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cis-3-Hexenyl Acetate

Product Name
cis-3-Hexenyl Acetate
CAS No.
3681-71-8
Chemical Name
cis-3-Hexenyl Acetate
Synonyms
(Z)-3-HEXENYL ACETATE;LEAF ACETATE;cis-3-Hexenyl;(Z)-hex-3-en-1-yl acetate;Hexenyl acetate;(Z)-Hex-3-enyl acetate;CIS-3-HEXEN-1-YL ACETATE;(Z)-3-hexen-1-ol acetate;(Z)-3-hexenol acetate;(3Z)-hex-3-en-1-yl acetate
CBNumber
CB1727292
Molecular Formula
C8H14O2
Formula Weight
142.2
MOL File
3681-71-8.mol
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cis-3-Hexenyl Acetate Property

Boiling point:
75-76 °C23 mm Hg(lit.)
Density 
0.897 g/mL at 25 °C(lit.)
vapor pressure 
2.14hPa at 25℃
refractive index 
n20/D 1.427(lit.)
FEMA 
3171 | CIS-3-HEXEN-1-YL ACETATE
Flash point:
135 °F
storage temp. 
Inert atmosphere,Room Temperature
color 
Colorless to Almost colorless
Odor
at 10.00 % in dipropylene glycol. fresh green sweet fruity banana apple grassy
Odor Type
green
Water Solubility 
1.11g/L at 20℃
JECFA Number
134
BRN 
1721854
LogP
2.7 at 30℃
CAS DataBase Reference
3681-71-8(CAS DataBase Reference)
NIST Chemistry Reference
3-Hexen-1-ol, acetate, (Z)-(3681-71-8)
EPA Substance Registry System
3-Hexen-1-ol, acetate, (3Z)- (3681-71-8)
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Safety

Risk Statements 
36/38-10
Safety Statements 
26-36-24/25
RIDADR 
UN 3272 3/PG 3
WGK Germany 
2
RTECS 
MP8425050
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29153900
Toxicity
Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Wohl, 1974).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W317101
Product name
cis-3-Hexenyl Acetate
Purity
≥98%, stabilized, FCC, FG
Packaging
200g
Price
$99.5
Updated
2024/03/01
Sigma-Aldrich
Product number
W317101
Product name
cis-3-Hexenyl Acetate
Purity
≥98%, stabilized, FCC, FG
Packaging
1kg
Price
$255
Updated
2024/03/01
Sigma-Aldrich
Product number
W317100
Product name
cis-3-Hexenyl Acetate
Purity
natural, ≥95%, FG
Packaging
sample-k
Price
$62.2
Updated
2024/03/01
Sigma-Aldrich
Product number
W317100
Product name
cis-3-Hexenyl Acetate
Purity
natural, ≥95%, FG
Packaging
100g
Price
$193
Updated
2024/03/01
Sigma-Aldrich
Product number
W317100
Product name
cis-3-Hexenyl Acetate
Purity
natural, ≥95%, FG
Packaging
1kg
Price
$1290
Updated
2024/03/01
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cis-3-Hexenyl Acetate Chemical Properties,Usage,Production

Description

cis-3-Hexen-1 -y 1-acetate has a powerful green, floral note reminiscent of banana. It may be prepared by acetylation of the corresponding alcohol.

Chemical Properties

Colorless liquid

Chemical Properties

(Z)-3-Hexenyl Acetate has been identified in many fruit aromas and green tea. It is a prototype for green odors and is often used in combination with (Z)-3-hexenol.

Chemical Properties

cis-3-Hexen-1-yl acetate has a powerful, green, fruity, floral note reminiscent of banana.

Occurrence

Reported found in apple, bilberry, guava, strawberry, black and green tea, yellow and purple passion fruit, citrus peel oils, melon, peach, raspberry, pear, pineapple, melon, celery, tomato, corn mint oil, spearmint oil, brandies, grape wines, soybeans, olive, plum, plumcot, starfruit, mango, cauliflower, dill, lovage, corn oil, nectarines, Chinese quince and chamomile oil.

Uses

Leaf Acetate increased leaf-feeding herbivores’ egg predation rates by a generalist predator. As a consequence, a plant could reduce the number of herbivores by more than 90% by releasing volatiles.

Preparation

By acetylation of the corresponding alcohol

Definition

ChEBI: An acetate ester that results from the formal condensation of acetic acid with (Z)-hex-3-en-1-ol.
In dilutions below 10 ppm, it produces very pleasant fruity-green flavours, and its taste individually at concentrations below 2 ppm is distinctly Banana-1ike. Very interesting combination flavors can be created with this ester and a few other chemicals: A concentration of about 1 ppm of cis-3-Hexenyl acetate in the presence of 0.05 ppm Allyl-iso-thiocyanate (Allyl mustard oil) will produce a distinct note of unripe Banana with the sharp greenness and the fruity notes unmistakably identifiable as Banana and absolutely no impression of Mustard. The two materials separately at the concentrations indicated give very weak and incomplete flavor pictures. However, this ester finds considerable use in perfumes, where it may lend pleasant and natural freshness to delicate florals (Muguet, Lilac, Narcisse, etc.) and participate in creating true-to-nature, foliage-green topnotes in other fragrance types. The ester is most likely to supersede the less stable and less natural-smelling Alkyl acetylenic esters, slowly being abandoned in modern perfumery.

