ChemicalBook > CAS DataBase List > CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID

CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID

Product Name
CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID
CAS No.
111955-05-6
Chemical Name
CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID
Synonyms
Cis-2-Carbomethoxycyclohexane-1-Carbox;2-carbomethoxycyclohexane-1-carboxylic acid;cis-2-Carbomethoxycyclohexanecarboxylic acid;2-methoxycarbonylcyclohexane-1-carboxylic acid;2-methoxycarbonyl-1-cyclohexanecarboxylic acid;CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID;cis-2-methoxycarbonylcyclohexanecarboxylic acid;rel-1-Methyl (1R,2S)-1,2-cyclohexanedicarboxylate;(1R,2S)-2-(Methoxycarbonyl)cyclohexanecarboxylic acid;(+/-)CIS-2-(METHOXYCARBONYL)CYCLOHEXANECARBOXYLIC ACID
CBNumber
CB1760765
Molecular Formula
C9H14O4
Formula Weight
186.21
MOL File
111955-05-6.mol
More
Less

CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Property

Melting point:
68-69 °C
Boiling point:
82 °C(Press: 0.5 Torr)
Density 
1.191±0.06 g/cm3(Predicted)
storage temp. 
Store at room temperature
pka
4.45±0.44(Predicted)
form 
solid
Appearance
White to off-white Solid
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

TRC
Product number
B415263
Product name
Cis-2-carbomethoxycyclohexane-1-carboxylicacid
Packaging
25mg
Price
$45
Updated
2021/12/16
TRC
Product number
B415263
Product name
Cis-2-carbomethoxycyclohexane-1-carboxylicacid
Packaging
250mg
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
086447
Product name
cis-2-Carbomethoxycyclohexane-1-carboxylic acid
Purity
97%
Packaging
1g
Price
$59
Updated
2021/12/16
Matrix Scientific
Product number
086447
Product name
cis-2-Carbomethoxycyclohexane-1-carboxylic acid
Purity
97%
Packaging
5g
Price
$188
Updated
2021/12/16
Rieke Metals
Product number
18503
Product name
Cis-2-Carbomethoxycyclohexane-1-carboxylicacid
Purity
97%
Packaging
1g
Price
$225
Updated
2021/12/16
More
Less

CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Chemical Properties,Usage,Production

Synthesis

67-56-1

13149-00-3

2484-60-8

The cis-1,2-cyclohexanedicarboxylic anhydride (7.0 g, 45.5 mmol) was dissolved in methanol (2 mL, 49.5 mmol) and the reaction was stirred at 100 °C for 1 hour. Upon completion of the reaction, the solvent was removed by evaporation to afford trans-2-(methoxycarbonyl)cyclohexanecarboxylic acid (8.46 g, 45.5 mmol, 100% yield) as a white solid, which could be used in subsequent steps without further purification. The melting point of the product is 67-69 °C. Infrared spectrum (KBr): ν 3060, 1710, 1670 cm-1. 1H NMR (400 MHz, CDCl3): δ 7.54 (s, 1H), 3.68 (s, 3H), 2.89-2.81 (m, 2H), 2.09-1.96 (m, 2H), 1.83-1.72 (m, 2H), 1.61-1.36 （13C NMR (100 MHz, CDCl3): δ 179.76, 174.06, 51.71, 42.48, 42.33, 26.25, 25.95, 23.74, 23.62. High-resolution mass spectrometry (ESI): Calculated value of C9H13O4 [M-H]- 185.0792, measured value of 185.0790. 185.0790.

References

[1] Letters in Organic Chemistry, 2018, vol. 15, # 5, p. 404 - 411
[2] Journal of Organic Chemistry, 2008, vol. 73, # 6, p. 2454 - 2457
[3] Organic and Biomolecular Chemistry, 2011, vol. 9, # 22, p. 7929 - 7940
[4] Patent: US2014/288314, 2014, A1. Location in patent: Paragraph 197; 198
[5] Chirality, 2015, vol. 27, # 10, p. 693 - 699

CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Suppliers

China 45 India 1 United Kingdom 1 United States 7 Global 54
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
ChemCell Biomedicine Co.,Ltd.
Tel
020-13556033878 2965585218 13556033878
Fax
0086-0757-85406358
Email
chemcell@hotmail.com
Country
China
ProdList
369
Advantage
52
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
Advantage
57
YangZhou Ruihong Biotech Co., Ltd.
Tel
0514-015380367604 15380367604
Fax
0514-83828236
Email
sales@ruibobiotech.com
Country
China
ProdList
511
Advantage
55
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd
Tel
0431-0431-80514535 19917294565
Email
et@chemextension.com
Country
China
ProdList
3935
Advantage
55
Shanghai SuperLan Chemcial Technique Centre
Tel
0-2022843681 15618226720
Fax
+86-21-51601218
Email
chaolaichem@foxmail.com
Country
China
ProdList
10410
Advantage
58
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
9ding chemical ( Shanghai) Limited
Tel
021-021-52271985 17721149837
Fax
+86 (21) 52271987
Email
sales@9dingchem.com
Country
China
ProdList
19800
Advantage
60
Aikon International Limited
Tel
025-58859352 18068836627
Fax
(5)02557626880
Email
dt3@aikonchem.com
Country
China
ProdList
15493
Advantage
58
Shanghai Anyinuo Biomedical Technology Co., Ltd.
Tel
021-34625901 18018851262;
Email
420970979@qq.com
Country
China
ProdList
5894
Advantage
58
Shanghai Benso Pharmaceutical Technology Co., Ltd.
Tel
15088289376
Email
248775804@qq.com
Country
China
ProdList
4995
Advantage
58
Chengdu Saint - Kay Biotechnology Co., Ltd.
Tel
028-85157043 15882256948
Email
676046971@qq.com
Country
China
ProdList
4181
Advantage
58
Cool Pharm, Ltd
Tel
021-58581007 18019463053
Fax
021-50966098
Email
sales@coolpharm.com
Country
China
ProdList
12878
Advantage
58
Hunan chemfish Scientific co.,ltd
Tel
19313119705 15707487186
Email
sales@chemfish.com
Country
China
ProdList
4960
Advantage
58
Shenzhen Polymeri Biochemical Technology Co., Ltd.
Tel
+86-400-002-6226 +86-13028896684;
Email
sales@rrkchem.com
Country
China
ProdList
57422
Advantage
58
Shanghai zhigan biotechnology co., LTD
Tel
Email
zhiqianbio@126.com
Country
China
ProdList
19778
Advantage
58
Aishilun biotechnology (Shanghai) co., LTD
Tel
021-50676523 18019098996
Email
info@acelybio.com
Country
China
ProdList
3960
Advantage
58
Career Henan Chemica Co
Tel
+86-0371-86658258 +8613203830695
Fax
0371-86658258
Email
laboratory@coreychem.com
Country
China
ProdList
30229
Advantage
58
HUNAN CHEMFISH SCIENTIFIC CO.,LTD
Tel
+86-0731-85567275 13298656710
Fax
QQ:3554193828
Email
sales05@chemfish.com
Country
China
ProdList
7448
Advantage
58
Changchun Sanbang Pharmaceutical Technology Co., Ltd.
Tel
0431-81884431
Email
liuy@san-bangchem.com
Country
China
ProdList
161
Advantage
58
Jiangsu yize medical technology co. LTD
Tel
18550739526
Fax
QQ: 3394205705
Email
23903480@qq.com
Country
China
ProdList
5840
Advantage
58
Haiji Pharmaceutical Technology (Suzhou) Co., Ltd
Tel
18012778619
Email
3394205705@qq.com
Country
China
ProdList
9844
Advantage
58
Beijing Haite lesk Technology Co., Ltd
Tel
15210893940; 15116916250
Fax
QQ: 237008221
Email
chemistryliu@163.com
Country
China
ProdList
7327
Advantage
58
Energy Chemical
Tel
021-58432009 400-005-6266
Fax
021-58436166
Email
marketing1@energy-chemical.com
Country
China
ProdList
44894
Advantage
58
Shanghai Ruipu Medical Technology Co., Ltd
Tel
15895968936
Fax
qq 1018762393
Email
1018762393@qq.com
Country
China
ProdList
9999
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
40000
Advantage
58
Beijing Stronger Science Co., Ltd.
Tel
0531-88924771 15614660963
Email
elsa.hang@strongerscience.com
Country
China
ProdList
10623
Advantage
58
PharmaBlock Sciences (Nanjing), Inc.
Tel
4000255188
Fax
025 86918232
Email
sales_china@pharmablock.com
Country
China
ProdList
10000
Advantage
58
Bide Pharmatech Ltd.
Tel
400-1647117 13681763483
Email
product02@bidepharm.com
Country
China
ProdList
59936
Advantage
58
Bide Pharmatech Ltd.
Tel
400-6005915
Email
sales@picasso-e.com
Country
China
ProdList
39665
Advantage
58
Hubei Hannuo Pharmaceutical Technology Co., Ltd
Tel
18662190603
Email
437347250@qq.com
Country
China
ProdList
7325
Advantage
58
Shandong Mingde Biotechnology Co., Ltd
Tel
15553348166
Email
m15553348166@163.com
Country
China
ProdList
9967
Advantage
58
Beijing InnoChem Science & Technology Co., Ltd.
Tel
15652467323
Email
sales@inno-chem.com.cn
Country
China
ProdList
8293
Advantage
58
Jiaxing Deyi Chemical Co., Ltd
Tel
0573-85866609 13588473046
Email
824930988@qq.com
Country
China
ProdList
7865
Advantage
58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50464
Advantage
58
PharmaBlock Sciences (Nanjing), Inc.
Tel
4000255188
Email
marketing@pharmablock.com
Country
China
ProdList
9126
Advantage
58
https://hanhongsci.com/
Tel
021-54306202 18917919676
Email
info@hanhongsci.com
Country
China
ProdList
29995
Advantage
58
Cheng Du Micxy Chemical Co.,Ltd
Tel
028-85632863 18108198598
Fax
028-85632863
Email
micxysales@163.com
Country
China
ProdList
10475
Advantage
58
Zhengzhou JACS Chemical Product Co., LTD
Tel
0371-86259281 13223061139
Email
893596907@qq.com
Country
China
ProdList
7993
Advantage
58
Shandong benrite new chemical materials co.,ltd
Tel
0533-2866658 15615638350
Email
sales@benritechem.com
Country
China
ProdList
6650
Advantage
58
Suzhou ARTK Medchem Co., Ltd.
Tel
+86-512-68323658 +86-18168183658
Email
sales1@artkmedchem.com
Country
China
ProdList
39002
Advantage
58
Jilin Chinese Academy of Sciences-yanshen Technology
Tel
+undefined18143011203
Email
info@chemextension.com
Country
China
ProdList
42056
Advantage
58
Hangzhou MolCore BioPharmatech Co.,Ltd.
Tel
+86-057181025280; +8617767106207
Fax
0571-85806285
Email
sales@molcore.com
Country
China
ProdList
49734
Advantage
58
Guangzhou Weike Biotechnology Co., Ltd.
Tel
15902098758
Country
CHINA
ProdList
133
Advantage
58
Syntechem Co.,Ltd
Tel
--
Fax
--
Email
-
Country
China
ProdList
6193
Advantage
58
More
Less

