1,2-Bis(dimethylsilyl)benzene

Product Name: 1,2-Bis(dimethylsilyl)benzene
CAS No.: 17985-72-7
Chemical Name: 1,2-Bis(dimethylsilyl)benzene
Synonyms: DK136;1,2-Phenylenebis;o-Bis(dimethylsilyl)benzene;1,2-Bis(dimethylsily)benzene;1,2-BIS(DIMETHYLSILYL)BENZENE;O-PHENYLEN-BIS-(DIMETHYLSILAN);o-phenylenebis(dimethylsilane);1,2-PHENYLENEBIS(DIMETHYLSILANE);Benzene, 1,2-bis(dimethylsilyl)-;1,2-Bis(dimethylsilyl)benzene >
CBNumber: CB2131670
Molecular Formula: C10H18Si2
Formula Weight: 194.42
MOL File: 17985-72-7.mol

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1,2-Bis(dimethylsilyl)benzene Property

Melting point:: <25°C
Boiling point:: 101 °C13 mm Hg(lit.)
Density: 0.898 g/mL at 25 °C(lit.)
refractive index: n20/D 1.51(lit.)
Flash point:: 158 °F
storage temp.: Inert atmosphere,Room Temperature
form: Liquid
color: Colorless to Light yellow
Specific Gravity: 0.898
Water Solubility: insoluble
Hydrolytic Sensitivity: 3: reacts with aqueous base
BRN: 2937027
InChI: InChI=1S/C10H18Si2/c1-11(2)9-7-5-6-8-10(9)12(3)4/h5-8,11-12H,1-4H3
InChIKey: QAUCEYVYCBYVDK-UHFFFAOYSA-N
SMILES: C1([SiH](C)C)=CC=CC=C1[SiH](C)C
CAS DataBase Reference: 17985-72-7(CAS DataBase Reference)

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Safety

Risk Statements: 36/37/38
Safety Statements: 23-24/25
WGK Germany: 3
F: 10
TSCA: No
HS Code: 2931.90.9010

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: B1699
Product name: 1,2-Bis(dimethylsilyl)benzene
Purity: >94.0%(GC)
Packaging: 1mL
Price: $79
Updated: 2025/07/31

TCI Chemical

Product number: B1699
Product name: 1,2-Bis(dimethylsilyl)benzene
Purity: >94.0%(GC)
Packaging: 5mL
Price: $231
Updated: 2025/07/31

TRC

Product number: D476988
Product name: 1,2-bis(Dimethylsilyl)benzene
Packaging: 500mg
Price: $110
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ORS0006020
Product name: 1,2-BIS(DIMETHYLSILYL)BENZENE
Purity: 95.00%
Packaging: 0.5G
Price: $122.9
Updated: 2021/12/16

Chem-Impex

Product number: 40498
Product name: 1,2-Bis(dimethylsilyl)benzene,94%(GC)
Purity: 94%(GC)
Packaging: 1ML
Price: $73.92
Updated: 2021/12/16

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1,2-Bis(dimethylsilyl)benzene Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

1,2-Bis(dimethylsilyl)benzene is a protecting group-reagent for amines and amino acids forming "benzostabase" derivatives. It is an important raw material and in organic synthesis.

Synthesis

1066-35-9

583-53-9

17985-72-7

General procedure for the synthesis of 1,2-bis(dimethylsilyl)benzene from dimethylmonochlorosilane and 1,2-dibromobenzene: a condenser was assembled in a dry 50 mL two-necked flask, and stirring bars, magnesium powder (99.9%, 24 mmol), lithium chloride (24 mmol), N,N'-dimethylimidazolidinone (DMI, 20 mL) and chlorodimethylsilane ( 48 mmol). After stirring the reaction mixture for 15 minutes at room temperature, 1,2-dibromobenzene (3 mmol) was added and stirring was continued for 4 hours. After completion of the reaction, the reaction was quenched with saturated sodium bicarbonate solution. The sodium bicarbonate and the resulting precipitate were removed by filtration. The filtrate was extracted with hexane (3 x 20 mL), the organic phases were combined, washed with saturated brine, dried over anhydrous sodium sulfate and concentrated by rotary evaporation. The crude product was purified by silica gel column chromatography, and the eluent was pure hexane or hexane/dichloromethane mixed solvent.

