ChemicalBook > CAS DataBase List > Chlorodimethylsilane

Chlorodimethylsilane

Product Name
Chlorodimethylsilane
CAS No.
1066-35-9
Chemical Name
Chlorodimethylsilane
Synonyms
DMCS;DMSC;DIMETHYLCHLOROSILANE;Chlorodimethylhydrosilane;CD5470;CFS-359;orodimethyL;JACS-1066-35-9;Co-Formula CFS-359;Dimethylchlorsilane
CBNumber
CB3694606
Molecular Formula
C2H7ClSi
Formula Weight
94.62
MOL File
1066-35-9.mol
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Chlorodimethylsilane Property

Melting point:
−111 °C(lit.)
Boiling point:
34.7 °C(lit.)
Density 
0.852 g/mL at 25 °C(lit.)
vapor density 
4 (vs air)
vapor pressure 
8.56 psi ( 20 °C)
refractive index 
n20/D 1.383(lit.)
Flash point:
−20 °F
storage temp. 
2-8°C
solubility 
Miscible with organic solvents.
form 
Liquid
Specific Gravity
0.868
color 
Clear colorless
explosive limit
3.0-20.0%(V)
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN 
1633434
InChIKey
YGHUUVGIRWMJGE-UHFFFAOYSA-N
CAS DataBase Reference
1066-35-9(CAS DataBase Reference)
NIST Chemistry Reference
Silane, chlorodimethyl-(1066-35-9)
EPA Substance Registry System
Silane, chlorodimethyl- (1066-35-9)
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Safety

Hazard Codes 
F,C,F+
Risk Statements 
11-34-12-35-20-14/15
Safety Statements 
16-26-36/37/39-45-9-43
RIDADR 
UN 2988 4.3/PG 1
WGK Germany 
1
10-21
TSCA 
Yes
HazardClass 
3
PackingGroup 
I
HS Code 
29310095
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H224Extremely flammable liquid and vapour

H261In contact with water releases flammable gas

H314Causes severe skin burns and eye damage

H331Toxic if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
144207
Product name
Chlorodimethylsilane
Purity
98%
Packaging
50g
Price
$68.8
Updated
2024/03/01
TCI Chemical
Product number
C0778
Product name
Chlorodimethylsilane
Purity
>95.0%(GC)
Packaging
25mL
Price
$54
Updated
2024/03/01
TCI Chemical
Product number
C0778
Product name
Chlorodimethylsilane
Purity
>95.0%(GC)
Packaging
250mL
Price
$310
Updated
2024/03/01
Alfa Aesar
Product number
A13113
Product name
Chlorodimethylsilane, 97%
Packaging
50ml
Price
$51.1
Updated
2024/03/01
Alfa Aesar
Product number
A13113
Product name
Chlorodimethylsilane, 97%
Packaging
250ml
Price
$203
Updated
2024/03/01
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Chlorodimethylsilane Chemical Properties,Usage,Production

Chemical Properties

Colorless clear liquid

Uses

Chlorodimethylsilane is used to prepare vinyldimethylsilanols for palladium-catalyzed cross-coupling with aryl iodides. Chlorodimethylsilane in combination with a tertiary amine such as triethylamine is another useful reagent for the synthesis of hydrodimethylsilyl ethers, especially for large scale preparations.

Application

The popular uses of chlorodimethylsilane are listed as below:
Will form high-boiling polymeric by-products with aqueous work-up.
A monomer ('building block') in the production of silicone polymers. Silicone polymers may be oils, greases, rubbers and resins and have a wide-range of uses.
In the electronics industry for the production of ultra-pure polysilicon and in the manufacture of semiconductors and photovoltaics.
Although the end uses of products made from chlorodimethylsilane will vary, it can be assumed that due to its highly reactive nature, no residual unreacted material will be present in any of the final products.

General Description

A colorless fuming liquid with a pungent, burning odor. Flash point -18°F. Boiling point 95°F. Density about 6.9 lb / gal. Extremely corrosive to skin and respiratory tissues, both as a liquid and vapor. Vapors are heavier than air.

Air & Water Reactions

Highly flammable. Reacts violently on contact with water to liberate heat and hydrogen chloride gas.

