ChemicalBook > CAS DataBase List > 1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER

1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER

Product Name
1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER
CAS No.
177478-49-8
Chemical Name
1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER
Synonyms
Methyl 1,2,3,4-Tetrahydroquinoline-6-;Methyl 1,2,3,4-tetrahydroquinoline-6-carboxylate;Methyl 1,2,3,4-tetrahydroquinoline-6-carboxylate 97%;1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER;6-Quinolinecarboxylic acid, 1,2,3,4-tetrahydro-, methyl ester;Methyl 1,2,3,4-tetrahydroquinoline-6-carboxylate
CBNumber
CB1793220
Molecular Formula
C11H13NO2
Formula Weight
191.23
MOL File
177478-49-8.mol
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1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER Property

Melting point:
73-76 °C
Boiling point:
349.4±31.0 °C(Predicted)
Density 
1.123±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
powder
pka
2.60±0.20(Predicted)
Appearance
White to off-white Solid
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Safety

Hazard Codes 
T
Risk Statements 
25-36/37/38
Safety Statements 
26-45
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
HS Code 
2933499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
702374
Product name
Methyl 1,2,3,4-tetrahydroquinoline-6-carboxylate
Purity
97%
Packaging
1g
Price
$274
Updated
2023/06/20
Sigma-Aldrich
Product number
702374
Product name
Methyl 1,2,3,4-tetrahydroquinoline-6-carboxylate
Purity
97%
Packaging
250mg
Price
$83.6
Updated
2023/01/07
TRC
Product number
B486068
Product name
Methyl 1,2,3,4-tetrahydroquinoline-6-carboxylate
Packaging
50mg
Price
$45
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0122260
Product name
METHYL 1,2,3,4-TETRAHYDROQUINOLINE-6-CARBOXYLATE
Purity
95.00%
Packaging
2.5G
Price
$1011.6
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0122260
Product name
METHYL 1,2,3,4-TETRAHYDROQUINOLINE-6-CARBOXYLATE
Purity
95.00%
Packaging
5G
Price
$1210.63
Updated
2021/12/16
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1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

38896-30-9

177478-49-8

The general procedure for the synthesis of methyl 1,2,3,4-tetrahydroquinoline-6-carboxylate from methyl 6-quinolinecarboxylate was as follows: carbon-loaded palladium (1.50 g, 10% mass fraction) and ammonium formate (10.5 g, 165 mmol) were added in methanol (20 mL), followed by methyl 6-quinolinecarboxylate (1.20 g, 6.41 mmol). The reaction mixture was stirred at 70°C for 2 hours. Upon completion of the reaction, the synthesis was processed according to the synthesis method of Step 1 of Example 2 to afford the white solid product methyl 1,2,3,4-tetrahydroquinoline-6-carboxylate (1.20 g) in 97.9% yield.

References

[1] Catalysis Science and Technology, 2017, vol. 7, # 10, p. 1981 - 1985
[2] Catalysis Science and Technology, 2018, vol. 8, # 10, p. 2648 - 2653
[3] Patent: CN105524053, 2016, A. Location in patent: Paragraph 0534; 0535; 0536
[4] ACS Catalysis, 2018, vol. 8, # 5, p. 4545 - 4557
[5] Angewandte Chemie - International Edition, 2017, vol. 56, # 12, p. 3216 - 3220

1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER Suppliers

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View Lastest Price from 1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER manufacturers

Career Henan Chemical Co
Product
1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER 177478-49-8
Price
US $0.01/KG
Min. Order
1KG
Purity
98%; 99%
Supply Ability
500g； 1kg; 25kg
Release date
2020-01-10

177478-49-8, 1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTERRelated Search:

1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER CHEMBRDG-BB 5667569 ASISCHEM N57814 ASISCHEM B51549 RARECHEM AL BF 0792 ASISCHEM N57815 ASISCHEM N57789 ASISCHEM B51552 ASISCHEM N57804 RARECHEM AL BF 0592 ASISCHEM B51575 ASISCHEM W11550 ASISCHEM W23796 ASISCHEM N57801 RARECHEM AL BI 0592 ASISCHEM W06458 ASISCHEM B51577 ASISCHEM B51556

  • Methyl 1,2,3,4-tetrahydroquinoline-6-carboxylate
  • 1,2,3,4-TETRAHYDRO-QUINOLINE-6-CARBOXYLIC ACID METHYL ESTER
  • 6-Quinolinecarboxylic acid, 1,2,3,4-tetrahydro-, methyl ester
  • Methyl 1,2,3,4-tetrahydroquinoline-6-carboxylate 97%
  • Methyl 1,2,3,4-Tetrahydroquinoline-6-
  • Methyl 1,2,3,4-<WBR>tetrahydroquinoline-<WBR>6-<WBR>carboxylate
  • 177478-49-8