References

[1] Synthesis (Germany), 2017, vol. 49, # 11, p. 2495 - 2500
[2] Tetrahedron Letters, 2000, vol. 41, # 34, p. 6611 - 6614
[3] Tetrahedron, 1993, vol. 49, # 43, p. 9855 - 9866
[4] Journal of Organometallic Chemistry, 2018, vol. 854, p. 76 - 86
[5] Tetrahedron, 1991, vol. 47, # 47, p. 9807 - 9822

1,2-Bis(dimethylsilyl)benzene Preparation Products And Raw materials

Raw materials

Hexane Chlorodimethylsilane Tetrahydrofuran 1,2-Dibromobenzene Magnesium

Preparation Products

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1,2-Bis(dimethylsilyl)benzene Suppliers

Americas 1 China 84 Europe 1 Germany 2 India 3 Japan 2 Singapore 1 Switzerland 1 The Netherlands 1 United Kingdom 5 United States 16 Global 117

Shanghai chuqing Organosilane technology ltd

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View Lastest Price from 1,2-Bis(dimethylsilyl)benzene manufacturers

Career Henan Chemical Co

Product: 1,2-Bis(dimethylsilyl)benzene 17985-72-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-08

17985-72-7, 1,2-Bis(dimethylsilyl)benzene Related Search:

Dichlorodimethylsilane 1,3-Bis(isocyanatomethyl)benzene Benzene DIMETHYLSILANE Dimethyldimethoxysilane Diethoxydimethylsilane N,N-Dimethyl-1,4-phenylenediamine tert-Butyldimethylsilyl chloride 1,2-BIS(TRIMETHOXYSILYL)ETHANE 1,2-BIS(METHYLDIETHOXYSILYL)ETHYLENE 1,2-DIMETHYL-1,1,2,2-TETRAPHENYLDISILANE 1,2-DIMETHOXY-1,1,2,2-TETRAMETHYLDISILANE P-BIS(DIMETHYLSILYL)BENZENE,1,4-Bis(dimethylsilyl)benzene, 97+%,1,4 BIS(DIMETHYLSILYL)BENZENE MIN,1,4-BIS(DIMETHYLSILYL)BENZENE 1,2-BIS(TRIMETHYLSILYL)BENZENE 1,2-Bis(dimethylsilyl)benzene Dimethylaminobenzaldehyde 1,3-DIHYDRO-1,1,3,3-TETRAMETHYL-2,1,3-BENZOXADISILOLE 3,4,5-TRIMETHYLSILYLBENZOIC ACID METHYL ESTER

1,2-Bis(dimethylsilyl)benzene,98%

1,2-Bis(dimethylsily)benzene

O-PHENYLEN-BIS-(DIMETHYLSILAN)

1,2-BIS(DIMETHYLSILYL)BENZENE

1,2-PHENYLENEBIS(DIMETHYLSILANE)

o-phenylenebis(dimethylsilane)

1,2-BIS(DIMETHYLSILYL)BENZENE 98%

Silane, 1,2-phenylenebisdimethyl-

1,2-Phenylenebis

o-Bis(dimethylsilyl)benzene

1,2-Bis(dimethylsilyl)benzene &gt

[2-(dimethyl-λ3-silanyl)phenyl]-dimethylsilicon

Benzene, 1,2-bis(dimethylsilyl)-

2-(dimethyl-λsup3sup-silanyl)phenyl]-dimethylsilicon

DK136

17985-72-7

Si-H Compounds

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Protection & Derivatization Reagents (for Synthesis)

Protecting and Derivatizing Reagents

Protection and Derivatization

Silicon-Based

Synthetic Reagents

Protection & Derivatization Reagents (for Synthesis)

Si (Classes of Silicon Compounds)

Si-H Compounds

Silicon Compounds (for Synthesis)

Synthetic Organic Chemistry