6-BROMO-BENZO[B]THIOPHENE

Product Name: 6-BROMO-BENZO[B]THIOPHENE
CAS No.: 17347-32-9
Chemical Name: 6-BROMO-BENZO[B]THIOPHENE
Synonyms: 6-bromobenzothiophene;6-Bromo-1-benzothiophene;6-BROMO-BENZO[B]THIOPHENE;Benzo[b]thiophene, 6-bromo-;6-Bromobenzo[b]thiophene;6-Bromobenzothiophene in isooctane;Brexpiprazole Impurity 20 ,6-bromobenzo[b]thiophene
CBNumber: CB21477838
Molecular Formula: C8H5BrS
Formula Weight: 213.09
MOL File: 17347-32-9.mol

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6-BROMO-BENZO[B]THIOPHENE Property

Melting point:: 56.0 to 60.0 °C
Boiling point:: 140°C/30mmHg(lit.)
Density: 1.649±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: powder to crystal
color: White to Light yellow
InChI: InChI=1S/C8H5BrS/c9-7-2-1-6-3-4-10-8(6)5-7/h1-5H
InChIKey: OQIMJOXSDVGEBU-UHFFFAOYSA-N
SMILES: C12=CC(Br)=CC=C1C=CS2

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Safety

Hazard Codes: Xn
Risk Statements: 22-36
Safety Statements: 26
WGK Germany: 3
HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H319Causes serious eye irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 738328
Product name: 6-Bromobenzo[b]thiophene
Purity: 97%
Packaging: 1g
Price: $64
Updated: 2025/07/31

TCI Chemical

Product number: B5523
Product name: 6-Bromobenzo[b]thiophene
Purity: >95.0%(GC)
Packaging: 1g
Price: $125
Updated: 2025/07/31

TRC

Product number: B184975
Product name: 6-Bromobenzo[b]thiophene
Packaging: 1g
Price: $70
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB144117
Product name: 6-Bromobenzo[b]thiophene
Packaging: 1g
Price: $80
Updated: 2021/12/16

AK Scientific

Product number: W3787
Product name: 6-bromobenzothiophene
Packaging: 1g
Price: $89
Updated: 2021/12/16

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6-BROMO-BENZO[B]THIOPHENE Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Uses

6-Bromobenzo[b]thiophene is a reagent for the synthesis of aminobenzo[b]thiophene 1,1-dioxides as STAT3 inhibitors with antitumor activities being an attractive therapeutic target for cancer therapy.

Synthesis

19075-58-2

17347-32-9

Part C. Preparation of 6-bromobenzo[b]thiophene. 6-Bromobenzo[b]thiophene-2-carboxylic acid (0.70 g, 2.73 mmol) from Part B was mixed with DBU (1.35 mL, 8.94 mmol) in DMA (6 mL) in a sealed tube and heated in a microwave reactor for 70 min at 200 °C. After completion of the reaction, the resulting dark solution was diluted with 1 M HCl (20 mL) and extracted with dichloromethane (2 x 20 mL). The organic layers were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography using dichloromethane as eluent to afford 6-bromobenzo[b]thiophene as an oil (0.484 g, 83% yield).

References

[1] Journal of Medicinal Chemistry, 2016, vol. 59, # 1, p. 264 - 281
[2] Tetrahedron Letters, 2004, vol. 45, # 52, p. 9645 - 9647
[3] Patent: WO2009/39134, 2009, A1. Location in patent: Page/Page column 159
[4] Patent: WO2012/149413, 2012, A1. Location in patent: Page/Page column 59
[5] European Journal of Medicinal Chemistry, 2017, vol. 125, p. 538 - 550

6-BROMO-BENZO[B]THIOPHENE Preparation Products And Raw materials

Raw materials

Preparation Products

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6-BROMO-BENZO[B]THIOPHENE Suppliers

Americas 1 China 196 Europe 1 India 5 Japan 1 Slovakia 1 United Kingdom 2 United States 13 Global 220

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China Langchem Inc.

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View Lastest Price from 6-BROMO-BENZO[B]THIOPHENE manufacturers

Career Henan Chemical Co

Product: 6-BROMO-BENZO[B]THIOPHENE 17347-32-9
Price: US $0.10/KG
Min. Order: 1KG
Purity: 95%-99%
Supply Ability: 500kg
Release date: 2019-12-24

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6-BROMO-BENZO[B]THIOPHENE

6-bromobenzothiophene

6-Bromo-1-benzothiophene

Brexpiprazole Impurity 20 ,6-bromobenzo[b]thiophene

Benzo[b]thiophene, 6-bromo-

6-Bromobenzothiophene in isooctane

6-Bromobenzo[<i>b</i>]thiophene

17347-32-9