2-amino-6-bromobenzonitrile

Product Name: 2-amino-6-bromobenzonitrile
CAS No.: 77326-62-6
Chemical Name: 2-amino-6-bromobenzonitrile
Synonyms: 3-Bromo-2-cyanoaniline;Bromo-6-amino-benzonitrile;2-AMINO-6-BROMOBENZONITRILE;Benzonitrile, 2-amino-6-bromo-;2-Amino-6-bromobenzonitrile,95%;2-Amino-6-bromobenzonitrile 97%
CBNumber: CB11483018
Molecular Formula: C7H5BrN2
Formula Weight: 197.03
MOL File: 77326-62-6.mol

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2-amino-6-bromobenzonitrile Property

Melting point:: 152-154℃
Boiling point:: 343.3±32.0 °C(Predicted)
Density: 1.68
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 0.74±0.10(Predicted)
form: Powder
color: Off-white
CAS DataBase Reference: 77326-62-6

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Safety

HazardClass: IRRITANT
HazardClass: 6.1
HS Code: 2926907090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar

Product number: H61927
Product name: 2-Amino-6-bromobenzonitrile, 95%
Packaging: 1g
Price: $80.2
Updated: 2021/12/16

Alfa Aesar

Product number: H61927
Product name: 2-Amino-6-bromobenzonitrile, 95%
Packaging: 5g
Price: $319
Updated: 2021/12/16

Alfa Aesar

Product number: H61927
Product name: 2-Amino-6-bromobenzonitrile, 95%
Packaging: 250mg
Price: $27
Updated: 2021/12/16

TRC

Product number: A578790
Product name: 2-Amino-6-bromobenzonitrile
Packaging: 5g
Price: $130
Updated: 2021/12/16

Matrix Scientific

Product number: 066622
Product name: 2-Amino-6-bromobenzonitrile
Purity: 98%
Packaging: 25g
Price: $148
Updated: 2021/12/16

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2-amino-6-bromobenzonitrile Chemical Properties,Usage,Production

Uses

2-amino-6-bromobenzonitrile is a versatile building block that can be used to create a range of compounds, such as 4'-methoxy-3-(phenylethynyl)-[1,1'-biphenyl]-2-carbonitrile, etc.
Substituted phenylboronic acid (6 mmol), 2-amino-6-bromobenzonitrile (5 mmol), PdCl2(PPh3)2 (35.0 mg, 0.05 mmol) and Cs2CO3 (4.89 g, 15.0 mmol) were added in CH3CN (20 mL) and H2O (1.6 mL). The reaction mixture was stirred at 80 she℃ under an argon atmosphere for 12 h. After the reaction, the mixture was cooled to room temperature and extracted with EtOAc (40 × 3 mL). The combined organic phase was washed with brine (40 mL), and dried over anhydrous MgSO4. The solvent was removed under vacuum to give the crude product C without further purification.

References

[1] Zhou, Nengneng et al. “TBPB-initiated cascade cyclization of 3-arylethynyl-[1,1′-biphenyl]-2-carbonitriles with sulfinic acids: access to sulfone-containing cyclopenta[gh]phenanthridines?.” Organic & Biomolecular Chemistry 9 (2020): 1733–1737.

2-amino-6-bromobenzonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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2-amino-6-bromobenzonitrile Suppliers

China 116 India 2 Switzerland 1 United Kingdom 3 United States 10 Global 132

Alfa Aesar

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View Lastest Price from 2-amino-6-bromobenzonitrile manufacturers

Honest Joy Holdings Limited

Product: 2-Amino-6-bromobenzonitrile 77326-62-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.3%
Supply Ability: 100 tons
Release date: 2022-01-14

Career Henan Chemical Co

Product: 2-AMINO-6-BROMOBENZONITRILE 77326-62-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-11

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77326-62-6