lithium hydrogenacetylide
- Product Name
- lithium hydrogenacetylide
- CAS No.
- 1111-64-4
- Chemical Name
- lithium hydrogenacetylide
- Synonyms
- Lithioethyne;Ethynyllithium;Ethinyl lithiuM;Lithioacetylene;LITHIUM ACETYLENIDE;Monolithium acetylide;lithium hydrogenacetylide
- CBNumber
- CB1888948
- Molecular Formula
- C2HLi
- Formula Weight
- 31.97
- MOL File
- 1111-64-4.mol
lithium hydrogenacetylide Property
- solubility
- soluble in THF
lithium hydrogenacetylide Chemical Properties,Usage,Production
Definition
ChEBI: An alkynyllithium compound resulting from the replacement of one of the hydrogens of acetylene by lithium.
Application
Lithium Acetylide is a reagent for adding Acetylene to ketones, opening epoxides, and ethynylation of alkyl halides.
Synthesis
Monolithium lithium acetylide is prepared by treating a THF solution of Acetylene with n-Butyllithium at 78 °C (eq 1). It is critical to keep the temperature at -78 °C. The concentration should be 0.5 M or less. At higher concentrations and temperatures, a white precipitate forms (presumably Dilithium Acetylide), and yields of additional product fall appreciably. Properly formed lithium acetylide in THF should be a clear, colorless solution.
Precautions
Lithium acetylide/THF solution must be used immediately after preparation. It decomposes above -78 °C. A saturated solution of THF/acetylene should not be used during the preparation of lithium acetylide since this may lead to an acetylene atmosphere above the THF. n-Butyllithium dropping through the acetylene atmosphere may react violently. Lithium acetylide is air and moisture sensitive.
lithium hydrogenacetylide Preparation Products And Raw materials
Raw materials
Preparation Products
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