Dicyclohexylborane
- Product Name
- Dicyclohexylborane
- CAS No.
- 1568-65-6
- Chemical Name
- Dicyclohexylborane
- Synonyms
- icyclohexylboron;Dicyclohexylborane;Borane, dicyclohexyl-
- CBNumber
- CB21074659
- Molecular Formula
- C12H23B
- Formula Weight
- 178.12
- MOL File
- 1568-65-6.mol
Dicyclohexylborane Property
- Melting point:
- 103-105 °C
- Boiling point:
- 263.7±23.0 °C(Predicted)
- solubility
- Soluble in THF, diethyl ether, dichloromethane, and pentane.
Safety
- Hazard Codes
- F,C
- Risk Statements
- 17-34
- Safety Statements
- 16-23-26-36/37/39-45
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H250Catches fire spontaneously if exposed to air
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222Do not allow contact with air.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P334IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P321Specific treatment (see … on this label).
P363Wash contaminated clothing before reuse.
P370+P378In case of fire: Use … for extinction.
P405Store locked up.
P422Store contents under …
P501Dispose of contents/container to..…
Dicyclohexylborane Chemical Properties,Usage,Production
Uses
Dicyclohexylborane is a reducing reagent such as in the synthesis of chlorosulfolipid products such as deschloromytilipin A.
Synthesis Reference(s)
Journal of the American Chemical Society, 95, p. 6876, 1973 DOI: 10.1021/ja00801a081
Reactivity Profile
Dicyclohexylborane is a reagent for the reduction of ketones and α,β-unsaturated ketones; it is used for the hydroboration of alkynes, alkenes, and allenes.
Synthesis
Dicyclohexylborane is a stable white solid available via the hydroboration of cyclohexene with either Borane-Tetrahydrofuran or Borane-Dimethyl Sulfide. Recently, dicyclohexylborane has been prepared via the hydroboration of cyclohexene with borane-1,4-thioxane.
Precautions
Dicyclohexylborane must be used immediately upon generation or stored as a solid under dry nitrogen. Use in a fume hood.
Dicyclohexylborane Preparation Products And Raw materials
Raw materials
Preparation Products
Dicyclohexylborane Suppliers
- Tel
- --
- Fax
- --
- sales@chemos-group.com
- Country
- Germany
- ProdList
- 6350
- Advantage
- 71
View Lastest Price from Dicyclohexylborane manufacturers
- Product
- Dicyclohexylborane 1568-65-6
- Price
- US $1.00/ASSAYS
- Min. Order
- 1ASSAYS
- Purity
- 99.99%
- Supply Ability
- 200kg
- Release date
- 2019-12-20