Reactivity Profile

Chlorosilanes, such as DIMETHYLCHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.

Health Hazard

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Flammability and Explosibility

Extremely flammable

Chlorodimethylsilane Preparation Products And Raw materials

Raw materials

Preparation Products

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Chlorodimethylsilane Suppliers

Shanghai Gileader Advanced Material Technology Co.,Ltd
Tel
021-69980372 18516111942
Email
823898732@qq.com
Country
China
ProdList
1336
Advantage
56
Hubei xingongli Chemical Co., Ltd
Tel
027-59503710 15172325309
Fax
027-59503710
Email
1400858877@qq.com
Country
China
ProdList
9965
Advantage
58
Wuhan Hongde Yuexin Pharmaceutical Technology Co., Lt
Tel
027-83855392 15827396479
Fax
QQ:2265885441
Email
wuhanfudechem03@sina.com
Country
China
ProdList
3027
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9555
Advantage
66
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
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View Lastest Price from Chlorodimethylsilane manufacturers

Hebei Kangcang new material Technology Co., LTD
Product
Chlorodimethylsilane 1066-35-9
Price
US $9.00-70.00/g
Min. Order
10g
Purity
99%
Supply Ability
10 tons
Release date
2024-03-27
Hebei Dangtong Import and export Co LTD
Product
Chlorodimethylsilane 1066-35-9
Price
US $1165.00-1150.00/Tons
Min. Order
1Tons
Purity
99.99%
Supply Ability
100Tons
Release date
2023-03-03
Hebei Yanxi Chemical Co., Ltd.
Product
Chlorodimethylsilane 1066-35-9
Price
US $2.60/Kg/Drum
Min. Order
16T
Purity
95%
Supply Ability
2000tons/month
Release date
2020-07-03

1066-35-9, ChlorodimethylsilaneRelated Search:


  • Co-Formula CFS-359
  • CFS-359
  • CD5470
  • chlorodimethyl-silan
  • Chlorodimethylhydrosilane
  • Dimethylchlorohydrosilane
  • Dimethylhydrosilyl chloride
  • Dimethylmonochlorosilane
  • chrolodimethylsilane
  • Chlorodimethylsilane,96%
  • Dimethylchlorsilane
  • Chlorodimethylsilane,DMCS, Dimethylchlorosilane
  • ChlorodiMethylsilane (GW-01)
  • ChlorodiMethylsilane, 96% 10GR
  • ChlorodiMethylsilane, 96% 50GR
  • CHLORODIMETHYLSILANE FOR SYNTHESIS
  • Chlorodimethylsilane(DMCS)
  • orodimethyL
  • DIMETHYLCHLOROSILANE GC STATIONERY PAHSE
  • Dimethylchlorosilane, DMCS
  • Dimethylchlorosilane(Chlorodimethylsilane)
  • Silane, chlorodimethyl-
  • DIMETHYLHYDROGENCHLOROSILANE
  • dimethylchlorosilane(flammableliquids,corrosive,n.o.s.)
  • CHLORODIMETHYLSILANE
  • DIMETHYLSILYL CHLORIDE
  • DIMETHYLCHLOROSILANE
  • DMSC
  • DMCS
  • JACS-1066-35-9
  • Chlorodimethylsilane &gt
  • chloro(dimethyl)silicon
  • 1066-35-9
  • CH32SiHCl
  • C2H7ClSi
  • Dimethylsilylation (GC Derivatizing Reagents)
  • Monochlorosilanes
  • Si (Classes of Silicon Compounds)
  • Silylation (GC Derivatizing Reagents)
  • Si-H Compounds
  • Reduction
  • GC Derivatizing Reagents
  • Si-Cl Compounds
  • Protection and Derivatization
  • Protecting and Derivatizing Reagents
  • Silicon-Based
  • Synthetic Reagents
  • Indolines ,Indoles
  • Dimethylsilylation (GC Derivatizing Reagents)
  • Analytical Chemistry
  • GC Derivatizing Reagents
  • Monochlorosilanes
  • Reduction
  • Si (Classes of Silicon Compounds)
  • Si-Cl Compounds
  • Si-H Compounds
  • Silylation (GC Derivatizing Reagents)
  • Synthetic Organic Chemistry