ChemicalBook > CAS DataBase List > CYCLOPENTYLZINC BROMIDE
CYCLOPENTYLZINC BROMIDE
- Product Name
- CYCLOPENTYLZINC BROMIDE
- CAS No.
- 171860-68-7
- Chemical Name
- CYCLOPENTYLZINC BROMIDE
- Synonyms
- CYCLOPENTYLZINC BROMIDE;Zinc, bromocyclopentyl-;bromozinc(1+),cyclopentane;cyclopentylzinc(II) broMide;cyclopentylzinc bromide solution;Cyclopentylzinc bromide, 0.50 M in THF;Cyclopentylzinc bromide solution 0.5 in THF;Cyclopentylzinc broMide solution 0.5 M in THF;Cyclopentylzinc broMide, 0.5 M solution in THF, SpcSeal;CYCLOPENTYLZINC BROMIDE, 0.5M SOLUTION I N TETRAHYDROFURAN
- CBNumber
- CB6381277
- Molecular Formula
- C5H9BrZn
- Formula Weight
- 214.42
- MOL File
- 171860-68-7.mol
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CYCLOPENTYLZINC BROMIDE Property
- Density
- 0.955 g/mL at 25 °C
- Flash point:
- 1 °F
- storage temp.
- 2-8°C
- Water Solubility
- Reacts with water.
- Sensitive
- Air Sensitive
- Exposure limits
- ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
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Safety
- Hazard Codes
- F,Xn
- Risk Statements
- 11-14-19-22-36/37/38-40-36/37
- Safety Statements
- 16-26-33-36-36/37
- RIDADR
- UN 3399 4.3/PG 2
- WGK Germany
- 1
- HazardClass
- 4.3
- HS Code
- 29319090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H261In contact with water releases flammable gas
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H315Causes skin irritation
H318Causes serious eye damage
H319Causes serious eye irritation
H333May be harmful if inhaled
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232Handle under inert gas. Protect from moisture.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
P402+P404Store in a dry place. Store in a closed container.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 498041
- Product name
- Cyclopentylzinc bromide solution
- Purity
- 0.5 M in THF
- Packaging
- 50ml
- Price
- $335
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- H58764
- Product name
- Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
- Packaging
- 50ml
- Price
- $213.65
- Updated
- 2024/03/01
Rieke Metals
- Product number
- 2028
- Product name
- Cyclopentylzincbromide
- Packaging
- 50mL
- Price
- $280
- Updated
- 2021/12/16
Rieke Metals
- Product number
- 2429
- Product name
- Cyclopentylzincbromide
- Packaging
- 50mL
- Price
- $290
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 121890
- Product name
- Cyclopentylzincbromide
- Purity
- 0.50MinTHF97%
- Packaging
- 50ml
- Price
- $425
- Updated
- 2021/12/16
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CYCLOPENTYLZINC BROMIDE Chemical Properties,Usage,Production
Uses
Cyclopentylzinc bromide is an organozinc reagent that can be used in:
- The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
- Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
- The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.
CYCLOPENTYLZINC BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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