3-METHOXY-BENZENE-1,2-DIAMINE

Product Name: 3-METHOXY-BENZENE-1,2-DIAMINE
CAS No.: 37466-89-0
Chemical Name: 3-METHOXY-BENZENE-1,2-DIAMINE
Synonyms: NSC 521887;hydrosulphate;2,3-DiaMinoanisol;2,3-Diaminoanisole;Esomeprazol Impurity 7;Esomeprazole Impurity 29;3-Methoxy-2-amino-aniline;1,2-Diamino-3-methoxybenzene;3-Methoxy-1,2-benzenediamine;3-Methoxy-1,2-diaminobenzene
CBNumber: CB1470817
Molecular Formula: C7H10N2O
Formula Weight: 138.17
MOL File: 37466-89-0.mol

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3-METHOXY-BENZENE-1,2-DIAMINE Property

Melting point:: 77-78℃
Boiling point:: 114-116 °C(Press: 0.5 Torr)
Density: 1.170±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: solid
pka: 4.10±0.10(Predicted)
color: Black
Water Solubility: Slightly soluble in water.
Sensitive: Air Sensitive
CAS DataBase Reference: 37466-89-0

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Safety

HazardClass: 6.1
HS Code: 2922290090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

SynQuest Laboratories

Product number: 4656-1-2S
Product name: 3-Methoxyphenylene-1,2-diamine
Packaging: 250mg
Price: $56
Updated: 2021/12/16

AK Scientific

Product number: 4785AB
Product name: 3-Methoxybenzene-1,2-diamine
Packaging: 250mg
Price: $130
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4656-1-2S
Product name: 3-Methoxyphenylene-1,2-diamine
Packaging: 1g
Price: $144
Updated: 2021/12/16

Matrix Scientific

Product number: 125986
Product name: 3-Methoxybenzene-1,2-diamine;sulfuricacid
Purity: >95%
Packaging: 500mg
Price: $276
Updated: 2021/12/16

Matrix Scientific

Product number: 125986
Product name: 3-Methoxybenzene-1,2-diamine;sulfuricacid
Purity: >95%
Packaging: 1g
Price: $372
Updated: 2021/12/16

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3-METHOXY-BENZENE-1,2-DIAMINE Chemical Properties,Usage,Production

Uses

3-Methoxy-o-phenylenediamine is used as pharmaceutical intermediate.

Synthesis

16554-47-5

37466-89-0

General procedure for the synthesis of 1,2-diamino-3-methoxybenzene from 2-nitro-3-methoxyaniline: 5% palladium-carbon catalyst (18 mg, 20 wt%) was added to a solution of 2-nitro-3-methoxyaniline (90 mg, 0.54 mmol) in ethanol (3 mL). The reaction mixture was stirred at room temperature in a hydrogen atmosphere for 18 hours. Upon completion of the reaction, the catalyst was removed by diatomaceous earth filtration and the filtrate was subsequently evaporated to afford the target product 3-methoxy-1,2-benzenediamine (73 mg, 100% yield).

References

[1] Patent: WO2006/50506, 2006, A1. Location in patent: Page/Page column 126
[2] Bulletin of the Korean Chemical Society, 2010, vol. 31, # 11, p. 3441 - 3444
[3] Patent: EP2168959, 2010, A1. Location in patent: Page/Page column 121
[4] Patent: EP2168960, 2010, A1. Location in patent: Page/Page column 61-62
[5] Patent: US2011/301170, 2011, A1. Location in patent: Page/Page column 29

3-METHOXY-BENZENE-1,2-DIAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-METHOXY-BENZENE-1,2-DIAMINE Suppliers

China 77 France 1 India 3 United Kingdom 1 United States 7 Global 89

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View Lastest Price from 3-METHOXY-BENZENE-1,2-DIAMINE manufacturers

Career Henan Chemical Co

Product: 3-METHOXY-BENZENE-1,2-DIAMINE 37466-89-0
Price: US $2.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg, 5kg ,50kg
Release date: 2020-01-08

37466-89-0, 3-METHOXY-BENZENE-1,2-DIAMINERelated Search:

2-METHOXY-6-NITRO-PHENYLAMINE (+/-)-CGP-12177 HYDROCHLORIDE 1,2-Diamino-3,4-ethylenedioxybenzene 5,6,7-TRINITRO-2,3-DIHYDRO-1,4-BENZODIOXINE ZERENEX ZX005138 AKOS BB-9291 ETHYL 6,8-DIMETHOXYPYRAZOLO[5,1-C][1,2,4]BENZOTRIAZINE-3-CARBOXYLATE ZERENEX ZX005131 2,5-DIETHOXY-6-MORPHOLINO-BENZENE-DIAZONIUM-TETRAFLUOROBORATE 4-METHOXY-2,3-DINITROANILINE 2-METHOXY-4-MORPHOLINO-3,5-DINITROPHENYL METHYL ETHER 5-METHOXY-6,7,8-TRINITRO-2,3-DIHYDRO-1,4-BENZODIOXINE 1,2-dimethoxy-3,4,5-trinitro-benzene N-(2-AMINO-3,6-DIMETHOXYPHENYL)-2-CHLORO-2,2-DIFLUOROACETAMIDE 5,6-Dinitro-2,3-dihydro-1,4-benzodioxin 2-AMINO-3-NITROANISOLE DIAZOTATE (-)-CGP 12177, [5,7-3H]-

3-Methoxyphenylene-1,2-diamine

hydrosulphate

2,3-Diaminoanisole

1,2-Diamino-3-methoxybenzene

3-Methoxy-1,2-phenylenediamine

3-METHOXY-BENZENE-1,2-DIAMINE

Esomeprazole Impurity 29

1,2-BenzenediaMine, 3-Methoxy-

Methoxy-para-phenylenediaMine

2,3-DiaMinoanisol

3-Methoxy-o-phenylenediaMine, 97%

3-Methoxy-1,2-benzenediamine

3-Methoxy-1,2-diaminobenzene

NSC 521887

3-Methoxy-o-phenylenediamine,97%

(S)-2-(((4-chloro-3,5-dimethylpyridin-2-yl)methyl)sulfinyl)-5-methoxy-1H-benzo[d]imidazole

Esomeprazol Impurity 7

3-METHOXY-BENZENE-1,2-DIAMINE 97%min

3-Methoxy-2-amino-aniline

37466-89-0