3-BROMO-4-NITROANISOLE
- Product Name
- 3-BROMO-4-NITROANISOLE
- CAS No.
- 98447-30-4
- Chemical Name
- 3-BROMO-4-NITROANISOLE
- Synonyms
- 3-Methoxy-6-nitrobrom;3-Methoxy-6-nitrobromobenzene;2-Bromo-4-methoxynitrobenzene;Benzene, 2-bromo-4-methoxy-1-nitro-
- CBNumber
- CB21484320
- Molecular Formula
- C7H6BrNO3
- Formula Weight
- 232.03
- MOL File
- 98447-30-4.mol
3-BROMO-4-NITROANISOLE Property
- Melting point:
- 69℃
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Off-white to light yellow Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B700690
- Product name
- 2-Bromo-4-methoxy-1-nitrobenzene
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FB70174
- Product name
- 3-Bromo-4-nitroanisole
- Packaging
- 5G
- Price
- $75
- Updated
- 2021/12/16
- Product number
- CS-W005563
- Product name
- 2-Bromo-4-methoxy-1-nitrobenzene
- Purity
- 99.18%
- Packaging
- 1g
- Price
- $33
- Updated
- 2021/12/16
- Product number
- CS-W005563
- Product name
- 2-Bromo-4-methoxy-1-nitrobenzene
- Purity
- 99.18%
- Packaging
- 5g
- Price
- $104
- Updated
- 2021/12/16
- Product number
- V9911
- Product name
- 2-Bromo-4-methoxy-1-nitrobenzene
- Packaging
- 1g
- Price
- $107
- Updated
- 2021/12/16
3-BROMO-4-NITROANISOLE Chemical Properties,Usage,Production
Synthesis
1882-69-5
98447-30-4
General procedure for the synthesis of 3-bromo-4-nitroanisole from 5-methoxy-2-nitrobenzoic acid: silver sulfate (6.2 mg), copper acetate (36.3 mg), 2,9-dimethyl-1,10-o-phenanthroline (12.5 mg), 5-methoxy-2-nitrobenzoic acid (39.4 mg), and sodium bromide (30.9 mg), followed by the addition of 4 mL of dimethyl sulfoxide (DMSO) as solvent. The reaction mixture was heated to 160°C under oxygen atmosphere and stirred for 24 hours. After completion of the reaction, the reaction was quenched by the addition of distilled water and extracted three times with ethyl acetate (10 mL each time). The organic phases were combined and concentrated to afford 3-bromo-4-nitroanisole (20.4 mg) in 44% yield.
References
[1] Journal of Organic Chemistry, 2016, vol. 81, # 7, p. 2794 - 2803
[2] Patent: CN107325002, 2017, A. Location in patent: Paragraph 0133
[3] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421
[4] Tetrahedron Letters, 2010, vol. 51, # 50, p. 6646 - 6648
3-BROMO-4-NITROANISOLE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-BROMO-4-NITROANISOLE manufacturers
- Product
- 3-BROMO-4-NITROANISOLE 98447-30-4
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-11