ChemicalBook > CAS DataBase List > N-BENZYLQUININIUM CHLORIDE

N-BENZYLQUININIUM CHLORIDE

Product Name
N-BENZYLQUININIUM CHLORIDE
CAS No.
67174-25-8
Chemical Name
N-BENZYLQUININIUM CHLORIDE
Synonyms
QUIBEC;(2S,4S,5R);-1-Benzyl-2-((R);1-Benzylquininium chloride;N-BENZYLQUININIUM CHLORIDE;N-Benzylquinine (chloride);iNi-BenzylquininiumChloride;N-Benzylquininium chloride 95%;N-Benzylquininium chloride ,98%;N-Benzylquininium chloride, 95%, for synthesis
CBNumber
CB1475236
Molecular Formula
C27H31ClN2O2
Formula Weight
451.01
MOL File
67174-25-8.mol
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N-BENZYLQUININIUM CHLORIDE Property

Melting point:
200-205 °C (dec.) (lit.)
refractive index 
227.5 ° (C=1.5, H2O)
storage temp. 
2-8°C
solubility 
freely sol H2O, alcohols, acetone; slightly sol EtOAc; sparingly sol CHCl3
form 
powder to crystal
color 
White to Light yellow
optical activity
[α]20/D 235°, c = 1.5 in H2O
BRN 
5702637
CAS DataBase Reference
67174-25-8
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
374482
Product name
N-Benzylquininium chloride
Purity
95%
Packaging
5g
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
B1685
Product name
N-Benzylquininium Chloride [Chiral Phase-Transfer Catalyst]
Purity
>98.0%(T)
Packaging
5g
Price
$111
Updated
2023/06/20
Alfa Aesar
Product number
H53424
Product name
N-Benzylquininium chloride, 95%
Packaging
1g
Price
$34.65
Updated
2024/03/01
Alfa Aesar
Product number
H53424
Product name
N-Benzylquininium chloride, 95%
Packaging
5g
Price
$148.65
Updated
2024/03/01
Alfa Aesar
Product number
H53424
Product name
N-Benzylquininium chloride, 95%
Packaging
25g
Price
$489
Updated
2021/12/16
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N-BENZYLQUININIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Off-white to brown powder

Uses

N-Benzylquininium chloride can be used as a phase transfer catalyst:

  • In the sulfenylation of various β-keto sulfoxides.
  • To synthesize N-carbamoyl-protected β-nitroamines from α-amido sulfones by asymmetric aza-Henry reaction.

General Description

N-Benzylquininium chloride (or Quibec) belongs to the class of cinchona family of alkaloids. It is used as a catalyst in the presence of hydroxide bases in various phase transfer reactions, epoxidations, alkylations, and Michael reactions.

N-BENZYLQUININIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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N-BENZYLQUININIUM CHLORIDE Suppliers

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View Lastest Price from N-BENZYLQUININIUM CHLORIDE manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
N-BENZYLQUININIUM CHLORIDE 67174-25-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-15
Hebei Mojin Biotechnology Co., Ltd
Product
N-BENZYLQUININIUM CHLORIDE 67174-25-8
Price
US $1850.00/g
Min. Order
1g
Purity
99.99%
Supply Ability
200ton
Release date
2023-08-10
Career Henan Chemical Co
Product
N-BENZYLQUININIUM CHLORIDE 67174-25-8
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Kg/T
Release date
2019-12-19

67174-25-8, N-BENZYLQUININIUM CHLORIDERelated Search:

Quinine Quinine hydrochloride Mepiquat chloride N-BENZYLQUININIUM CHLORIDE N-Benzyl-N-methylpiperidinium chloride N-Benzylcinchonidinium chloride Benzyltripropylammonium chloride Tetraethylammonium Chloride Benzyltriethylammonium chloride BENZYL(2-HYDROXYETHYL)DIMETHYLAMMONIUM CHLORIDE 6-BENZYLAMINO-1-HEXANOL Methyltripropyl ammonium chloride CINCHONIDINE HYDROCHLORIDE 4-(2-AMINOETHYL)PYRIDINE HCL triethyl(2-hydroxyethyl)ammonium chloride (1-BENZYL-2-PIPERIDINYL)METHANOL N-BUTYLTRIETHYLAMMONIUM CHLORIDE

  • N-Benzylquininium Chloride [Chiral Phase-Transfer Catalyst]
  • N-BENZYLQUININIUM CHLORIDE
  • QUIBEC
  • N-Benzylquininium chloride ,98%
  • CinchonaniuM, 9-hydroxy-6'-Methoxy-1-(phenylMethyl)-,chloride, (8a,9R)-
  • 1-Benzylquininium chloride
  • N-Benzylquininium chloride 95%
  • (2S,4S,5R)
  • -1-Benzyl-2-((R)
  • (2S,4S,5R)-1-Benzyl-2-((R)-hydroxy(6-methoxyquinolin-4-yl)methyl)-5-vinylquinuclidin-1-ium chloride
  • N-Benzylquininium Chloride [Chiral Phase-Transfer Catalyst]&gt
  • N-Benzylquininium chloride, 95%, for synthesis
  • iNi-BenzylquininiumChloride
  • N-BENZYLQUININIUM CHLORIDE ISO 9001：2015 REACH
  • (1S,2S,4S,5R)-1-Benzyl-2-((R)-hydroxy(6-methoxyquinolin-4-yl)methyl)-5-vinylquinuclidin-1-ium chloride
  • N-Benzylquinine (chloride)
  • 67174-25-8
  • C27H31N2O2Cl
  • Phase Transfer Reaction
  • Alkoxyquinolines
  • Chiral Phase-Transfer Catalysts
  • Ammonium Chlorides (Quaternary)
  • Quinoline Alkaloids
  • Alkaloids
  • Asymmetric Synthesis
  • Quinolines
  • Quaternary Ammonium Compounds
  • Chiral Catalysts, Ligands, and Reagents
  • Ammonium Chlorides (Quaternary)
  • Asymmetric Synthesis
  • Biochemistry
  • Chiral Phase-Transfer Catalysts
  • Quaternary Ammonium Compounds
  • Quinoline Alkaloids
  • Quinolines
  • Synthetic Organic Chemistry
  • Alkaloids
  • Alkoxyquinolines