselective diazotization of primary amines with in situ-generated fluorosulfonyl azide and their use in the preparation of a combinatorial library of 1,2,3-triazole.
Flammability and Explosibility
Not classified
Synthesis
111-40-0
57-13-6
6281-42-1
693 kg (6.728 kmol) of diethylenetriamine (DETA) was added to a 1 m3 stirred reactor equipped with a double jacket, a liquid feed device, a nitrogen inerting system, a reaction vessel, and a scrubber tower for recovery of ammonia and ammonia solution. The reaction system was warmed up to 130°C while nitrogen was introduced to remove oxygen from the DETA. When the temperature reached 130 °C, slow addition of a 40% aqueous urea solution totaling 671.4 kg (4.476 kmol) was initiated, resulting in a molar ratio of DETA to urea of 1.5:1. The addition of the urea solution continued for a period of 4 h in batches. The ammonia released immediately at the beginning of the reaction was recovered through a scrubbing tower, and the scrubbing solution and the aqueous ammonia solution were collected in a special container. After the addition was completed, the reaction mixture was kept at 130°C for 1.5 hours to ensure complete water removal. Subsequently, the reaction temperature was gradually increased: first to 140 °C in 45 min and held for 45 min, then to 150 °C and held for 45 min, and finally at 160 °C for 5 h. The reaction temperature was then increased to 140 °C in 45 min and held for 45 min. At the end of the reaction, the system was cooled to 125 °C and the excess DETA was removed by distillation under a reduced pressure of 10 to 1.5 mbar and a mild nitrogen stream, a process that did not take more than 5 hours. After restoring the system to atmospheric pressure, it was cooled to 60 °C and the product was removed from the reactor. The resulting product contained 95-96% of 1-(2-aminoethyl)-2-imidazolidinone (UDETA) and 1-2.5% of tetraethyleneurea (TETU).
References
[1] Patent: US2013/23667, 2013, A1. Location in patent: Paragraph 0044; 0045; 0046; 0047
[2] Patent: US2613212, 1950,
[3] Patent: US6630599, 2003, B1. Location in patent: Page/Page column 10
1-(2-Aminoethyl)imidazolidin-2-one Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-(2-Aminoethyl)imidazolidin-2-one manufacturers
- Product
- 1-(2-Aminoethyl)imidazolidin-2-one 6281-42-1
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 200kg
- Release date
- 2018-12-24