ChemicalBook > CAS DataBase List > (+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL

(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL

Product Name
(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL
CAS No.
137365-16-3
Chemical Name
(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL
Synonyms
(+)-DINOL;(4S-trans)-2,2-di-me-A,A,A,A-tetra-2-nap -dioxo;(+)-2,3-O-isopropylidene-1,1,4,4-tetra (2-naph.)-D-threitol;(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL;(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL;(4s,5s)-2,2-dimethyl-α,α,α',α'-tetra(2-naphthyl)dioxolane-4,5-dimethanol;(+)-DINOL, (+)-2,3-O-Isopropylidene-1,1,4,4-tetra(2-naphthyl)-D-threitol;(4S,5S)-2,2-DiMethyl-α,α,α`,α`-tetra(2-naphthyl)-1,3-dioxolane-4,5-diMethanol;((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-2-yl)methanol);(4s-trans)-2,2-dimethyl-α,α,α',α'-tetra(2-naphthyl)-1,3-dioxolane-4,5-dimethanol
CBNumber
CB1463840
Molecular Formula
C47H38O4
Formula Weight
666.8
MOL File
137365-16-3.mol
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(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Property

Melting point:
214-216 °C(lit.)
Density 
1.269±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
12.14±0.29(Predicted)
optical activity
[α]20/D +116°, c = 1 in ethyl acetate
InChIKey
QWADMRIAKWGVBF-CXNSMIOJSA-N
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Safety

WGK Germany 
3
F 
10
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
CHM0004335
Product name
(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA (2-NAPH)-D-THREITOL
Purity
95.00%
Packaging
1G
Price
$893.19
Updated
2021/12/16
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(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Chemical Properties,Usage,Production

Uses

Reagent for the highly enantioselective addition of primary alkyl Grignards to ketones. Chiral auxiliary used for the asymmetric addition of nucleophiles to carbonyls.

(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL Suppliers

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137365-16-3, (+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOLRelated Search:

D-THREITOL 3,3-Diphenylpropanol (+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL (R)-(+)-ALPHA-METHYL-2-NAPHTHALENEMETHANOL (S)-(-)-ALPHA-METHYL-2-NAPHTHALENEMETHANOL PHENYLETHYL ACETAL 4-METHYL-1-PHENYL-2-PENTANOL 3-NAPHTHALEN-2-YL-PROPAN-1-OL 2-ISOPROPYLNAPHTHALENE 1-(2-NAPHTHYL)ETHANOL 1,1-DIPHENYL-2-PROPANOL (+)-Taddol (S)-(-)-1,1-DIPHENYL-1,2-PROPANEDIOL (-)-2,3-O-Isopropylidene-D-threitol Naphthalen-2-ethanol (S)-(+)-1,1-DIPHENYL-2-PROPANOL

  • (4S,5S)-2,2-dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-1,3-Dioxolane-4,5-dimethanol
  • (+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL
  • (4S-TRANS)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(2-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOL
  • (4S,5S)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(2-NAPHTHYL)DIOXOLANE-4,5-DIMETHANOL
  • (+)-DINOL
  • (+)-2,3-O-isopropylidene-1,1,4,4-tetra (2-naph.)-D-threitol
  • (4S-trans)-2,2-di-me-A,A,A,A-tetra-2-nap -dioxo
  • (4S-TRANS)-2,2-DI-ME-A,A,A',A'-TETRA-2-N AP -DIOXOLAN-DIMETHANOL, 98%(99% EE/HPLC
  • (4S,5S)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(2-naphthyl)dioxolane-4,5-di
  • (4s,5s)-2,2-dimethyl-α,α,α',α'-tetra(2-naphthyl)dioxolane-4,5-dimethanol
  • (4s-trans)-2,2-dimethyl-α,α,α',α'-tetra(2-naphthyl)-1,3-dioxolane-4,5-dimethanol
  • (+)-DINOL, (4S,5S)-2,2-Dimethyl-α,α,αμ,αμ-tetra(2-naphthyl)dioxolane-4,5-dimethanol, (+)-2,3-O-Isopropylidene-1,1,4,4-tetra(2-naphthyl)-D-threitol
  • (+)-DINOL, (+)-2,3-O-Isopropylidene-1,1,4,4-tetra(2-naphthyl)-D-threitol
  • (4S,5S)-2,2-DiMethyl-α,α,α`,α`-tetra(2-naphthyl)-1,3-dioxolane-4,5-diMethanol
  • [(4S,5S)-5-[hydroxy(dinaphthalen-2-yl)Methyl]-2,2-diMethyl-1,3-dioxolan-4-yl]-dinaphthalen-2-ylMethanol
  • 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-, (4S,5S)-
  • (+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-D-THREITOL
  • ((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-2-yl)methanol)
  • (4S,5S)-2,2-dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-1,3-Dioxolane-4,5-dimethanol
  • 137365-16-3
  • Privileged Ligands
  • TADDOLs
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents