TRIPHENYLPHOSPHINE DIBROMIDE
- Product Name
- TRIPHENYLPHOSPHINE DIBROMIDE
- CAS No.
- 1034-39-5
- Chemical Name
- TRIPHENYLPHOSPHINE DIBROMIDE
- Synonyms
- DIBROMOTRIPHENYLPHOSPHORANE;Triphenyldibromophosphorane;SKL183;phosphine dibromide;dibromo(triphenyl)-;dibromotriphenyl-phosphoran;DIBROMO TRIPHENYL PHOSPHINE;TRIPHENYLPHOSPHINE DIBROMIDE;Phosphorane, dibromotriphenyl-;Dibromotriphenylphosphorane,98%
- CBNumber
- CB1670688
- Molecular Formula
- C18H15Br2P
- Formula Weight
- 422.09
- MOL File
- 1034-39-5.mol
TRIPHENYLPHOSPHINE DIBROMIDE Property
- Melting point:
- 235 °C (dec.) (lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Crystalline Powder
- color
- Light yellow to light pink
- Water Solubility
- Soluble in water, dichloromethane, acetonitrile, phenyl cyanide, dimethyl formamide, ether, chloroform, alcohol, carbon tetrachloride, acetic acid and carbon disulfide. Sparingly soluble in phenyl chloride, triphenylphosphine and phenyl hydride. Insoluble in aqueous bromine.
- Sensitive
- Moisture Sensitive
- BRN
- 917652
- InChIKey
- OCXGTPDKNBIOTF-UHFFFAOYSA-N
- CAS DataBase Reference
- 1034-39-5(CAS DataBase Reference)
- EPA Substance Registry System
- Phosphorane, dibromotriphenyl- (1034-39-5)
Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 3-10-21
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29319019
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 270946
- Product name
- Triphenylphosphine dibromide
- Purity
- 96%
- Packaging
- 5g
- Price
- $40.2
- Updated
- 2024/03/01
- Product number
- 270946
- Product name
- Triphenylphosphine dibromide
- Purity
- 96%
- Packaging
- 25g
- Price
- $148
- Updated
- 2024/03/01
- Product number
- A11552
- Product name
- Triphenylphosphine dibromide, 96%
- Packaging
- 10g
- Price
- $46.65
- Updated
- 2024/03/01
- Product number
- A11552
- Product name
- Triphenylphosphine dibromide, 96%
- Packaging
- 50g
- Price
- $201
- Updated
- 2024/03/01
- Product number
- 15-0990
- Product name
- Dibromotriphenylphosphorane, 98%
- Packaging
- 10g
- Price
- $60
- Updated
- 2024/03/01
TRIPHENYLPHOSPHINE DIBROMIDE Chemical Properties,Usage,Production
Chemical Properties
light yellow to light pink crystalline powder
Uses
Triphenylphosphine dibromide is used as a reagent for conversion of aldoximes into nitriles. It acts as a reagent for cleavage of acetals. It reacts with amines to give iminophosphoranes. Further, it serves as a reagent in the preparation of alkyl and aryl bromides from alcohols and phenols without rearrangement.
Purification Methods
It recrystallises from MeCN/Et2O. Although it has been recrystallised from EtOH, this is not recommended as it converts alcohols to alkyl bromides. It deteriorates on keeping, and it is best to prepare it afresh. [Anderson & Freenor J Am Chem Soc 86 5037 1964, Horner et al. Justus Liebigs Ann Chem 626 26 1959, Beilstein 16 III 864.]
TRIPHENYLPHOSPHINE DIBROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
TRIPHENYLPHOSPHINE DIBROMIDE Suppliers
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View Lastest Price from TRIPHENYLPHOSPHINE DIBROMIDE manufacturers
- Product
- Triphenylphosphine Dibromide 1034-39-5
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 20 tons
- Release date
- 2023-11-20
- Product
- Triphenylphosphine Dibromide 1034-39-5
- Price
- US $30.00-10.00/KG
- Min. Order
- 50KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2022-09-21
- Product
- TRIPHENYLPHOSPHINE DIBROMIDE 1034-39-5
- Price
- US $9.00/KG
- Min. Order
- 1KG
- Purity
- 99.9
- Supply Ability
- 1 ton
- Release date
- 2024-08-21