1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE
- Product Name
- 1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE
- CAS No.
- 98577-44-7
- Chemical Name
- 1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE
- Synonyms
- EOS-60772;AKOS BBS-00001998;1,1-Dibromo-2,2-bis(chL;1,1-BIS(CHLOROMETHYL)-2,2-DIBROMOCYCLOPROPANE;1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE;2,2-Bis-(chloromethyl)-1,1-dibromocyclopropane;Cyclopropane,1,1-dibroMo-2,2-bis(chloroMethyl)-;1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)-CYCLOP ROPANE, TECH., 90%;1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE ISO 9001：2015 REACH;1,1-DibroMo-2,2-bis(chloroMethyl)cyclopropane 90%, technical grade
- CBNumber
- CB1717239
- Molecular Formula
- C5H6Br2Cl2
- Formula Weight
- 296.82
- MOL File
- 98577-44-7.mol
1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE Property
- Melting point:
- 48-50 °C (lit.)
- Boiling point:
- 277.1±10.0 °C(Predicted)
- Density
- 2.065±0.06 g/cm3 (20 ºC 760 Torr)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- powder to crystal
- color
- White to Orange to Green
- InChI
- InChI=1S/C5H6Br2Cl2/c6-5(7)1-4(5,2-8)3-9/h1-3H2
- InChIKey
- RCRVZCIUKQNOIS-UHFFFAOYSA-N
- SMILES
- C1(Br)(Br)CC1(CCl)CCl
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 393665
- Product name
- 1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane
- Purity
- 90%, technical grade
- Packaging
- 10g
- Price
- $242
- Updated
- 2024/03/01
- Product number
- 393665
- Product name
- 1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane
- Purity
- 90%, technical grade
- Packaging
- 100g
- Price
- $896
- Updated
- 2024/03/01
- Product number
- D5290
- Product name
- 1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane
- Purity
- >96.0%(GC)
- Packaging
- 1g
- Price
- $29
- Updated
- 2024/03/01
- Product number
- D5290
- Product name
- 1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane
- Purity
- >96.0%(GC)
- Packaging
- 5g
- Price
- $85
- Updated
- 2024/03/01
- Product number
- B426238
- Product name
- 1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane
- Packaging
- 50g
- Price
- $315
- Updated
- 2021/12/16
1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE Chemical Properties,Usage,Production
Uses
1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane may be used as a starting material in the synthesis of [1.1.1]-propellane and ((3-ethynylbicyclo[1.1.1]pentan-1-yl)ethynyl)trimethylsilane.
Preparation
1000 ml 1,1-bis(chloromethyl)-2,2-dibromocyclopropane was added to a vigorously stirred mixture within 10-15 min, which contains bromoform (370 ml, 4.24 mol), 3-chloro-2-chloromethyl-1-propane (250 g, 2.0 mol), 10 g benzyltriethylammonium chloride, 8 ml ethanol and 200 ml methylene chloride . The temperature was maintained between 25°-35° C. After overnight stirring, 500 ml methylene chloride was added and the thick black mixture was allowed to separate into layers. The top aqueous layer was removed and the bottom layer was gently washed with water (500 ml). 500 ml water was then added and well shaken. Separated the organic phase, treated the residual emulsion with solid sodium chloride and filtered through Celite. All aqueous layers were washed with methylene chloride. The organic extracts were combined, dried over magnesium sulfate, and filtered through Celite. Concentration and vacuum distillation gave the mixture of starting material and black-brown residue which was distilled on a Kugel-Rohr giving semicrystalline fraction containing the product. Crystallization from 400 ml of pentane from a dry ice-acetone bath gave the white wet crystals. The crude product was dissolved in 400 ml of penfane, then 7.5 g silica gel was added. Filtered and low temperature recrystallized again. Finally, obtain the product (1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE )
General Description
1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane is a halogenated cyclopropane derivative. It has been reported to be synthesized from 3-chloro-2-(chloromethyl)-1-propene. It is formed as an intermediate during the synthesis of [1.1.1]propellane by Szeimies method.
1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE manufacturers
- Product
- 1,1-DIBROMO-2,2-BIS(CHLOROMETHYL)CYCLOPROPANE 98577-44-7
- Price
- US $101.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-28
- Product
- 1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane 90%, technical grade 98577-44-7
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- 1,1-dibromo-2,2-bis(chloromethyl)cyclopropane 98577-44-7
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000 tons
- Release date
- 2020-01-13