ChemicalBook > CAS DataBase List > (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE

Product Name
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE
CAS No.
364732-88-7
Chemical Name
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE
Synonyms
(R)-Phanephos, 98%, ee 98%;(Rp)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane;(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane,99%e.e.;(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%;(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%,99%ee;Phosphine, 1,1'-(tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diyl)bis[1,1-diphenyl-, stereoisomer
CBNumber
CB1972821
Molecular Formula
C40H34P2
Formula Weight
576.65
MOL File
364732-88-7.mol
More
Less

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE Property

Melting point:
222-225°C
alpha 
-62.6° (c 3.11, CH2Cl2)
storage temp. 
Inert atmosphere,Room Temperature
form 
solid
color 
white
optical activity
[α]/D -34±4°, c = 1 in chloroform
CAS DataBase Reference
364732-88-7
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
37
WGK Germany 
3
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
682144
Product name
(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane
Purity
96%
Packaging
100mg
Price
$120
Updated
2024/03/01
Sigma-Aldrich
Product number
682144
Product name
(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane
Purity
96%
Packaging
500mg
Price
$547
Updated
2024/03/01
Alfa Aesar
Product number
H25812
Product name
(R)-Phanephos, 98%, ee 98%
Packaging
250mg
Price
$139.18
Updated
2021/12/16
Strem Chemicals
Product number
15-0425
Product name
(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS
Packaging
100mg
Price
$102
Updated
2024/03/01
Strem Chemicals
Product number
15-0425
Product name
(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS
Packaging
500mg
Price
$412
Updated
2024/03/01
More
Less

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE Chemical Properties,Usage,Production

Uses

Efficient ligand for asymmetric hydrogentation of dehydroamino acids, methyl esters and keytones.

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
7195
Advantage
65
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41462
Advantage
60
Sinocompound Catalysts Co., Ltd.
Tel
0512-67216630 67216634
Fax
0512-56316689
Email
sales@sinocompound.com
Country
China
ProdList
278
Advantage
64
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Shanghai Chiral bio-compound co., Ltd.
Tel
021-5068 3667/17749785980/1029026415; 17749785980
Fax
021-50683667
Email
1029026415@qq.com
Country
China
ProdList
3013
Advantage
58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel
0371-65511006 18625597674
Email
sales@kingorgchem.com
Country
China
ProdList
953
Advantage
55
Zhengzhou Huiju Chemical Co., Ltd.
Tel
0371-55900031 18137872243
Fax
QQ:2853979815
Email
2853979815@qq.com
Country
China
ProdList
10001
Advantage
55
More
Less

View Lastest Price from (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE manufacturers

Career Henan Chemical Co
Product
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE, 96% 364732-88-7
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

364732-88-7, (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANERelated Search:


  • (R)-Phanephos, 98%, ee 98%
  • (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane,99%e.e.
  • (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%
  • (Rp)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane
  • Phosphine, 1,1'-(tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diyl)bis[1,1-diphenyl-, stereoisomer
  • (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%,99%ee
  • 364732-88-7
  • Chiral Phosphine
  • PHANEPhos Series