4-Methylbenzyl chloride

Product Name: 4-Methylbenzyl chloride
CAS No.: 104-82-5
Chemical Name: 4-Methylbenzyl chloride
Synonyms: 1-(Chloromethyl)-4-methylbenzene;MBC;P-XYLYL CHLORIDE;P-METHYLBENZYL CHLORIDE;PXCL1;pha-ChL;oro-p-xyL;4-Xylyl chloride;A-CHLORO-P-XYLENE;AKOS BBS-00003956
CBNumber: CB1735857
Molecular Formula: C8H9Cl
Formula Weight: 140.61
MOL File: 104-82-5.mol

More

Less

4-Methylbenzyl chloride Property

Melting point:: 4 °C(lit.)
Boiling point:: 200 °C(lit.)
Density: 1.062 g/mL at 25 °C(lit.)
refractive index: n20/D 1.533(lit.)
Flash point:: 168 °F
storage temp.: 2-8°C
form: Low Melting Solid or Liquid
color: Colorless to white to yellow
Water Solubility: Insoluble
Sensitive: Lachrymatory
Merck: 14,10091
BRN: 507387
InChI: 1S/C8H9Cl/c1-7-2-4-8(6-9)5-3-7/h2-5H,6H2,1H3
InChIKey: DMHZDOTYAVHSEH-UHFFFAOYSA-N
SMILES: Cc1ccc(CCl)cc1
CAS DataBase Reference: 104-82-5(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-(chloromethyl)-4-methyl-(104-82-5)
EPA Substance Registry System: Benzene, 1-(chloromethyl)-4-methyl- (104-82-5)

More

Less

Safety

Hazard Codes: C,Xi
Risk Statements: 34-36/37/38-22
Safety Statements: 26-27-36/37/39-45-37/39
RIDADR: UN 2922 8/PG 3
WGK Germany: 1
RTECS: ZE4030000
F: 19
Hazard Note: Harmful/Corrosive/Lachrymatory
TSCA: TSCA listed
HazardClass: 8
PackingGroup: III
HS Code: 29036990
Storage Class: 8A - Combustible corrosive hazardous materials
Hazard Classifications: Acute Tox. 4 Oral
Skin Corr. 1B
Hazardous Substances Data: 104-82-5(Hazardous Substances Data)

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: C73400
Product name: 4-Methylbenzyl chloride
Purity: 98%
Packaging: 5g
Price: $47.2
Updated: 2025/07/31

Sigma-Aldrich

Product number: C73400
Product name: 4-Methylbenzyl chloride
Purity: 98%
Packaging: 100g
Price: $81.3
Updated: 2025/07/31

TCI Chemical

Product number: C0312
Product name: α-Chloro-p-xylene
Packaging: 25G
Price: $25
Updated: 2025/07/31

TCI Chemical

Product number: C0312
Product name: α-Chloro-p-xylene
Packaging: 500G
Price: $96
Updated: 2025/07/31

TRC

Product number: C369770
Product name: α-Chloro-p-methyltoluene
Packaging: 25g
Price: $150
Updated: 2021/12/16

More

Less

4-Methylbenzyl chloride Chemical Properties,Usage,Production

Chemical Properties

clear colourless to light yellow liquid

Uses

α-Chloro-p-methyltoluene-13C is the labeled analogue of α-Chloro-p-methyltoluene(C369770). α-Chloro-p-methyltoluene is a building block that has been used as a reactant for the preparation of 6-aminoquinolone derivatives as submicromolar hepatitis C virus NS5B inhibitors

Synthesis

The main process for the industrial production of 4-methylbenzyl chloride is currently based on 3-hydroxybenzaldehyde as raw material, and the target product is obtained by methylation with dimethyl sulfate, reduction with potassium borohydride or hydrogenation, and chlorination with alum chloride or concentrated hydrochloric acid.

Purification Methods

Dry the chloride with CaSO4 and fractionally distil it under vacuum. [Beilstein 5 H 384, 5 III 854, 5 IV 966.]

4-Methylbenzyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

α-phenyl-2-p-tolylethylamine

More

Less

4-Methylbenzyl chloride Suppliers

Americas 1 Belgium 1 Canada 1 China 378 Europe 3 Germany 6 India 11 Japan 12 Slovakia 1 South Korea 2 Switzerland 2 Ukraine 2 United Kingdom 9 United States 43 Global 472

HUBEI ZHENBO CHEM CO,LTD

Tel: 18086513998
Email: 280306684@qq.com
Country: China
ProdList: 290
Advantage: 58

Qingdao and Fine Chemical Co., Ltd. -

Tel: 0532-66915948
Fax: 86-532-66916851
Email: sxq@unionfinechem.com
Country: China
ProdList: 46
Advantage: 62

Weifang QianJin Fine Chemical Co., Ltd.

