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3-MORPHOLIN-4-YLMETHYLBENZOIC ACID

Product Name
3-MORPHOLIN-4-YLMETHYLBENZOIC ACID
CAS No.
67451-81-4
Chemical Name
3-MORPHOLIN-4-YLMETHYLBENZOIC ACID
Synonyms
AKOS BB-9413;3-(Morpholinomethyl);3-(Morpholinomethyl)benzoic Acid;3-MORPHOLIN-4-YLMETHYLBENZOIC ACID;3-(4-Morpholinylmethyl)Benzoic acid;3-Morpholin-4-ylmethylbenzoicacid95%;Benzoic acid, 3-(4-morpholinylmethyl)-;3-MORPHOLIN-4-YLMETHYLBENZOIC ACID 95%
CBNumber
CB2145934
Molecular Formula
C12H15NO3
Formula Weight
221.25
MOL File
67451-81-4.mol
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3-MORPHOLIN-4-YLMETHYLBENZOIC ACID Property

Boiling point:
376.9±32.0 °C(Predicted)
Density 
1.233±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
3.98±0.10(Predicted)
Appearance
White to off-white Solid
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Safety

Hazard Codes 
Xn
Risk Statements 
22
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC
Product number
M732740
Product name
3-(Morpholinomethyl)benzoicAcid
Packaging
500mg
Price
$155
Updated
2021/12/16
Matrix Scientific
Product number
071860
Product name
3-Morpholin-4-ylmethylbenzoic acid
Purity
95+%
Packaging
1g
Price
$347
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
COR0002485
Product name
3-MORPHOLIN-4-YLMETHYLBENZOIC ACID
Purity
95.00%
Packaging
1G
Price
$258.3
Updated
2021/12/16
Matrix Scientific
Product number
071860
Product name
3-Morpholin-4-ylmethylbenzoic acid
Purity
95+%
Packaging
5g
Price
$998
Updated
2021/12/16
Matrix Scientific
Product number
071860
Product name
3-Morpholin-4-ylmethylbenzoic acid
Purity
95+%
Packaging
10g
Price
$1519
Updated
2021/12/16
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3-MORPHOLIN-4-YLMETHYLBENZOIC ACID Chemical Properties,Usage,Production

Synthesis

190660-95-8

67451-81-4

General procedure for the synthesis of 3-morpholin-4-ylmethylbenzoic acid from methyl 3-(4-morpholinylmethyl)benzoate: to a solution of methyl 3-(4-morpholinylmethyl)benzoate (5.02 g, 21.0 mmol) in methanol (100 mL) was added a sodium hydroxide solution (21.0 mL, 42.0 mmol, 2M). The reaction mixture was heated at 50 °C with stirring for 16 hours. After completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was adjusted to pH=3 with 1M hydrochloric acid and the resulting suspension was subsequently filtered. The collected solid was dissolved in acetonitrile (15 mL) and concentrated to afford 3-(morpholin-4-ylmethyl)benzoic acid (4.6 g, 100% yield) as a white solid, which was used directly in the subsequent reaction without further purification.

References

[1] Patent: WO2018/169777, 2018, A1. Location in patent: Paragraph 0229

3-MORPHOLIN-4-YLMETHYLBENZOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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3-MORPHOLIN-4-YLMETHYLBENZOIC ACID Suppliers

Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
AKos Consulting & Solutions GmbH
Tel
--
Fax
--
Email
akos@akosgmbh.de
Country
Germany
ProdList
6717
Advantage
72