5-Bromo-2-chlorophenol

Product Name: 5-Bromo-2-chlorophenol
CAS No.: 183802-98-4
Chemical Name: 5-Bromo-2-chlorophenol
Synonyms: 5-Bromo-2-chlorophen;2-ch1oro-5-bromophenol;2-chloro-5-bromophenol;5-BROMO-2-CHLOROPHENOL;Phenol, 5-bromo-2-chloro-;5-Bromo-2-chlorophenol >5-bromo-2-chlorophenol 98%;5-Bromo-2-chlorophenol ,97%;5-Bromo-2-chlorophenol, 98+%
CBNumber: CB1695740
Molecular Formula: C6H4BrClO
Formula Weight: 207.45
MOL File: 183802-98-4.mol

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5-Bromo-2-chlorophenol Property

Melting point:: 46-47
Boiling point:: 234°C(lit.)
Density: 1.788±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: powder to crystal
pka: 7.53±0.10(Predicted)
color: White to Light yellow to Light orange
InChI: InChI=1S/C6H4BrClO/c7-4-1-2-5(8)6(9)3-4/h1-3,9H
InChIKey: UEVFFMZHGNYDKM-UHFFFAOYSA-N
SMILES: C1(O)=CC(Br)=CC=C1Cl
CAS DataBase Reference: 183802-98-4(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-36/37/39-36/37
Hazard Note: Corrosive
HS Code: 29089990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical

Product number: B2919
Product name: 5-Bromo-2-chlorophenol
Purity: >98.0%(GC)
Packaging: 1g
Price: $67
Updated: 2025/07/31

TCI Chemical

Product number: B2919
Product name: 5-Bromo-2-chlorophenol
Purity: >98.0%(GC)
Packaging: 5g
Price: $201
Updated: 2025/07/31

TRC

Product number: B684168
Product name: 5-Bromo-2-chlorophenol
Packaging: 1g
Price: $75
Updated: 2021/12/16

TRC

Product number: B684168
Product name: 5-Bromo-2-chlorophenol
Packaging: 250mg
Price: $55
Updated: 2021/12/16

Matrix Scientific

Product number: 118881
Product name: 5-Bromo-2-chlorophenol
Purity: 98%
Packaging: 1g
Price: $14
Updated: 2021/12/16

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5-Bromo-2-chlorophenol Chemical Properties,Usage,Production

Chemical Properties

Light yellow to White crystals

Synthesis

16817-43-9

183802-98-4

General procedure for the synthesis of 5-bromo-2-chlorophenol from 5-bromo-2-chloroanisole: BBr3 (8.2 mL, 84.9 mmol) was slowly added dropwise to a solution of 5-bromo-2-chloroanisole (18.26 g, 82.4 mmol) in dichloromethane (45 mL) under stirring conditions at 0-5 °C. The reaction mixture was stirred continuously for 4 hours at room temperature. Upon completion of the reaction, the mixture was carefully poured into a pre-cooled 2N NaOH/ice mixture and washed twice with tert-butyl methyl ether (TBME). The aqueous phase was acidified with 2N HCl to a suitable pH and then extracted again with TBME twice. All organic phases were combined and dried with anhydrous Na2SO4, followed by evaporation of the solvent under reduced pressure to afford the target product 5-bromo-2-chlorophenol as colorless crystals (16.35 g, 95% yield). The product was confirmed by 1H-NMR (400 MHz, DMSO-d6) and mass spectrometry (ES+) analysis: 1H-NMR δ (ppm): 6.97 (dd, 1H), 7.09 (d, 1H), 7.26 (d, 1H), 10.65 (bs, 1H, OH); MS (m/z) ES+: 210 (15), 208 (70, M+) , 206 (50), 179 (20), 177 (15), 63 (100).

References

[1] Patent: WO2007/91152, 2007, A1. Location in patent: Page/Page column 43
[2] Patent: US2006/25349, 2006, A1. Location in patent: Page/Page column 17
[3] Patent: US2006/35841, 2006, A1. Location in patent: Page/Page column 18
[4] Patent: WO2005/103054, 2005, A2. Location in patent: Page/Page column 158-159
[5] Patent: WO2003/105853, 2003, A1. Location in patent: Page 57

5-Bromo-2-chlorophenol Preparation Products And Raw materials

Raw materials

Preparation Products

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5-Bromo-2-chlorophenol Suppliers

Americas 1 China 159 Europe 1 Germany 4 India 8 Japan 1 The Netherlands 1 United Kingdom 7 United States 19 Global 201

HBCChem, Inc.

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View Lastest Price from 5-Bromo-2-chlorophenol manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 5-Bromo-2-chlorophenol 183802-98-4
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-12-03

Hebei Chuanghai Biotechnology Co,.LTD

Product: 5-Bromo-2-chlorophenol 183802-98-4
Price: US $1.90/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 ton
Release date: 2024-08-20

Career Henan Chemical Co

Product: 5-Bromo-2-chlorophenol 183802-98-4
Price: US $2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: Customise
Release date: 2018-08-09

183802-98-4, 5-Bromo-2-chlorophenolRelated Search:

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5-Bromo-2-chlorophen

183802-98-4

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Bromine Compounds

Chlorine Compounds

Phenols