View Lastest Price from CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID manufacturers

Career Henan Chemica Co
Product
CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID 111955-05-6
Price
US $6.05/ASSAYS
Min. Order
200g
Purity
95.0%-99.0%
Supply Ability
100kg
Release date
2020-11-05

111955-05-6, CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACIDRelated Search:

CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID CIS-DIETHYL BICYCLO[2.2.1]HEPTANE-2,3-DICARBOXYLATE Cicloxolone (1S,2R)-Cyclohexane-1,2-dicarboxylic acid diethyl ester Monoacryloyloxyethy Hexahydrophthalate (MAHP) Dimethyl cyclohexane-1,2-dicarboxylate

  • 1,2-Cyclohexanedicarboxylic acid, 1-methyl ester, (1R,2S)-rel-
  • (1R,2S)-2-(Methoxycarbonyl)cyclohexanecarboxylic acid
  • 2-carbomethoxycyclohexane-1-carboxylic acid
  • 2-methoxycarbonyl-1-cyclohexanecarboxylic acid
  • 2-methoxycarbonylcyclohexane-1-carboxylic acid
  • (1S,2R)-2-(methoxycarbonyl)cyclohexane-1-carboxylic acid
  • (1R,2S)-2-methoxycarbonylcyclohexane-1-carboxylic acid
  • CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID
  • cis-2-Carbomethoxycyclohexanecarboxylic acid
  • (+/-)CIS-2-(METHOXYCARBONYL)CYCLOHEXANECARBOXYLIC ACID
  • Cis-2-Carbomethoxycyclohexane-1-Carbox
  • rel-1-Methyl (1R,2S)-1,2-cyclohexanedicarboxylate
  • cis-2-methoxycarbonylcyclohexanecarboxylic acid
  • 111955-05-6
  • Carboxylic acid