ChemicalBook > CAS DataBase List > BUTYLZINC BROMIDE

BUTYLZINC BROMIDE

Product Name
BUTYLZINC BROMIDE
CAS No.
92273-73-9
Chemical Name
BUTYLZINC BROMIDE
Synonyms
Zinc, bromobutyl-;BUTYLZINC BROMIDE;N-BUTYLZINC BROMIDE;butylzinc bromide solution;Butylzinc bromide, 0.5 M in THF;Butylzinc bromide, 0.50 M in THF;Butylzinc bromide solution 0.5 in THF;Butylzinc broMide solution 0.5 M in THF;n-Butylzinc bromide 0.5 M in Tetrahydrofuran;BUTYLZINC BROMIDE, 0.5M SOLUTION IN TETR AHYDROFURAN
CBNumber
CB5418525
Molecular Formula
C4H9BrZn
Formula Weight
202.4
MOL File
92273-73-9.mol
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BUTYLZINC BROMIDE Property

Density 
0.958 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
2-8°C
Water Solubility 
Reacts with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
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Safety

Hazard Codes 
F,Xn
Risk Statements 
11-14-19-22-36/37/38-40-36/37
Safety Statements 
16-26-33-36-36/37
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
1
HazardClass 
4.3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H319Causes serious eye irritation

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
497746
Product name
Butylzinc bromide solution
Purity
0.5 M in THF
Packaging
50ml
Price
$323
Updated
2024/03/01
Alfa Aesar
Product number
H58121
Product name
n-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
50ml
Price
$189.65
Updated
2024/03/01
Rieke Metals
Product number
2433
Product name
n-Butylzincbromide
Packaging
50mL
Price
$290
Updated
2021/12/16
Oakwood
Product number
213843
Product name
n-Butylzincbromide0.5MinTetrahydrofuran
Packaging
5ml
Price
$80
Updated
2021/12/16
Matrix Scientific
Product number
121881
Product name
Butylzincbromide
Purity
0.50MinTHF97%
Packaging
50ml
Price
$435
Updated
2021/12/16
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BUTYLZINC BROMIDE Chemical Properties,Usage,Production

Uses

Butylzinc bromide is an organozinc compound, which can be used as a reagent:

  • In palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bond by reacting with organic halides or triflates.
  • To prepare n-butylanisole by treating with 4-bromoanisole in the presence of a tetraphosphine ligand and a palladium catalyst.

BUTYLZINC BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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BUTYLZINC BROMIDE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
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jkinfo@jkchemical.com
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China
ProdList
96815
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
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Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
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info@hanhongsci.com
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China
ProdList
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Sigma-Aldrich
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021-61415566 800-8193336
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orderCN@merckgroup.com
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China
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Giant chemicals
Tel
028-85434334 18108076537
Fax
QQ:245797092
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market@gianthx.com
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China
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Tel
15902145085
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Guangzhou Jhd Chemical Reagent Co., Ltd.
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020-84383047
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020-84380294
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sales@jhd.com.cn
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China
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Shenzhen Polymeri Biochemical Technology Co., Ltd.
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+86-400-002-6226 13028896684
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Zhengzhou Alfa Chemical Co.,Ltd
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Guangdong Wengjiang Chemical Reagent Co., Ltd.
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CONIER CHEM AND PHARMA LIMITED
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Energy Chemical
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Tianjin Yankai Scientific Co. Ltd.
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Pushan Industry (Shaanxi) Co., Ltd.
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Shaanxi Didu New Material Co., Ltd
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Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
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Huangshi Bo’Er Chemical Co., Ltd.
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Guangzhou WeiBo Chemical Co., Ltd.
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--
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92273-73-9, BUTYLZINC BROMIDERelated Search:


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