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TRIPHENYLPHOSPHINE DIBROMIDE

Product Name
TRIPHENYLPHOSPHINE DIBROMIDE
CAS No.
1034-39-5
Chemical Name
TRIPHENYLPHOSPHINE DIBROMIDE
Synonyms
DIBROMOTRIPHENYLPHOSPHORANE;Triphenyldibromophosphorane;SKL183;phosphine dibromide;dibromo(triphenyl)-;dibromotriphenyl-phosphoran;DIBROMO TRIPHENYL PHOSPHINE;TRIPHENYLPHOSPHINE DIBROMIDE;Phosphorane, dibromotriphenyl-;Dibromotriphenylphosphorane,98%
CBNumber
CB1670688
Molecular Formula
C18H15Br2P
Formula Weight
422.09
MOL File
1034-39-5.mol
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TRIPHENYLPHOSPHINE DIBROMIDE Property

Melting point:
235 °C (dec.) (lit.)
storage temp. 
Inert atmosphere,Room Temperature
form 
Crystalline Powder
color 
Light yellow to light pink
Water Solubility 
Soluble in water, dichloromethane, acetonitrile, phenyl cyanide, dimethyl formamide, ether, chloroform, alcohol, carbon tetrachloride, acetic acid and carbon disulfide. Sparingly soluble in phenyl chloride, triphenylphosphine and phenyl hydride. Insoluble in aqueous bromine.
Sensitive 
Moisture Sensitive
BRN 
917652
InChIKey
OCXGTPDKNBIOTF-UHFFFAOYSA-N
CAS DataBase Reference
1034-39-5(CAS DataBase Reference)
EPA Substance Registry System
Phosphorane, dibromotriphenyl- (1034-39-5)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
3-10-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29319019
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
270946
Product name
Triphenylphosphine dibromide
Purity
96%
Packaging
5g
Price
$40.2
Updated
2024/03/01
Sigma-Aldrich
Product number
270946
Product name
Triphenylphosphine dibromide
Purity
96%
Packaging
25g
Price
$148
Updated
2024/03/01
Alfa Aesar
Product number
A11552
Product name
Triphenylphosphine dibromide, 96%
Packaging
10g
Price
$46.65
Updated
2024/03/01
Alfa Aesar
Product number
A11552
Product name
Triphenylphosphine dibromide, 96%
Packaging
50g
Price
$201
Updated
2024/03/01
Strem Chemicals
Product number
15-0990
Product name
Dibromotriphenylphosphorane, 98%
Packaging
10g
Price
$60
Updated
2024/03/01
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TRIPHENYLPHOSPHINE DIBROMIDE Chemical Properties,Usage,Production

Chemical Properties

light yellow to light pink crystalline powder

Uses

Triphenylphosphine dibromide is used as a reagent for conversion of aldoximes into nitriles. It acts as a reagent for cleavage of acetals. It reacts with amines to give iminophosphoranes. Further, it serves as a reagent in the preparation of alkyl and aryl bromides from alcohols and phenols without rearrangement.

Purification Methods

It recrystallises from MeCN/Et2O. Although it has been recrystallised from EtOH, this is not recommended as it converts alcohols to alkyl bromides. It deteriorates on keeping, and it is best to prepare it afresh. [Anderson & Freenor J Am Chem Soc 86 5037 1964, Horner et al. Justus Liebigs Ann Chem 626 26 1959, Beilstein 16 III 864.]

TRIPHENYLPHOSPHINE DIBROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIPHENYLPHOSPHINE DIBROMIDE Suppliers

Innochem(Beijing) Technology Co.,Ltd.
Tel
10-56541685 13070143590
Fax
010-56541685
Email
sales@innochem.cn
Country
China
ProdList
124
Advantage
57
Nanjing Kaitian Chemical Co., Ltd
Tel
133-3781-5734 15951673915
Email
2361662303@qq.com
Country
China
ProdList
94
Advantage
58
Shanghai Boyle Chemical Co., Ltd.
Tel
021-50182298 021-50180596
Fax
+86-21-57758967
Email
sales@boylechem.com
Country
China
ProdList
2208
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
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View Lastest Price from TRIPHENYLPHOSPHINE DIBROMIDE manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Triphenylphosphine Dibromide 1034-39-5
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-20
Hebei Weibang Biotechnology Co., Ltd
Product
Triphenylphosphine Dibromide 1034-39-5
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2022-09-21
Hebei Chuanghai Biotechnology Co,.LTD
Product
TRIPHENYLPHOSPHINE DIBROMIDE 1034-39-5
Price
US $9.00/KG
Min. Order
1KG
Purity
99.9
Supply Ability
1 ton
Release date
2024-08-21

1034-39-5, TRIPHENYLPHOSPHINE DIBROMIDERelated Search:


  • TRIPHENYLPHOSPHINE DIBROMIDE
  • DIBROMO TRIPHENYL PHOSPHINE
  • DIBROMOTRIPHENYLPHOSPHORANE
  • BROMOTRIPHENYLPHOSPHONIUM BROMIDE
  • dibromotriphenyl-phosphoran
  • phosphine dibromide
  • Dibromotriphenylphosphorane,98%
  • Phosphorane, dibromotriphenyl-
  • Bromotriphenylphosphonium bromide, Dibromotriphenylphosphorane
  • Triphenyldibromophosphorane
  • dibroMotriphenyl-$l^{5}-phosphane
  • Triphenylphosphine dibroMide 96%
  • Triphenylphosphine dibromide, ca. 33% bromine
  • Triphenylphosphine dibromide, tech. 90%
  • Triphenylphosphine dibromide,Bromotriphenylphosphonium bromide, Dibromotriphenylphosphorane
  • Triphenylphosphine dibromide, 95%, for synthesis
  • SKL183
  • Triphenylphosphonium Dibromide pure, 98%
  • dibromo(triphenyl)-
  • 1034-39-5
  • C6H53PBr2
  • C18H15BrP
  • C18H15Br2P
  • Bromination
  • Synthetic Reagents
  • C-X Bond Formation (Halogen)
  • organophosphorus compound