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6-BROMO-O-CRESOL

Product Name
6-BROMO-O-CRESOL
CAS No.
13319-71-6
Chemical Name
6-BROMO-O-CRESOL
Synonyms
6-BROMO-O-CRESOL;6-Bromo-o-cresol >6-Bromo-2-methylphenol;2-methyl-6-bromophenol;2-Bromo-6-methylphenol;6-Bromo-o-cresol;Phenol,2-broMo-6-Methyl-;2-Bromo-6-methylphenol96%;2-Bromo-6-methylphenol 96%;6-BroMo-o-cresol,2-BroMo-6-Methylphenol
CBNumber
CB21478981
Molecular Formula
C7H7BrO
Formula Weight
187.03
MOL File
13319-71-6.mol
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6-BROMO-O-CRESOL Property

Melting point:
16 °C
Boiling point:
208 °C
Density 
1.51
refractive index 
1.5680-1.5720
Flash point:
80°
storage temp. 
Inert atmosphere,Room Temperature
form 
clear liquid
pka
8.78±0.10(Predicted)
color 
Colorless to Light orange to Yellow
InChIKey
YXZPTVOCJLCMRO-UHFFFAOYSA-N
CAS DataBase Reference
13319-71-6
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Safety

HS Code 
2908190090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3126
Product name
6-Bromo-o-cresol
Purity
>94.0%(GC)
Packaging
5g
Price
$177
Updated
2025/07/31
TCI Chemical
Product number
B3126
Product name
6-Bromo-o-cresol
Purity
>94.0%(GC)
Packaging
25g
Price
$622
Updated
2025/07/31
TRC
Product number
B697420
Product name
2-Bromo-6-methylphenol
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
B697420
Product name
2-Bromo-6-methylphenol
Packaging
500mg
Price
$65
Updated
2021/12/16
Matrix Scientific
Product number
115209
Product name
2-Bromo-6-methylphenol
Purity
96+%
Packaging
5g
Price
$89
Updated
2021/12/16
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6-BROMO-O-CRESOL Chemical Properties,Usage,Production

Synthesis

95-48-7

13319-71-6

The general procedure for the synthesis of 2-bromo-6-methylphenol from o-cresol is as follows: Example 36 Synthesis of 2-bromo-6-methylphenol To a dichloromethane (500 mL) solution of o-cresol (20.0 g, 0.19 mol) and diisopropylamine (2.63 mL, 18.5 mmol), a dichloromethane (500 mL) solution of N-bromosuccinimide (NBS, 32.9 g, 0.19 mol) was slowly added dropwise, and the dropwise process lasted for 7 hours. After completion of the titration, the reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the reaction mixture was acidified to pH=1 with concentrated hydrochloric acid and subsequently diluted by adding sulfuric acid and water (400 mL). The organic layer was separated, dried with anhydrous sodium sulfate, and concentrated under reduced pressure to remove the solvent to give 34.6 g of crude product in 97% yield. The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 2.30 (s, 3H), 5.54 (s, 2H), 6.71 (t, J=7.6 Hz, 1H), 7.05 (d, J=7.6 Hz, 1H), 7.28 (d, J=8.0 Hz, 1H).

References

[1] Advanced Synthesis and Catalysis, 2008, vol. 350, # 9, p. 1309 - 1315
[2] Patent: US2009/203657, 2009, A1. Location in patent: Page/Page column 51
[3] Patent: US2009/197871, 2009, A1. Location in patent: Page/Page column 54
[4] Chemistry - A European Journal, 2018, vol. 24, # 10, p. 2379 - 2383
[5] Tetrahedron Letters, 1998, vol. 39, # 19, p. 2947 - 2950

6-BROMO-O-CRESOL Preparation Products And Raw materials

Raw materials

Preparation Products

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6-BROMO-O-CRESOL Suppliers

Americas 1 China 110 Europe 1 Germany 3 India 6 Japan 1 United Kingdom 3 United States 9 Global 134
TCI Chemicals (India) Pvt. Ltd.
Tel
--
Fax
--
Email
sales-in@tcichemicals.com
Country
India
ProdList
6768
Advantage
58
CLEANCHEM LABORATORIES LLP
Tel
--
Fax
--
Email
sales4@cleanchemlab.com
Country
India
ProdList
325
Advantage
58
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
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View Lastest Price from 6-BROMO-O-CRESOL manufacturers

Career Henan Chemical Co
Product
6-BROMO-O-CRESOL 13319-71-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-12

13319-71-6, 6-BROMO-O-CRESOLRelated Search:

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  • 13319-71-6