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CYCLOPENTYLZINC BROMIDE

Product Name
CYCLOPENTYLZINC BROMIDE
CAS No.
171860-68-7
Chemical Name
CYCLOPENTYLZINC BROMIDE
Synonyms
CYCLOPENTYLZINC BROMIDE;Zinc, bromocyclopentyl-;bromozinc(1+),cyclopentane;cyclopentylzinc(II) broMide;cyclopentylzinc bromide solution;Cyclopentylzinc bromide, 0.50 M in THF;Cyclopentylzinc bromide solution 0.5 in THF;Cyclopentylzinc broMide solution 0.5 M in THF;Cyclopentylzinc broMide, 0.5 M solution in THF, SpcSeal;CYCLOPENTYLZINC BROMIDE, 0.5M SOLUTION I N TETRAHYDROFURAN
CBNumber
CB6381277
Molecular Formula
C5H9BrZn
Formula Weight
214.42
MOL File
171860-68-7.mol
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CYCLOPENTYLZINC BROMIDE Property

Density 
0.955 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
2-8°C
Water Solubility 
Reacts with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
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Safety

Hazard Codes 
F,Xn
Risk Statements 
11-14-19-22-36/37/38-40-36/37
Safety Statements 
16-26-33-36-36/37
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
1
HazardClass 
4.3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H318Causes serious eye damage

H319Causes serious eye irritation

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
498041
Product name
Cyclopentylzinc bromide solution
Purity
0.5 M in THF
Packaging
50ml
Price
$335
Updated
2024/03/01
Alfa Aesar
Product number
H58764
Product name
Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
50ml
Price
$213.65
Updated
2024/03/01
Rieke Metals
Product number
2028
Product name
Cyclopentylzincbromide
Packaging
50mL
Price
$280
Updated
2021/12/16
Rieke Metals
Product number
2429
Product name
Cyclopentylzincbromide
Packaging
50mL
Price
$290
Updated
2021/12/16
Matrix Scientific
Product number
121890
Product name
Cyclopentylzincbromide
Purity
0.50MinTHF97%
Packaging
50ml
Price
$425
Updated
2021/12/16
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CYCLOPENTYLZINC BROMIDE Chemical Properties,Usage,Production

Uses

Cyclopentylzinc bromide is an organozinc reagent that can be used in:

  • The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
  • Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
  • The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.

CYCLOPENTYLZINC BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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CYCLOPENTYLZINC BROMIDE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
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86-10-82849933
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jkinfo@jkchemical.com
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China
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96815
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
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saleschina@alfa-asia.com
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China
ProdList
30123
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Energy Chemical
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021-021-58432009 400-005-6266
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021-58436166
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sales8178@energy-chemical.com
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021-54306202 13764082696
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info@hanhongsci.com
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Syntechem Co.,Ltd
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Fax
E-Mail Inquiry
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info@syntechem.com
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China
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Sigma-Aldrich
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021-61415566 800-8193336
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orderCN@merckgroup.com
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15902145085
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Guangzhou Jhd Chemical Reagent Co., Ltd.
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020-84383047
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3A Chemicals
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400-668-9898
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service@3achem.com
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Shenzhen Polymeri Biochemical Technology Co., Ltd.
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Beijing yiyou Zhiyuan technology co., ltd
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Hefei TNJ Chemical Industry Co.,Ltd.
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Shandong Zhishang New Material Co., Ltd.
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Career Henan Chemica Co
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Guangdong Wengjiang Chemical Reagent Co., Ltd.
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CONIER CHEM AND PHARMA LIMITED
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Energy Chemical
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Huangshi Bo’Er Chemical Co., Ltd.
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Guangzhou WeiBo Chemical Co., Ltd.
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171860-68-7, CYCLOPENTYLZINC BROMIDERelated Search:


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  • Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal&trade
  • bromozinc(1+),cyclopentane
  • 171860-68-7
  • C5H9BrZn
  • C5H9ZnBr
  • Organozinc Halides
  • Organometallic Reagents
  • Reike and Organozinc Reagents
  • Alkyl
  • Alkyl
  • Organozinc Halides
  • Reike and Organozinc Reagents