ChemicalBook > CAS DataBase List > 4-(4'-Bromophenyl)piperidine

4-(4'-Bromophenyl)piperidine

Product Name
4-(4'-Bromophenyl)piperidine
CAS No.
80980-89-8
Chemical Name
4-(4'-Bromophenyl)piperidine
Synonyms
4-(4-BROMOPHENYL)PIPERIDINE;4-(4'-Bromophenyl)piperidine;Piperidine, 4-(4-bromophenyl)-;4-(4′-Bromophenyl)piperidine, CAS 80980-89-8
CBNumber
CB1748699
Molecular Formula
C11H14BrN
Formula Weight
240.14
MOL File
80980-89-8.mol
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4-(4'-Bromophenyl)piperidine Property

Melting point:
144-146 °C
Boiling point:
307.6±42.0 °C(Predicted)
Density 
1.313±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
solid
pka
10.14±0.10(Predicted)
color 
Pale yellow
InChI
InChI=1S/C11H14BrN/c12-11-3-1-9(2-4-11)10-5-7-13-8-6-10/h1-4,10,13H,5-8H2
InChIKey
ZKABWLFDCJKQRE-UHFFFAOYSA-N
SMILES
N1CCC(C2=CC=C(Br)C=C2)CC1
CAS DataBase Reference
80980-89-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-52
Safety Statements 
26-36/37/39
HazardClass 
IRRITANT
HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Matrix Scientific
Product number
037289
Product name
4-(4-Bromophenyl)piperidine
Packaging
500mg
Price
$40
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB150418
Product name
4-(4'-Bromophenyl)piperidine
Packaging
50mg
Price
$59
Updated
2021/12/16
SynQuest Laboratories
Product number
3H31-9-47
Product name
4-(4-Bromophenyl)piperidine
Purity
97%
Packaging
1g
Price
$87
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB150418
Product name
4-(4'-Bromophenyl)piperidine
Packaging
100mg
Price
$103
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB150418
Product name
4-(4'-Bromophenyl)piperidine
Packaging
250mg
Price
$205
Updated
2021/12/16
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4-(4'-Bromophenyl)piperidine Chemical Properties,Usage,Production

Synthesis

91347-99-8

80980-89-8

General procedure for the synthesis of 4-(4-bromophenyl)piperidine from 4-(4-bromophenyl)-1,2,3,6-tetrahydropyridine: to a solution of 4-(4-bromophenyl)-1,2,3,6-tetrahydropyridine (0.90 g, 3.78 mmol) in anhydrous methanol (20 mL) and triethylamine (2 mL), the Rh/C catalyst (0.060 g, J. Bishop & Co. Platinum). The reaction mixture was placed in a hydrogen atmosphere (100 psi) and stirred at room temperature for 24 hours. Upon completion of the reaction, the mixture was filtered through a Celite?(Sigma Aldrich, St. Louis, MO) filter cake and the filtrate was concentrated to afford 4-(4-bromophenyl)piperidine as a white solid (0.91 g, 98% yield). The product was confirmed by 1H NMR (400 MHz, MeOD): δ 1.55-1.59 (2H, m), 1.61-1.70 (2H, m), 2.55-2.56 (1H, m), 2.64-2.70 (2H, m), 3.09-3.06 (2H, m), 7.13 (2H, J = 8.0 Hz, d), 7.31 ( 2H, J = 8.0 Hz, d).13C NMR (100 MHz, MeOD): δ 32.7, 41.4, 45.6, 119.4, 126.4, 128.2, 128.5, 131.2, 145.3. m/z of mass spectrum (ESI-MS): 241 [M+H]+.

References

[1] Journal of Medicinal Chemistry, 2016, vol. 59, # 13, p. 6149 - 6168
[2] Patent: WO2017/53769, 2017, A1. Location in patent: Paragraph 0117; 0118

4-(4'-Bromophenyl)piperidine Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-(4'-Bromophenyl)piperidine manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
4-(4"-Bromophenyl)piperidine 80980-89-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-(4"-Bromophenyl)piperidine 80980-89-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09
Career Henan Chemical Co
Product
4-(4'-Bromophenyl)piperidine 80980-89-8
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1ton
Release date
2018-08-06

80980-89-8, 4-(4'-Bromophenyl)piperidineRelated Search:

DROPERIDOL Haloperidol 2,2,6,6-Tetramethyl-4-piperidinol Diphenoxylate PHENCYCLIDINE-D5 HYDROCHLORIDE 4-(4-Bromophenyl)-4-piperidinol 1-N-BOC-4-(4-BROMOPHENYL)PIPERIDINE BROMPERIDOL Piperidine N-(3-BROMOPHENYL)PIPERIDINE,1-(3-BROMOPHENYL)PIPERIDINE 3-(4-Bromophenyl)piperidine 2-(2-BROMOPHENYL)PIPERIDINE HYDROCHLORIDE N-(4-BROMOPHENYL)PIPERIDINE,1-(4-Bromophenyl)piperidine 97%,1-(4-BROMOPHENYL)PIPERIDINE 4-(3-BROMOPHENYL) PIPERIDINE 2-(3-BROMOPHENYL)PIPERIDINE 1-BOC-4-(4-BROMO-PHENYL)-PIPERIDIN-4-OL 4-(4-Bromo-phenyl)-piperidine-2,6-dione 4-(4'-BROMOPHENYL)PIPERIDINE HYDROCHLORIDE

  • 4-(4-BROMOPHENYL)PIPERIDINE
  • Piperidine, 4-(4-bromophenyl)-
  • 4-(4'-Bromophenyl)piperidine
  • 4-(4′-Bromophenyl)piperidine, CAS 80980-89-8
  • 80980-89-8