ChemicalBook > CAS DataBase List > 1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane

Product Name
1,3-Bis(diphenylphosphino)propane
CAS No.
6737-42-4
Chemical Name
1,3-Bis(diphenylphosphino)propane
Synonyms
DPPP;1,3-bis(diphenyphosphino)propane;Bis(1,3-diphenylphosphino)propane;1,3-BIS(DIPHENYLPHOSPHINE)PROPANE;98% DPPP;1,3-Bis(diphenyL;phosphino)propane;PH2PCH2 CH2CH2PPH2;1,3-BIS(DIPHENYPHOSPHINO);1,3-bis-(diphosphino)propane
CBNumber
CB4132404
Molecular Formula
C27H26P2
Formula Weight
412.45
MOL File
6737-42-4.mol
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1,3-Bis(diphenylphosphino)propane Property

Melting point:
63-65 °C (lit.)
Boiling point:
529.7±33.0 °C(Predicted)
Flash point:
235°C
storage temp. 
Inert atmosphere,Room Temperature
form 
Granules or Powder
color 
White to light yellow-beige
Water Solubility 
insoluble
Sensitive 
Air Sensitive
BRN 
2821785
InChI
InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChIKey
LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES
P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
CAS DataBase Reference
6737-42-4(CAS DataBase Reference)
NIST Chemistry Reference
1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPA Substance Registry System
Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39-36
WGK Germany 
3
10-23
TSCA 
Yes
HS Code 
29310095
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
262048
Product name
1,3-Bis(diphenylphosphino)propane
Purity
97%
Packaging
1g
Price
$35.4
Updated
2024/03/01
Sigma-Aldrich
Product number
262048
Product name
1,3-Bis(diphenylphosphino)propane
Purity
97%
Packaging
5g
Price
$65.3
Updated
2024/03/01
TCI Chemical
Product number
B1138
Product name
1,3-Bis(diphenylphosphino)propane
Purity
>98.0%(GC)
Packaging
5g
Price
$34
Updated
2024/03/01
TCI Chemical
Product number
B1138
Product name
1,3-Bis(diphenylphosphino)propane
Purity
>98.0%(GC)
Packaging
25g
Price
$79
Updated
2024/03/01
Alfa Aesar
Product number
A12931
Product name
1,3-Bis(diphenylphosphino)propane, 97%
Packaging
5g
Price
$76.9
Updated
2024/03/01
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1,3-Bis(diphenylphosphino)propane Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

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1,3-Bis(diphenylphosphino)propane Suppliers

Puyang Huicheng Electronic Material Co. Ltd.
Tel
0393-0393-8910800 18339358320
Fax
0393-8912775
Email
info@huichengchem.com
Country
China
ProdList
544
Advantage
64
Chongqing Xingcan Pharmaceutical Technology Co., Ltd.
Tel
15523000485
Email
xingcanyaoye@sina.com
Country
China
ProdList
1788
Advantage
58
Entegris, Inc.
Tel
021-52980362 18121213678
Email
jenny.ji@entegris.com
Country
China
ProdList
101
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
Advantage
66
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1998
Advantage
65
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
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View Lastest Price from 1,3-Bis(diphenylphosphino)propane manufacturers

Shanghai UCHEM Inc.
Product
1,3-Bis(diphenylphosphino)propane 6737-42-4
Price
US $10.00-178.00/g
Min. Order
25g
Purity
0.98
Supply Ability
100kg
Release date
2023-10-20
Hebei Yanxi Chemical Co., Ltd.
Product
1,3-Bis(diphenylphosphino)propane 6737-42-4
Price
US $30.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-10
WUHAN FORTUNA CHEMICAL CO., LTD
Product
1,3-Bis(diphenylphosphino)propane 6737-42-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-06

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