Taste threshold values

Taste characteristics at 10 ppm: green, fruity, apple and pear with fresh tropical nuances

Synthesis Reference(s)

Canadian Journal of Chemistry, 65, p. 2327, 1987 DOI: 10.1139/v87-388

Flammability and Explosibility

Flammable

cis-3-Hexenyl Acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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cis-3-Hexenyl Acetate Suppliers

Americas 1 Australia 1 Brazil 1 Canada 1 China 239 Europe 3 France 3 Germany 6 India 68 Israel 2 Italy 1 Japan 5 Mexico 1 Singapore 2 Slovakia 1 South Africa 1 Spain 2 Switzerland 4 Ukraine 1 United Kingdom 9 United States 65 USA 1 Global 418
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View Lastest Price from cis-3-Hexenyl Acetate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Cis-3-Hexenyl Acetate 3681-71-8
Price
US $75.00-20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-29
WUHAN FORTUNA CHEMICAL CO., LTD
Product
cis-3-Hexenyl Acetate 3681-71-8
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
98%min
Supply Ability
500kg
Release date
2021-07-01
Hebei Weibang Biotechnology Co., Ltd
Product
cis-3-Hexenyl Acetate 3681-71-8
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100 mt
Release date
2024-11-21

3681-71-8, cis-3-Hexenyl AcetateRelated Search:

PHENYL ACETATE Ammonium acetate Magnesium acetate Ethyl acetate Vinyl acetate Benzyl acetate Cellulose acetate POLY(VINYL ACETATE) 2,2,4-Trimethyl-1,3-pentanediol monoisobutyrate Isobornyl acetate Amyl acetate Propyleneglycol alginate Diphenolic acid Isopropyl acetate Sodium acetate CIS-3-HEXENYL SALICYLATE Allyl phenoxyacetate Citronellyl acetate cis-3-Hexenyl acetate

  • Zinc05225119
  • Leaf Acetate or CIS-3-Hexenyl Acetate
  • cis-3-Hexenyl acetate,(3Z)-C-3-Hexenyl acetate, 3-Hexen-1-ol, Leaf acetate
  • VERDURAL
  • (Z)-3-HEXENYL ACETATE
  • Hexenyl acetate
  • CIS-3-HEXENYL ACETATE 98+% FCC
  • Leaf Acetate or CIS-3-Hexenyl Acetate 98%
  • CIS-3-Hexenyl Acetate 98%
  • cis-3-Hexenyl
  • Leaf acetate cis-3-Hexenyl acetate
  • Z-3-hexenyl-1-acetate
  • <i>cis</i>-3-Hexenyl acetate
  • HEX-3(CIS)-ENYL ACETATE
  • FEMA 3171
  • LEAF ACETATE
  • CIS-3-HEXEN-1-YL ACETATE
  • CIS-3-HEXENYL ACETATE
  • C3 HEXENYL ACETATE
  • cis-3-hexenolacetate
  • cis-3-Hexenyl-1-Acetate
  • cis-3-hexenylethanoate
  • cis-hex-3-enyl acetate
  • Hex-3(Z)-enyl acetate
  • Verduralextra
  • Cis-3-Hexene-1-Yl Acetate
  • Cis-3-HexeneylAcetate
  • cis-3-Hexenylacetate,99%
  • hexenylacetate,(Z)-3-hexenylacetate
  • 3-Hexen-1-ol, acetate, (3Z)-
  • (3z)-c-3-hexenyl acetate
  • cis-3-Hexenyl acetate Odor Standard
  • (Z)-Hex-3-enylacetat
  • 3-Hexen-1-ol, 1-acetate, (3Z)-
  • ACETIC ACID CIS-3-HEXEN-1-YL ESTER
  • ACETIC ACID CIS-3-HEXENYL ESTER
  • (3Z)-3-Hexenyl acetate
  • (Z)-3-hexen-1-ol acetate
  • (Z)-3-Hexen-1-yl, acetate
  • (Z)-3-hexenol acetate
  • (Z)-hex-3-en-1-yl acetate
  • (Z)-Hex-3-enyl acetate
  • 3(Z)-hexenyl acetate
  • 3-Hexen-1-ol,acetate,(Z)-
  • 3-Hexenol acetate, cis
  • 3-hexenylacetate
  • acetate,(z)-3-hexen-1-o
  • acetate,(Z)-3-Hexen-1-ol
  • HEXENYLACETAT-CIS-3
  • CIS-3-HEXENYL ACETATE, NATURAL
  • (3Z)-C-3-Hexenyl acetate, 3-Hexen-1-ol, Leaf acetate
  • Acetic acid (Z)-3-hexen-1-yl ester
  • Acetic acid (Z)-3-hexenyl ester
  • Acetic acid [(Z)-3-hexenyl] ester
  • Leaf Acetate or CIS-III-Hexenyl Acetate 98%
  • (3Z)-hex-3-en-1-yl acetate
  • cis-3-HEXENYL ACETATE FCC
  • CIS-3-HEXENYL CPROATE