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ETHYLALUMINUM DICHLORIDE

Product Name
ETHYLALUMINUM DICHLORIDE
CAS No.
563-43-9
Chemical Name
ETHYLALUMINUM DICHLORIDE
Synonyms
EADC;uminum dichL;dichloroethyl-aluminu;Ethyldichloroaluminum;DICHLOROETHYLALUMINUM;Aluminum,dichloroethyl-;dichlororthyl aluminium;Ethylaluminiumdichlorid;Dichloro(ethyl)aluminium;Aluminiumethyldichloride
CBNumber
CB1476899
Molecular Formula
C2H5AlCl2
Formula Weight
126.95
MOL File
563-43-9.mol
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ETHYLALUMINUM DICHLORIDE Property

Melting point:
32 °C(lit.)
Boiling point:
68-70°C
Density 
0.927 g/mL at 25 °C
vapor pressure 
5 mm Hg ( 60 °C)
Flash point:
40 °F
storage temp. 
0-6°C
form 
Liquid
color 
Colorless to pale yellow
Specific Gravity
0.927
Water Solubility 
Soluble in acetone. Miscible with alcohol, chloroform, ether. Reacts with water.
FreezingPoint 
32℃
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
Merck 
326
BRN 
4123357
Exposure limits
ACGIH: TWA 50 ppm (Skin)
OSHA: TWA 500 ppm(1800 mg/m3)
NIOSH: IDLH 1100 ppm; TWA 50 ppm(180 mg/m3)
InChIKey
UAIZDWNSWGTKFZ-UHFFFAOYSA-L
CAS DataBase Reference
563-43-9(CAS DataBase Reference)
EPA Substance Registry System
Aluminum, dichloroethyl- (563-43-9)
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Safety

Hazard Codes 
F,T,N,C
Risk Statements 
11-15-23/24/25-34-14-67-65-62-51/53-48/20-14/15-17-63
Safety Statements 
16-26-36/37/39-45-62-61-43-27
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
1
RTECS 
BD0705000
10-21
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
I
HS Code 
29319090
Hazardous Substances Data
563-43-9(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H304May be fatal if swallowed and enters airways

H314Causes severe skin burns and eye damage

H336May cause drowsiness or dizziness

H373May cause damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
192759
Product name
Ethylaluminum dichloride solution
Purity
25wt. % in toluene
Packaging
100g
Price
$87.9
Updated
2024/03/01
Sigma-Aldrich
Product number
192759
Product name
Ethylaluminum dichloride solution
Purity
25wt. % in toluene
Packaging
800g
Price
$466
Updated
2024/03/01
Alfa Aesar
Product number
041712
Product name
Ethylaluminum dichloride, 1M in hexane
Packaging
10ml
Price
$13.65
Updated
2024/03/01
Alfa Aesar
Product number
041712
Product name
Ethylaluminum dichloride, 1M in hexane
Packaging
250ml
Price
$111.65
Updated
2024/03/01
Sigma-Aldrich
Product number
251615
Product name
Ethylaluminum dichloride solution
Purity
1.0M in hexanes
Packaging
100ml
Price
$91.9
Updated
2024/03/01
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ETHYLALUMINUM DICHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to yellow solution

Chemical Properties

The aluminum alkyl halides are flammable, reactive, and may be spontaneously combustible in air. They are colorless to yellow liquids. Ethylaluminum dichloride:(563-43-9):

Uses

Catalyst for olefin polymerization, aromatic hydrogenation; intermediate.

Uses

Ethylaluminum dichloride is used as a catalyst component in the polyolefin industry, for the synthesis of synthetic rubbers and for the dimerisation of olefins. It is also employed as a catalyst for Friedel-Crafts acylations.

General Description

A colorless to light-yellow heated liquid. Freezing point 90°F.

Air & Water Reactions

Highly flammable. Ignites when exposed to air. Reacts violently with water or moisture in air forming hydrogen chloride fumes and flammable ethane gas (Rose 1961).

Reactivity Profile

Organometallics, such as ETHYLALUMINUM DICHLORIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Organometallics containing halogens (fluorine, chlorine, bromine, iodine) bonded to the metal typically with generate gaseous hydrohalic acids (HF, HCl, HBr, HI) with water.

Hazard

Ignites on contact with air, dangerous fire risk, reacts violently with water. Skin irritant.

Health Hazard

Inhalation of smoke from fire causes metal-fume fever (flu-like symptoms); acid fumes irritate nose and throat. Contact with liquid (which is spontaneously flammable) causes severe burns of eyes and skin.

Potential Exposure

These materials are used as components of olefin polymerization catalysts. The reader is referred to the entry on “Aluminum alkyls” for additional information on this entry. The aluminum alkyl halides parallel very closely the aluminum alkyls

Shipping

UN3052 Spontaneously combustible. Water reactive releasing large quantities of toxic and deadly hydrogen gas. (Note: this number does not appear in the 49/CFR HazMat tables)

Incompatibilities

The aluminum alkyl halides are strong reducing agents; they react—possibly violently—with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. These chemicals react violently with nitromethaneEthylaluminum sesquichloride reacts explosively with carbon tetrachloride at room temperature. This chemical reacts violently with water, forming corrosive hydrogen chloride and flammable ethane gas. Diethylaluminum chloride may form an explosive product with chlorine azide.

ETHYLALUMINUM DICHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYLALUMINUM DICHLORIDE Suppliers

Huangshi Bo’Er Chemical Co., Ltd.
Tel
0714-6401888 18671400300
Fax
0714-6401888
Email
273568016@qq.com
Country
China
ProdList
536
Advantage
58
Baoji Funuokang Industrial Co., Ltd
Tel
13220096790
Email
1754423088@qq.com
Country
China
ProdList
2998
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Hangzhou Yuhao Chemical Technology Co., Ltd
Tel
0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
9387
Advantage
52
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View Lastest Price from ETHYLALUMINUM DICHLORIDE manufacturers

Career Henan Chemical Co
Product
ETHYLALUMINUM DICHLORIDE 563-43-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kgs
Release date
2020-03-05
Career Henan Chemical Co
Product
ETHYLALUMINUM DICHLORIDE 563-43-9
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
1ton
Release date
2019-12-31

563-43-9, ETHYLALUMINUM DICHLORIDERelated Search:


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  • 563-43-9
  • CH3CH2AlCl2
  • C2H5AlCl2
  • C2H5Cl2Al
  • C2H5AICI2