ChemicalBook > CAS DataBase List > PHENETHYLZINC BROMIDE

PHENETHYLZINC BROMIDE

Product Name
PHENETHYLZINC BROMIDE
CAS No.
308796-14-7
Chemical Name
PHENETHYLZINC BROMIDE
Synonyms
PHENETHYLZINC BROMIDE;2-Phenylethylzinc bromide;phenethylzinc bromide solution;Phenethylzinc bromide, 0.50 M in THF;PHENETHYLZINC BROMIDE, 0.5M SOLUTION IN;Phenethylzinc bromide solution 0.5 in THF;Phenethylzinc bromide solution 0.5 M in THF;2-Phenylethylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles;2-Phenylethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™2-Phenylethylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
CBNumber
CB0321479
Molecular Formula
C8H9BrZn
Formula Weight
250.45
MOL File
308796-14-7.mol
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PHENETHYLZINC BROMIDE Property

Boiling point:
65 °C
Density 
0.965 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
2-8°C
Water Solubility 
Reacts with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
CAS DataBase Reference
308796-14-7
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Safety

Hazard Codes 
F,Xn
Risk Statements 
14-19-22-36/38-40-36/37-11
Safety Statements 
16-26-33-36-36/37
RIDADR 
UN 2056 3/PG 2
WGK Germany 
1
HazardClass 
4.3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H319Causes serious eye irritation

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
499307
Product name
Phenethylzinc bromide solution
Purity
0.5 M in THF
Packaging
50ml
Price
$215.4
Updated
2024/03/01
Alfa Aesar
Product number
H58154
Product name
2-Phenylethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
50ml
Price
$189.65
Updated
2024/03/01
Rieke Metals
Product number
2097
Product name
Phenethylzincbromide
Packaging
50mL
Price
$263
Updated
2021/12/16
Matrix Scientific
Product number
121889
Product name
Phenethylzincbromide
Purity
0.50MinTHF97%
Packaging
50ml
Price
$435
Updated
2021/12/16
Matrix Scientific
Product number
121889
Product name
Phenethylzincbromide
Purity
0.50MinTHF97%
Packaging
100ml
Price
$646
Updated
2021/12/16
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PHENETHYLZINC BROMIDE Chemical Properties,Usage,Production

Uses

Phenethylzinc bromide can be used as a reagent:

  • In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
  • To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
  • To synthesize benzyl substituted thienopyrimidine derivatives.

PHENETHYLZINC BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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PHENETHYLZINC BROMIDE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Guangzhou Jhd Chemical Reagent Co., Ltd.
Tel
020-84383047
Fax
020-84380294
Email
sales@jhd.com.cn
Country
China
ProdList
9186
Advantage
65
Shenzhen Polymeri Biochemical Technology Co., Ltd.
Tel
+86-400-002-6226 +86-13028896684;
Email
sales@rrkchem.com
Country
China
ProdList
57412
Advantage
58
Guangdong Wengjiang Chemical Reagent Co., Ltd.
Tel
0751-2886766 13927870850
Fax
0751-2886756
Email
3001267247@qq.com
Country
China
ProdList
9974
Advantage
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CONIER CHEM AND PHARMA LIMITED
Tel
+8618523575427
Email
sales@conier.com
Country
China
ProdList
49374
Advantage
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Energy Chemical
Tel
021-58432009 400-005-6266
Fax
021-58436166
Email
marketing@energy-chemical.com
Country
China
ProdList
44918
Advantage
58
Shaanxi Didu New Material Co., Ltd
Tel
029-81145920 15353716720
Email
1046@dideu.com
Country
China
ProdList
9983
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Huangshi Bo’Er Chemical Co., Ltd.
Tel
0714-6401888 18671400300
Fax
0714-6401888
Email
273568016@qq.com
Country
China
ProdList
540
Advantage
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Guangzhou WeiBo Chemical Co., Ltd.
Tel
--
Fax
--
Email
weibochem@163.com
Country
China
ProdList
6187
Advantage
67

308796-14-7, PHENETHYLZINC BROMIDERelated Search:


  • PHENETHYLZINC BROMIDE
  • phenethylzinc bromide solution
  • Phenethylzinc bromide solution 0.5 in THF
  • PHENETHYLZINC BROMIDE, 0.5M SOLUTION IN
  • 2-Phenylethylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
  • Phenethylzinc bromide solution 0.5 M in THF
  • 2-Phenylethylzinc bromide
  • Phenethylzinc bromide, 0.50 M in THF
  • 2-Phenylethylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
  • 2-Phenylethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal&trade
  • 308796-14-7
  • C8H9BrZn
  • C6H5CH2CH2ZnBr
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  • Organozinc Halides
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  • Chemical Synthesis
  • Organometallic Reagents
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  • Rieke and Organozinc Reagents
  • Alkyl
  • Organozinc Halides
  • Reike and Organozinc Reagents