ChemicalBook > CAS DataBase List > PHENETHYLZINC BROMIDE
PHENETHYLZINC BROMIDE
- Product Name
- PHENETHYLZINC BROMIDE
- CAS No.
- 308796-14-7
- Chemical Name
- PHENETHYLZINC BROMIDE
- Synonyms
- PHENETHYLZINC BROMIDE;2-Phenylethylzinc bromide;phenethylzinc bromide solution;Phenethylzinc bromide, 0.50 M in THF;PHENETHYLZINC BROMIDE, 0.5M SOLUTION IN;Phenethylzinc bromide solution 0.5 in THF;Phenethylzinc bromide solution 0.5 M in THF;2-Phenylethylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles;2-Phenylethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™2-Phenylethylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
- CBNumber
- CB0321479
- Molecular Formula
- C8H9BrZn
- Formula Weight
- 250.45
- MOL File
- 308796-14-7.mol
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PHENETHYLZINC BROMIDE Property
- Boiling point:
- 65 °C
- Density
- 0.965 g/mL at 25 °C
- Flash point:
- 1 °F
- storage temp.
- 2-8°C
- Water Solubility
- Reacts with water.
- Sensitive
- Air Sensitive
- Exposure limits
- ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) - CAS DataBase Reference
- 308796-14-7
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Safety
- Hazard Codes
- F,Xn
- Risk Statements
- 14-19-22-36/38-40-36/37-11
- Safety Statements
- 16-26-33-36-36/37
- RIDADR
- UN 2056 3/PG 2
- WGK Germany
- 1
- HazardClass
- 4.3
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H261In contact with water releases flammable gas
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H319Causes serious eye irritation
H333May be harmful if inhaled
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 499307
- Product name
- Phenethylzinc bromide solution
- Purity
- 0.5 M in THF
- Packaging
- 50ml
- Price
- $215.4
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- H58154
- Product name
- 2-Phenylethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
- Packaging
- 50ml
- Price
- $189.65
- Updated
- 2024/03/01
Rieke Metals
- Product number
- 2097
- Product name
- Phenethylzincbromide
- Packaging
- 50mL
- Price
- $263
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 121889
- Product name
- Phenethylzincbromide
- Purity
- 0.50MinTHF97%
- Packaging
- 50ml
- Price
- $435
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 121889
- Product name
- Phenethylzincbromide
- Purity
- 0.50MinTHF97%
- Packaging
- 100ml
- Price
- $646
- Updated
- 2021/12/16
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PHENETHYLZINC BROMIDE Chemical Properties,Usage,Production
Uses
Phenethylzinc bromide can be used as a reagent:
- In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
- To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
- To synthesize benzyl substituted thienopyrimidine derivatives.
PHENETHYLZINC BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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