ChemicalBook > CAS DataBase List > 2-Amino-4-chloro-6-picoline

2-Amino-4-chloro-6-picoline

Product Name
2-Amino-4-chloro-6-picoline
CAS No.
36340-61-1
Chemical Name
2-Amino-4-chloro-6-picoline
Synonyms
oro-6-picoL;6-AMINO-4-CHLORO-2-PICOLINE;2-Amino-4-chloro-6-picoline;4-chloro-6-Methyl-2-PyridinaMine;2-AMino-4-chloro-6-Methylpyridine;4-Chloro-6-methylpyridin-2-ylamine;2-Pyridinamine, 4-chloro-6-methyl-;2-Amino-4-chloro-6-picoline ISO 9001：2015 REACH
CBNumber
CB1947100
Molecular Formula
C6H7ClN2
Formula Weight
142.59
MOL File
36340-61-1.mol
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2-Amino-4-chloro-6-picoline Property

Melting point:
108-109 °C
Boiling point:
245.1±35.0 °C(Predicted)
Density 
1.260±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
solid
pka
5.96±0.35(Predicted)
color 
Grey
InChI
InChI=1S/C6H7ClN2/c1-4-2-5(7)3-6(8)9-4/h2-3H,1H3,(H2,8,9)
InChIKey
IKKMKJOVXQEEHS-UHFFFAOYSA-N
SMILES
C1(N)=NC(C)=CC(Cl)=C1
CAS DataBase Reference
36340-61-1
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
A595890
Product name
2-Amino-4-chloro-6-picoline
Packaging
50mg
Price
$90
Updated
2021/12/16
Biosynth Carbosynth
Product number
NA66773
Product name
2-Amino-4-chloro-6-methylpyridine
Packaging
250g
Price
$62.5
Updated
2021/12/16
Biosynth Carbosynth
Product number
NA66773
Product name
2-Amino-4-chloro-6-methylpyridine
Packaging
500g
Price
$100
Updated
2021/12/16
SynQuest Laboratories
Product number
3H30-5-8G
Product name
4-Chloro-6-methylpyridin-2-amine
Purity
97%
Packaging
250mg
Price
$119
Updated
2021/12/16
Biosynth Carbosynth
Product number
NA66773
Product name
2-Amino-4-chloro-6-methylpyridine
Packaging
1g
Price
$150
Updated
2021/12/16
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2-Amino-4-chloro-6-picoline Chemical Properties,Usage,Production

Synthesis

823-96-1

116632-24-7

36340-61-1

The general procedure for the synthesis of 2-amino-4-chloro-6-methylpyridine from 2-amino-4,6-dichloropyridine and trimethylcyclotriboroxane is as follows: to a 10% aqueous solution of dioxane (0.1 M) were added sequentially 2-amino-4,6-dichloropyridine (1.0 eq.), trimethylcyclotriboroxane (1.5 eq.), tetrakis(triphenylphosphine)palladium (0.10 eq.) and potassium carbonate (3.0 eq.). The reaction mixture was heated to 120 °C in an oil bath with continuous stirring for 18 hours. Upon completion of the reaction, it was cooled to room temperature (note: not all ingredients were completely consumed). The reaction mixture was extracted with ethyl acetate and the organic phase was dried over anhydrous sodium sulfate and subsequently concentrated under reduced pressure. The crude product was purified by silica gel column chromatography using 5% methanol/dichloromethane as eluent, resulting in an off-white 2-amino-4-chloro-6-methylpyridine solid in 23% yield.LCMS analysis showed a molecular ion peak (m/z) of 143 (MH+) for the target compound with a retention time (Rt) of 1.11 min on the liquid chromatogram.

References

[1] Patent: US2011/195980, 2011, A1. Location in patent: Page/Page column 15

2-Amino-4-chloro-6-picoline Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Amino-4-chloro-6-picoline Suppliers

China 88 India 2 United Kingdom 2 United States 11 Global 103
Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
Eurolabs Limited
Tel
--
Fax
--
Country
United Kingdom
ProdList
6309
Advantage
46
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View Lastest Price from 2-Amino-4-chloro-6-picoline manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
2-Amino-4-chloro-6-picoline 36340-61-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-18
Dideu Industries Group Limited
Product
2-Amino-4-chloro-6-picoline 36340-61-1
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons min
Release date
2021-08-30
Career Henan Chemical Co
Product
2-Amino-4-chloro-6-picoline 36340-61-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-12-24

36340-61-1, 2-Amino-4-chloro-6-picoline Related Search:


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  • 2-Amino-4-chloro-6-picoline
  • 6-AMINO-4-CHLORO-2-PICOLINE
  • 4-chloro-6-Methyl-2-PyridinaMine
  • 2-AMino-4-chloro-6-Methylpyridine
  • oro-6-picoL
  • 2-Pyridinamine, 4-chloro-6-methyl-
  • 2-Amino-4-chloro-6-picoline ISO 9001：2015 REACH
  • 36340-61-1