Diphenylphosphinic acid

Product Name: Diphenylphosphinic acid
CAS No.: 1707-03-5
Chemical Name: Diphenylphosphinic acid
Synonyms: Diphenylphosphine acid;GC-DPPO，DPPO;AURORA KA-1519;iphenylphosphinicaci;DIPHENYLPHOSPHINICACID;DIPHENYLPHOSPINIC ACID;diphenyl-phosphinicaci;DIPHENYLPHOSPHONIC ACID;DIPHENYLPHOSPHINIC ACID;DiphenylphosphinicAcid>
CBNumber: CB1181911
Molecular Formula: C12H11O2P
Formula Weight: 218.19
MOL File: 1707-03-5.mol

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Diphenylphosphinic acid Property

Melting point:: 193-195 °C(lit.)
Boiling point:: 194 °C
Density: 1.25±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: 0.1 M NaOH: soluble0.5g/10 mL, clear, colorless
pka: 2.30±0.10(Predicted)
form: Fine Crystalline Solid
color: White
Water Solubility: Soluble in water.
BRN: 2804567
CAS DataBase Reference: 1707-03-5(CAS DataBase Reference)
NIST Chemistry Reference: Diphenyl phosphinic acid(1707-03-5)

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Safety

Risk Statements: 36/37/38
Safety Statements: 22-24/25
WGK Germany: 3
RTECS: SZ5315000
HS Code: 29310095

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 43153
Product name: Diphenylphosphinic acid
Purity: ≥98.0% (T)
Packaging: 5g
Price: $47.2
Updated: 2024/03/01

TCI Chemical

Product number: D3627
Product name: Diphenylphosphinic Acid
Purity: >98.0%(HPLC)(T)
Packaging: 5g
Price: $33
Updated: 2024/03/01

TCI Chemical

Product number: D3627
Product name: Diphenylphosphinic Acid
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $112
Updated: 2024/03/01

Alfa Aesar

Product number: A11563
Product name: Diphenylphosphinic acid, 99%
Packaging: 5g
Price: $38.65
Updated: 2024/03/01

Alfa Aesar

Product number: A11563
Product name: Diphenylphosphinic acid, 99%
Packaging: 25g
Price: $115.65
Updated: 2024/03/01

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Diphenylphosphinic acid Chemical Properties,Usage,Production

Chemical Properties

white fine crystalline solid

Uses

Diphenylphosphinic acid is used as a reagent employed in the synthesis of bidentate ligands and peptide coupling agents.

Definition

ChEBI: Diphenylphosphinic acid is a member of phosphinic acids.

Synthesis Reference(s)

The Journal of Organic Chemistry, 22, p. 1671, 1957 DOI: 10.1021/jo01363a037

General Description

Diphenylphosphinic acid (DPPA, hdpp) is an organophosphinic acid compound. It finds application as a reactive flame-retardant and promoter for palladium catalytic systems. Thermal degradation of DPPA has been studied by thermogravimetric analysis (TGA) method. DPPA reacts with cadmium nitrate in dimethylformamide solvent to afford the one-dimensional coordination polymer catena-poly[[bis(dimethylformamide-κO)cadmium(II)]-bis(μ-diphenylphosphinato-κ(2)O:O′)]. It has been repoted to promote the carbonylation of nitrobenzene and aniline to diphenylurea. Ortho-lithiated DPPA can form mono ortho-functionalized derivatives by electrophilic trapping and biphenyl-2,2′-diylbis(phenylphosphinic acid) by copper catalyzed coupling.

Purification Methods

Recrystallise it from 95% EtOH and dry it under vacuum at room temperature. [see Kosolapoff Organophosphorus Compounds J Wiley, NY, 1950, Kosolapoff and Maier Organic Phosphorus Compounds Wiley-Interscience, NY, 1972-1976, Beilstein 16 IV 1036.]

Diphenylphosphinic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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Diphenylphosphinic acid Suppliers

Americas 1 Austria 1 Belgium 1 Canada 1 China 243 Europe 3 France 1 Germany 6 India 6 Japan 5 South Korea 1 Switzerland 3 Turkey 1 United Kingdom 12 United States 27 Global 312

Shijiazhuang Benchu Technology Co., Ltd.

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BEIJING ODYSSEY CHEMICALS CO.,LTD

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Qingdao Yuqing Chemical Technology Co.,Ltd

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Shanghai Boyle Chemical Co., Ltd.

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INTATRADE GmbH

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3B Pharmachem (Wuhan) International Co.,Ltd.

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View Lastest Price from Diphenylphosphinic acid manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Diphenylphosphinic acid 1707-03-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-08

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Diphenylphosphinic Acid 1707-03-5
Price: US $120.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-30

Hebei Chuanghai Biotechnology Co,.LTD

Product: Diphenylphosphinic acid 1707-03-5
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-21

1707-03-5, Diphenylphosphinic acidRelated Search:

Ethyl 2-(Chlorosulfonyl)acetate Diphenylphosphine Chlorodiphenylphosphine Phenylphosphonic acid Diphenylphosphine oxide Stearic acid 1,3-Diphenyl-2-thiourea 1,5-Diphenylcarbazide Folic acid Citric acid 3,4'-DIAMINODIPHENYLMETHANE Diphenylsilane tert-Butylchlorodiphenylsilane Diphenylmethane Diphenyl-2-pyridylphosphine Cyclohexyldiphenylphosphine Ascoric Acid 1,3-Bis(diphenylphosphino)propane

AURORA KA-1519

DIPHENYLPHOSPINIC ACID

DIPHENYLPHOSPHINIC ACID

DIPHENYLPHOSPHONIC ACID

diphenyl-phosphinicaci

Hydroxydiphenylphosphine oxide

Phosphinic acid, diphenyl-

Diphenylphosphine acid

DIPHENYLPHOSPHINICACID

Diphenylphosphinic acid,99%

Bis(phenyl)phosphinic acid

GC-DPPO，DPPO

DiphenylphosphinicAcid&gt

Phosphinic acid, P,P-diphenyl-

iphenylphosphinicaci

1707-03-5

C6H52POOH

C12H11O2P

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