BUTYLZINC BROMIDE
- Product Name
- BUTYLZINC BROMIDE
- CAS No.
- 92273-73-9
- Chemical Name
- BUTYLZINC BROMIDE
- Synonyms
- Zinc, bromobutyl-;BUTYLZINC BROMIDE;N-BUTYLZINC BROMIDE;butylzinc bromide solution;Butylzinc bromide, 0.5 M in THF;Butylzinc bromide, 0.50 M in THF;Butylzinc bromide solution 0.5 in THF;Butylzinc broMide solution 0.5 M in THF;n-Butylzinc bromide 0.5 M in Tetrahydrofuran;BUTYLZINC BROMIDE, 0.5M SOLUTION IN TETR AHYDROFURAN
- CBNumber
- CB5418525
- Molecular Formula
- C4H9BrZn
- Formula Weight
- 202.4
- MOL File
- 92273-73-9.mol
BUTYLZINC BROMIDE Property
- Density
- 0.958 g/mL at 25 °C
- Flash point:
- 1 °F
- storage temp.
- 2-8°C
- Water Solubility
- Reacts with water.
- Sensitive
- Air Sensitive
- Exposure limits
- ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
Safety
- Hazard Codes
- F,Xn
- Risk Statements
- 11-14-19-22-36/37/38-40-36/37
- Safety Statements
- 16-26-33-36-36/37
- RIDADR
- UN 3399 4.3/PG 2
- WGK Germany
- 1
- HazardClass
- 4.3
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H261In contact with water releases flammable gas
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H319Causes serious eye irritation
H333May be harmful if inhaled
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 497746
- Product name
- Butylzinc bromide solution
- Purity
- 0.5 M in THF
- Packaging
- 50ml
- Price
- $323
- Updated
- 2024/03/01
- Product number
- H58121
- Product name
- n-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
- Packaging
- 50ml
- Price
- $189.65
- Updated
- 2024/03/01
- Product number
- 2433
- Product name
- n-Butylzincbromide
- Packaging
- 50mL
- Price
- $290
- Updated
- 2021/12/16
- Product number
- 213843
- Product name
- n-Butylzincbromide0.5MinTetrahydrofuran
- Packaging
- 5ml
- Price
- $80
- Updated
- 2021/12/16
- Product number
- 121881
- Product name
- Butylzincbromide
- Purity
- 0.50MinTHF97%
- Packaging
- 50ml
- Price
- $435
- Updated
- 2021/12/16
BUTYLZINC BROMIDE Chemical Properties,Usage,Production
Uses
Butylzinc bromide is an organozinc compound, which can be used as a reagent:
- In palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bond by reacting with organic halides or triflates.
- To prepare n-butylanisole by treating with 4-bromoanisole in the presence of a tetraphosphine ligand and a palladium catalyst.
BUTYLZINC BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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