ChemicalBook > CAS DataBase List > 2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T&

2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T&

Product Name
2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T&
CAS No.
77047-87-1
Chemical Name
2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T&
Synonyms
zinc,propane,bromide;isopropylzinc bromide;2-propylzinc bromide solution;Zinc,bromo(1-methylethyl)- (9CI);2-Propylzinc bromide (5 M in THF);2-Propylzinc bromide, 0.5 M in THF;2-Propylzinc bromide, 0.50 M in THF;Iso-Propyl Zinc Bromide (0.5M in THF);2-Propylzinc bromide solution 0.5 in THF;2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T&
CBNumber
CB1972285
Molecular Formula
C3H7BrZn
Formula Weight
188.37
MOL File
77047-87-1.mol
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2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T& Property

Density 
0.963 g/mL at 25 °C
Flash point:
-20 °C
storage temp. 
2-8°C
Water Solubility 
Reacts with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
CAS DataBase Reference
77047-87-1
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Safety

Hazard Codes 
F+,Xi,Xn,F
Risk Statements 
11-19-36/37/38-40-14/15
Safety Statements 
7-26-43-36/37-16
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
3
HazardClass 
4.3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
680966
Product name
2-Propylzinc bromide solution
Purity
0.5 M in THF
Packaging
50ml
Price
$307
Updated
2024/03/01
Alfa Aesar
Product number
H58536
Product name
Isopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
50ml
Price
$235
Updated
2024/03/01
Rieke Metals
Product number
2248
Product name
2-Propylzincbromide
Packaging
50mL
Price
$263
Updated
2021/12/16
Rieke Metals
Product number
2380
Product name
2-Propylzincbromide
Packaging
50mL
Price
$336
Updated
2021/12/16
Matrix Scientific
Product number
121910
Product name
2-Propylzincbromide
Purity
0.50MinTHF97%
Packaging
50ml
Price
$435
Updated
2021/12/16
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2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T& Chemical Properties,Usage,Production

Uses

Isopropylzinc bromide is employed in croos-coupling reactions.

Uses

2-Propylzinc bromide solution (0.5 M in THF) has been used as a reagent in a protocol for the nickel-catalyzed dehalogenation of organic halides.

2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T& Preparation Products And Raw materials

Raw materials

Preparation Products

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2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T& Suppliers

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