ChemicalBook > CAS DataBase List > 3-BROMO-4-NITROANISOLE

3-BROMO-4-NITROANISOLE

Product Name
3-BROMO-4-NITROANISOLE
CAS No.
98447-30-4
Chemical Name
3-BROMO-4-NITROANISOLE
Synonyms
3-Methoxy-6-nitrobrom;3-Methoxy-6-nitrobromobenzene;2-Bromo-4-methoxynitrobenzene;Benzene, 2-bromo-4-methoxy-1-nitro-
CBNumber
CB21484320
Molecular Formula
C7H6BrNO3
Formula Weight
232.03
MOL File
98447-30-4.mol
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3-BROMO-4-NITROANISOLE Property

Melting point:
69℃
storage temp. 
Sealed in dry,Room Temperature
Appearance
Off-white to light yellow Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B700690
Product name
2-Bromo-4-methoxy-1-nitrobenzene
Packaging
500mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB70174
Product name
3-Bromo-4-nitroanisole
Packaging
5G
Price
$75
Updated
2021/12/16
ChemScene
Product number
CS-W005563
Product name
2-Bromo-4-methoxy-1-nitrobenzene
Purity
99.18%
Packaging
1g
Price
$33
Updated
2021/12/16
ChemScene
Product number
CS-W005563
Product name
2-Bromo-4-methoxy-1-nitrobenzene
Purity
99.18%
Packaging
5g
Price
$104
Updated
2021/12/16
AK Scientific
Product number
V9911
Product name
2-Bromo-4-methoxy-1-nitrobenzene
Packaging
1g
Price
$107
Updated
2021/12/16
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3-BROMO-4-NITROANISOLE Chemical Properties,Usage,Production

Synthesis

1882-69-5

98447-30-4

General procedure for the synthesis of 3-bromo-4-nitroanisole from 5-methoxy-2-nitrobenzoic acid: silver sulfate (6.2 mg), copper acetate (36.3 mg), 2,9-dimethyl-1,10-o-phenanthroline (12.5 mg), 5-methoxy-2-nitrobenzoic acid (39.4 mg), and sodium bromide (30.9 mg), followed by the addition of 4 mL of dimethyl sulfoxide (DMSO) as solvent. The reaction mixture was heated to 160°C under oxygen atmosphere and stirred for 24 hours. After completion of the reaction, the reaction was quenched by the addition of distilled water and extracted three times with ethyl acetate (10 mL each time). The organic phases were combined and concentrated to afford 3-bromo-4-nitroanisole (20.4 mg) in 44% yield.

References

[1] Journal of Organic Chemistry, 2016, vol. 81, # 7, p. 2794 - 2803
[2] Patent: CN107325002, 2017, A. Location in patent: Paragraph 0133
[3] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421
[4] Tetrahedron Letters, 2010, vol. 51, # 50, p. 6646 - 6648

3-BROMO-4-NITROANISOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-4-NITROANISOLE Suppliers

Yangzhou Siyu Chemical Co.,Ltd.
Tel
0514-87325867
Fax
0086-514-87325867
Email
sales@siyuchem.com
Country
China
ProdList
370
Advantage
55
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Beijing Eternalchem Co,. Ltd.
Tel
010-59484199 18611897322
Email
sales@eternalchem.com
Country
China
ProdList
4383
Advantage
60
Hangzhou Sage Chemical Co., Ltd.
Tel
+86057186818502 13588463833
Fax
Pls mail us for more information!
Email
info@sagechem.com
Country
China
ProdList
10266
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58
Candia Thamtech Company Limited
Tel
0371-86615086 18203638366 0371-86159066 13526786601
Fax
0371-86159066
Country
China
ProdList
2015
Advantage
60
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
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Jalor-Chem co.,LTD
Tel
0510-0510-86396359 13382276200
Email
sales@jalor-chem.com
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China
ProdList
996
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56
Nanjing Credit Trading Co.,Ltd
Tel
025-52164950
Fax
025-86800069
Email
Googlexu_0114@sina.com
Country
China
ProdList
644
Advantage
58
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
ShangHai KenEn Chemical Technology Co., Ltd.
Tel
13120367189
Fax
021-50315529
Email
mychess007@163.com
Country
China
ProdList
1994
Advantage
55
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View Lastest Price from 3-BROMO-4-NITROANISOLE manufacturers

Career Henan Chemical Co
Product
3-BROMO-4-NITROANISOLE 98447-30-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11