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Perfluoro-1-iodohexane

Product Name
Perfluoro-1-iodohexane
CAS No.
355-43-1
Chemical Name
Perfluoro-1-iodohexane
Synonyms
PERFLUOROHEXYL IODIDE;1,1,1,2,2,3,3,4,4,5,5,6,6-TRIDECAFLUORO-6-IODOHEXANE;Perfluorohexyl iodine;TRIDECAFLUORO-1-IODOHEXANE;TI-6;C1014NH5;uorohexyL;TridecafL;1-IODOPERFLUOROHEXANE;PERFLUORO-1-IODOHEXANE
CBNumber
CB1675643
Molecular Formula
C6F13I
Formula Weight
445.95
MOL File
355-43-1.mol
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Perfluoro-1-iodohexane Property

Melting point:
-45 °C
Boiling point:
117 °C(lit.)
Density 
2.063 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.329(lit.)
Flash point:
117°C
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Oil
color 
Pale Pink
Specific Gravity
2.063
Water Solubility 
insoluble
Sensitive 
Light Sensitive
BRN 
1802118
Stability:
Stable.
InChIKey
BULLJMKUVKYZDJ-UHFFFAOYSA-N
CAS DataBase Reference
355-43-1(CAS DataBase Reference)
NIST Chemistry Reference
Perfluorohexyl iodide(355-43-1)
EPA Substance Registry System
Hexane, 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-6-iodo- (355-43-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
23-24/25-37/39-26-37
RIDADR 
2810
WGK Germany 
3
8
Hazard Note 
Irritant
TSCA 
T
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29034700
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
262145
Product name
Perfluorohexyl iodide
Purity
99%
Packaging
5g
Price
$22.26
Updated
2024/03/01
Sigma-Aldrich
Product number
262145
Product name
Perfluorohexyl iodide
Purity
99%
Packaging
25g
Price
$90.6
Updated
2024/03/01
TCI Chemical
Product number
T1098
Product name
Tridecafluorohexyl Iodide
Purity
>98.0%(GC)
Packaging
5g
Price
$24
Updated
2024/03/01
TCI Chemical
Product number
T1098
Product name
Tridecafluorohexyl Iodide
Purity
>98.0%(GC)
Packaging
25g
Price
$79
Updated
2024/03/01
Alfa Aesar
Product number
B20958
Product name
Perfluoro-1-iodohexane, 98+%, stab. with copper
Packaging
10g
Price
$38.65
Updated
2024/03/01
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Perfluoro-1-iodohexane Chemical Properties,Usage,Production

Chemical Properties

liquid

Uses

Perfluorohexyl Iodide is an important intermediate in the synthesis of organic fluorides products. It also exhibits estrogenic activity in vitro. Perfluorohexyl Iodide is used in the screening assay for binding affinities of perfluoroalkyl iodide for estrogen receptor alpha and beta isoforms.

General Description

Perfluorohexyl iodide forms 1:1 complexes with a variety of hydrogen-bond acceptors. It has been grafted onto the isocitronellene/propene copolymer by radical reaction yielding a poly(α-olefin) with fluorinated side chains. The radical addition of perfluorohexyl iodide to vinyl acetate, using azo-bis( isobutyronitrile) (AIBN) as an initiator, has been investigated.

Safety Profile

Explodes in contact with sodium when heated to the boiling point of the iodide. When heated to decomposition it emits toxic fumes of Fí and Ií.

Synthesis

To an autoclave (stainless steel, volume:1L) equipped with a mixing tank and a stirrer, C4F9I which compound (1) flow rate 25mL/min, CF2=CF2 (tetrafluoroethylene) which compound (2) flow rate 0.37g/min, (C2F5COO)2 (10 and half hour life temperature: 31°C) which compound (4) flow rate 0.052 mmol/min were supplied, the mixture was prepared by mixing at stirrer. Temperature in the autoclave was 10°C, residence time of the mixture in the autoclave was 10 minutes. The molar ratio (C4F9I/CF2=CF2)of C4F9I and CF2=CF2 in the mixed solution was 41, the amount of (C2F5COO)2 with respect to C4F9I was 0.034 mol%. Only the mixture from the bottom of the autoclave was withdrawn in the absence of gas phase, the mixture was fed to the bottom of tubular reactor (Tankan-shiki, volume: 0.5L). The mixture was not seperated by gas-liquid separation, the mixture was flow towards the outlet from the inlet of the reaction tube in the tube reactor. The temperature of the reaction tube, and a 70°C, the residence time of the mixture in the tubular reactor was set to 20 minutes. The mixture containing a compound Perfluoro-1-iodohexane C6F13I was obtained.

Perfluoro-1-iodohexane Preparation Products And Raw materials

Raw materials

Preparation Products

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Perfluoro-1-iodohexane Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
AGC Chemicals
Tel
--
Fax
--
Country
Japan
ProdList
66
Advantage
58
Daikin Industries Ltd.
Tel
--
Fax
--
Email
norio.nagahama@daikin.co.jp
Country
Japan
ProdList
46
Advantage
58
Daikin Chemicals Sales, Ltd.
Tel
--
Fax
--
Country
Japan
ProdList
300
Advantage
55
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
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View Lastest Price from Perfluoro-1-iodohexane manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Perfluoro-1-iodohexane 355-43-1
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-21
Shaanxi Dideu Medichem Co. Ltd
Product
Perfluoro-1-iodohexane 355-43-1
Price
US $1.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
20T
Release date
2024-06-11
Wuhan Silworld Chemical Co.,Ltd
Product
Perfluoro-1-iodohexane 355-43-1
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000
Release date
2023-04-28

355-43-1, Perfluoro-1-iodohexaneRelated Search:


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