Tel: 18753684562
Fax: 0536-8897109
Email: 1577399715@qq.COM
Country: China
ProdList: 1739
Advantage: 55

Shandong Dexin Fine Chemical Co., Ltd.

Tel: 18553366272
Email: 3091507995@qq.com
Country: China
ProdList: 296
Advantage: 58

Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd.

Tel: 13396369453 QQ3007939906 18678026865
Fax: 0536-2101172
Email: sdfantai@163.com
Country: China
ProdList: 908
Advantage: 58

Shandong Qiancheng New Materials Co., Ltd

Tel: 15615255556
Email: 345251484@gg.com
Country: China
ProdList: 97
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TAIYUAN RHF CO.,LTD.

Tel: +86 351 7031519
Fax: +86 351 7031519
Email: sales@RHFChem.com
Country: China
ProdList: 2338
Advantage: 56

More

Less

View Lastest Price from 4-Methylbenzyl chloride manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 4-Methylbenzyl chloride 104-82-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10000KGS
Release date: 2025-11-14

Hebei Chuanghai Biotechnology Co., Ltd

Product: 4-Methylbenzyl chloride 104-82-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-12-03

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 4-Methylbenzyl chloride 104-82-5
Price: US $50.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-11-18

104-82-5, 4-Methylbenzyl chlorideRelated Search:

XYLENE CYANOL FF 2-CHLOROTHIOPHENOL Diethylstilbestrol p-Toluic acid Xylene Phenethyl alcohol Thionyl chloride 2-Chlorobenzyl chloride Musk xylene Choline chloride Benzyl chloride alpha-Chloro-o-fluorotoluene p-Cresol Benzyl chloroformate 4-Methoxybenzylchloride Potassium chloride Calcium chloride 4-tert-Butylbenzyl chloride

MBC

METHYLBENZYLCHLORIDE(4-)

4-METHYLBENZYL CHLORIDE

A-CHLORO-P-XYLENE

ALPHA-CHLORO-4-XYLENE

ALPHA-CHLORO-P-XYLENE

AKOS BBS-00003956

P-XYLYL CHLORIDE

PXCL1

P-METHYLBENZYL CHLORIDE

(4-methylphenyl)methylchloride

(Chloromethyl)toluene (2-(chloromethyl) plus 4-(chloromethyl))

(p-chloromethyl)toluene

1-(chloromethyl)-4-methyl-benzen

1-(Chloromethyl)-4-methylbenzene

4-Xylyl chloride

alpha-Chloro-p-xylene, 99+%

à-chloro-p-xylene

4-Methylbenzyl chloride 99%

PARA-METHYLBENZYLCHLORIDE

4-Methyl-1-chlormethylbenzol

6) PARA METHYL BENZYL CHLORIDE

ALPHA-CHLORO-P-XYLENE (4-METHYLBENZYL CHLORIDE)

alpha-Chloro-p-xylene, p-Xylyl chloride

α-Chloro-p-xylene, p-Xylyl chloride

4-Methylbenzyl chlor

4-Methyl chloride

alpha-Chloro-p-xylene, 99+% 100ML

alpha-Chloro-p-xylene, p-Xylyl chloride, 1-(Chloromethyl)-4-methylbenzene

The Methyl benzyl chloride

α-Chloro-p-xylene, 99+%

oro-p-xyL

pha-ChL

1-chloromethyl-4-methyl-benzene

1-Methyl-4-(chloromethyl)benzene

4-(Chloromethyl)toluene

alpha-chloro-p-xylen

p-(chloromethyl)toluene

p-Chloromethyltoluene

p-tolylmethylchloride

p-Xylene, alpha-chloro-

p-Xylyl-alpha-chloride

α-chloro-p-xylene

Benzene, 1-(chloromethyl)-4-methyl-

α-Chloro-p-xylene &gt

Plerixafor Impurity 49

α-Chloro-p-methyltoluene

P-methyl Benzyl Choride(Pmbc)

TIANFU-CHEM 4-Methylbenzyl chloride 104-82-5

Pulesafu impurity 40

Plerixafor Impurity 40

α-Chloro-p-xylene in isooctane

4-Methylbenzyl chloride, 98%

a-Chloro-p-methyltoluene

104-82-5

Building Blocks

BENZYL HALIDE

Halogenated Hydrocarbons