Methyl 3-(cyanomethyl)benzoate
- Product Name
- Methyl 3-(cyanomethyl)benzoate
- CAS No.
- 68432-92-8
- Chemical Name
- Methyl 3-(cyanomethyl)benzoate
- Synonyms
- METHYL 3-(CYANOMETHYL) BENZOATE;Famoxadone Impurity 13;Methyl m-(cyanomethyl)benzoate;3-(Cyanomethyl)benzoate methyl ester;3-CYANOMETHYLBENZOIC ACID METHYL ESTER;Benzoicacid, 3-(cyanomethyl)-, methyl ester;high quality 3-CYANOMETHYLBENZOIC ACID METHYL ESTER
- CBNumber
- CB1757286
- Molecular Formula
- C10H9NO2
- Formula Weight
- 175.18
- MOL File
- 68432-92-8.mol
Methyl 3-(cyanomethyl)benzoate Property
- Boiling point:
- 314.1±25.0 °C(Predicted)
- Density
- 1.141±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
Safety
- HazardClass
- IRRITANT
- HS Code
- 2926907090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- M338090
- Product name
- Methyl3-(cyanomethyl)benzoate
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- M338090
- Product name
- Methyl3-(cyanomethyl)benzoate
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- FC70223
- Product name
- 3-Cyanomethylbenzoic acid methyl ester
- Packaging
- 100g
- Price
- $60
- Updated
- 2021/12/16
- Product number
- FC70223
- Product name
- 3-Cyanomethylbenzoic acid methyl ester
- Packaging
- 250g
- Price
- $125
- Updated
- 2021/12/16
- Product number
- P498
- Product name
- Methyl3-(cyanomethyl)benzoate
- Packaging
- 5g
- Price
- $127
- Updated
- 2021/12/16
Methyl 3-(cyanomethyl)benzoate Chemical Properties,Usage,Production
Uses
Methyl 3-(cyanomethyl)benzoate is used as an intermediate in organic synthesis for the preparation of other compounds such as 3-(cyanomethyl)benzoic acid.
Synthesis
Methyl 3-(cyanomethyl)benzoate is synthesised using Methyl 3-(bromomethyl)benzoate as raw material by chemical reaction. The specific synthesis steps are as follows:
(i) To a solution of methyl 3-bromobenzoate (10.0 g, 44 mmol) in acetonitrile (100 mL) were added potassium cyanide (5.7 g, 87 mmol) and 18-crown-6 (1.0 g), and the mixture was stirred at room temperature for 3 days. The reaction mixture was filtered, and the solvent was evaporated under reduced pressure. The residue was purified by silica gel column chromatography (ethyl acetate/hexane=5/95-->30/70), and the fraction containing the object product was concentrated under reduced pressure to give the title compound (7.0 g, 91percent) as a colorless oil. 1H-NMR (DMSO-d6, 300 MHz) δ 3.88 (3H, s), 4.17 (2H, s), 7.57 (1H, t, J = 7.6 Hz), 7.61 - 7.69 (1H, m), 7.88 - 7.95 (1H, m), 7.97 (1H, br s).
Methyl 3-(cyanomethyl)benzoate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl 3-(cyanomethyl)benzoate Suppliers
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