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Phenyl phosphine

Product Name
Phenyl phosphine
CAS No.
638-21-1
Chemical Name
Phenyl phosphine
Synonyms
PHPH2;Phenylp;Phenylph;Fenylfosfin;Phosphaniline;AURORA KA-1101;PHENYLPHOSPHINE;phenyl-phosphin;Phenyl-phosphane;Phosphine, phenyl-
CBNumber
CB0140869
Molecular Formula
C6H7P
Formula Weight
110.09
MOL File
638-21-1.mol
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Phenyl phosphine Property

Boiling point:
160°C
Density 
1.001
vapor density 
3.79 (vs air)
vapor pressure 
760 mmHg ( 160 °C)
refractive index 
1.578
Flash point:
-20°F
storage temp. 
?20°C
form 
liquid
color 
colorless
Water Solubility 
Insoluble in water.
Sensitive 
Air & Moisture Sensitive
BRN 
741946
InChIKey
RPGWZZNNEUHDAQ-UHFFFAOYSA-N
CAS DataBase Reference
638-21-1(CAS DataBase Reference)
NIST Chemistry Reference
Phenylphosphine(638-21-1)
EPA Substance Registry System
Phosphine, phenyl-(638-21-1)
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Safety

Hazard Codes 
F;T;N,N,T,F,Xn
Risk Statements 
11-17-23/24/25-36/37/38-48/20-51/53-62-65-67-38-20/21/22
Safety Statements 
16-26-36/37/39-45-62-61-36/37
RIDADR 
2924
WGK Germany 
3
RTECS 
SZ2100000
HazardClass 
4.2
PackingGroup 
I
Hazardous Substances Data
638-21-1(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H227Combustible liquid

H250Catches fire spontaneously if exposed to air

H252Self-heating in large quantities; may catch fire

H302Harmful if swallowed

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P222Do not allow contact with air.

P231Handle under inert gas.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P422Store contents under …

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N-Bromosuccinimide Price

Alfa Aesar
Product number
030155
Product name
Phenylphosphine
Packaging
5g
Price
$289
Updated
2018/11/16
Strem Chemicals
Product number
15-4400
Product name
Phenylphosphine, 99%
Packaging
10g
Price
$328
Updated
2018/11/13
Strem Chemicals
Product number
15-4400
Product name
Phenylphosphine, 99%
Packaging
2g
Price
$82
Updated
2018/11/13
Strem Chemicals
Product number
15-4403
Product name
Phenylphosphine, 99% (10 wt% in hexanes)
Packaging
20g
Price
$122
Updated
2018/11/13
Strem Chemicals
Product number
15-4403
Product name
Phenylphosphine, 99% (10 wt% in hexanes)
Packaging
100g
Price
$368
Updated
2018/11/13
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Phenyl phosphine Chemical Properties,Usage,Production

Chemical Properties

Phenylphosphine is a clear, colorless liquid. Foul odor.

Uses

suzuki reaction

General Description

Clear colorless liquid.

Air & Water Reactions

Pyrophoric in air. Insoluble in water. Slowly generates flammable or noxious gases in contact with water.

Reactivity Profile

Phenyl phosphine is a reducing agent. They slowly generate flammable or noxious gases in contact with water. Phosphides react quickly upon contact with moisture or acids to give the very toxic gas phosphine; phosphides also can react vigorously with oxidizing materials. In general, materials in this group are incompatible with oxidizers such as atmospheric oxygen. They are violently incompatible with acids, particularly oxidizing acids.

Fire Hazard

Flash point data are not available for Phenyl phosphine, but Phenyl phosphine is probably combustible.

Safety Profile

Poison by inhalation. Igmtes spontaneously in air. When heated to decomposition it emits toxic fumes of POx. See also PHOSPHINE.

Potential Exposure

Polyphosphinate is used as an intermediate or a chemical reagent. Polyphosphinate compounds are used as catalysts and antioxidants disproportionate, when heated to give phosphonic acid derivatives plus PF.

Shipping

UN2845 Pyrophoric liquids, organic, n.o.s Hazard Class: 4.2, Labels: 4.2-Spontaneously combustible material. Technical Name Required. Note: this chemical is also a strong reducing agent.

Incompatibilities

A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Water reactive; spontaneously combustible in high concentrations in moist air. Potential exposure to gaseous phenylphosphine and phosphorus oxides when heated above 200C. Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Phenyl phosphine Preparation Products And Raw materials

Raw materials

Preparation Products

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Phenyl phosphine Suppliers

Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
15719
Advantage
55
J & K SCIENTIFIC LTD.
Tel
400-666-7788 +86-10-82848833
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3579
Advantage
66
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30163
Advantage
84
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 qq:2355568890
Fax
0086-21-50182339
Email
sales@demochem.com; export1@demochem.com
Country
China
ProdList
2585
Advantage
57
BeiJing Hwrk Chemicals Limted
Tel
4006990298;010-57411839;0757-86311057;021-51691807
Fax
010-87653215;0757-86311057;021-55236763
Email
sales@hwrkchemical.com
Country
China
ProdList
14684
Advantage
55
Energy Chemical
Tel
021-58432009 / 400-005-6266
Fax
021-58436166-800
Email
info@energy-chemical.com
Country
China
ProdList
44025
Advantage
61
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078,021-50426030
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
10011
Advantage
60
Beijing VSciChem Technology Co., Ltd.
Tel
010-52483976 13811761079
Fax
010-60270130
Email
vscichem@163.com
Country
China
ProdList
234
Advantage
64
Chemfun Medical Technology(Shanghai) Co., Ltd.
Tel
021-67220633 & 021-37212706
Fax
+86-21-67220638
Email
chemfun@chemfun.net
Country
China
ProdList
21812
Advantage
59
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View Lastest Price from Phenyl phosphine manufacturers

career henan chemical co
Product
Phenyl phosphine 638-21-1
Price
US $1.00/KG
Min. Order
1G
Purity
99%
Supply Ability
100kg
Release date
2018-08-12

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