CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID
- Product Name
- CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID
- CAS No.
- 111955-05-6
- Chemical Name
- CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID
- Synonyms
- Cis-2-Carbomethoxycyclohexane-1-Carbox;2-carbomethoxycyclohexane-1-carboxylic acid;cis-2-Carbomethoxycyclohexanecarboxylic acid;2-methoxycarbonylcyclohexane-1-carboxylic acid;2-methoxycarbonyl-1-cyclohexanecarboxylic acid;CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID;cis-2-methoxycarbonylcyclohexanecarboxylic acid;rel-1-Methyl (1R,2S)-1,2-cyclohexanedicarboxylate;(1R,2S)-2-(Methoxycarbonyl)cyclohexanecarboxylic acid;(+/-)CIS-2-(METHOXYCARBONYL)CYCLOHEXANECARBOXYLIC ACID
- CBNumber
- CB1760765
- Molecular Formula
- C9H14O4
- Formula Weight
- 186.21
- MOL File
- 111955-05-6.mol
CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Property
- Melting point:
- 68-69 °C
- Boiling point:
- 82 °C(Press: 0.5 Torr)
- Density
- 1.191±0.06 g/cm3(Predicted)
- storage temp.
- Store at room temperature
- pka
- 4.45±0.44(Predicted)
- form
- solid
- Appearance
- White to off-white Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B415263
- Product name
- Cis-2-carbomethoxycyclohexane-1-carboxylicacid
- Packaging
- 25mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- B415263
- Product name
- Cis-2-carbomethoxycyclohexane-1-carboxylicacid
- Packaging
- 250mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 086447
- Product name
- cis-2-Carbomethoxycyclohexane-1-carboxylic acid
- Purity
- 97%
- Packaging
- 1g
- Price
- $59
- Updated
- 2021/12/16
- Product number
- 086447
- Product name
- cis-2-Carbomethoxycyclohexane-1-carboxylic acid
- Purity
- 97%
- Packaging
- 5g
- Price
- $188
- Updated
- 2021/12/16
- Product number
- 18503
- Product name
- Cis-2-Carbomethoxycyclohexane-1-carboxylicacid
- Purity
- 97%
- Packaging
- 1g
- Price
- $225
- Updated
- 2021/12/16
CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Chemical Properties,Usage,Production
Synthesis
67-56-1
13149-00-3
2484-60-8
The cis-1,2-cyclohexanedicarboxylic anhydride (7.0 g, 45.5 mmol) was dissolved in methanol (2 mL, 49.5 mmol) and the reaction was stirred at 100 °C for 1 hour. Upon completion of the reaction, the solvent was removed by evaporation to afford trans-2-(methoxycarbonyl)cyclohexanecarboxylic acid (8.46 g, 45.5 mmol, 100% yield) as a white solid, which could be used in subsequent steps without further purification. The melting point of the product is 67-69 °C. Infrared spectrum (KBr): ν 3060, 1710, 1670 cm-1. 1H NMR (400 MHz, CDCl3): δ 7.54 (s, 1H), 3.68 (s, 3H), 2.89-2.81 (m, 2H), 2.09-1.96 (m, 2H), 1.83-1.72 (m, 2H), 1.61-1.36 （13C NMR (100 MHz, CDCl3): δ 179.76, 174.06, 51.71, 42.48, 42.33, 26.25, 25.95, 23.74, 23.62. High-resolution mass spectrometry (ESI): Calculated value of C9H13O4 [M-H]- 185.0792, measured value of 185.0790. 185.0790.
References
[1] Letters in Organic Chemistry, 2018, vol. 15, # 5, p. 404 - 411
[2] Journal of Organic Chemistry, 2008, vol. 73, # 6, p. 2454 - 2457
[3] Organic and Biomolecular Chemistry, 2011, vol. 9, # 22, p. 7929 - 7940
[4] Patent: US2014/288314, 2014, A1. Location in patent: Paragraph 197; 198
[5] Chirality, 2015, vol. 27, # 10, p. 693 - 699
CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID manufacturers
- Product
- CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID 111955-05-6
- Price
- US $6.05/ASSAYS
- Min. Order
- 200g
- Purity
- 95.0%-99.0%
- Supply Ability
- 100kg
- Release date
- 2020-11-05