2-amino-6-bromobenzonitrile
- Product Name
- 2-amino-6-bromobenzonitrile
- CAS No.
- 77326-62-6
- Chemical Name
- 2-amino-6-bromobenzonitrile
- Synonyms
- 3-Bromo-2-cyanoaniline;Bromo-6-amino-benzonitrile;2-AMINO-6-BROMOBENZONITRILE;Benzonitrile, 2-amino-6-bromo-;2-Amino-6-bromobenzonitrile,95%;2-Amino-6-bromobenzonitrile 97%
- CBNumber
- CB11483018
- Molecular Formula
- C7H5BrN2
- Formula Weight
- 197.03
- MOL File
- 77326-62-6.mol
2-amino-6-bromobenzonitrile Property
- Melting point:
- 152-154℃
- Boiling point:
- 343.3±32.0 °C(Predicted)
- Density
- 1.68
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- pka
- 0.74±0.10(Predicted)
- form
- Powder
- color
- Off-white
- CAS DataBase Reference
- 77326-62-6
Safety
- HazardClass
- IRRITANT
- HazardClass
- 6.1
- HS Code
- 2926907090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- H61927
- Product name
- 2-Amino-6-bromobenzonitrile, 95%
- Packaging
- 1g
- Price
- $80.2
- Updated
- 2021/12/16
- Product number
- H61927
- Product name
- 2-Amino-6-bromobenzonitrile, 95%
- Packaging
- 5g
- Price
- $319
- Updated
- 2021/12/16
- Product number
- H61927
- Product name
- 2-Amino-6-bromobenzonitrile, 95%
- Packaging
- 250mg
- Price
- $27
- Updated
- 2021/12/16
- Product number
- A578790
- Product name
- 2-Amino-6-bromobenzonitrile
- Packaging
- 5g
- Price
- $130
- Updated
- 2021/12/16
- Product number
- 066622
- Product name
- 2-Amino-6-bromobenzonitrile
- Purity
- 98%
- Packaging
- 1g
- Price
- $17
- Updated
- 2021/12/16
2-amino-6-bromobenzonitrile Chemical Properties,Usage,Production
Uses
2-amino-6-bromobenzonitrile is a versatile building block that can be used to create a range of compounds, such as 4'-methoxy-3-(phenylethynyl)-[1,1'-biphenyl]-2-carbonitrile, etc.
Substituted phenylboronic acid (6 mmol), 2-amino-6-bromobenzonitrile (5 mmol), PdCl2(PPh3)2 (35.0 mg, 0.05 mmol) and Cs2CO3 (4.89 g, 15.0 mmol) were added in CH3CN (20 mL) and H2O (1.6 mL). The reaction mixture was stirred at 80 she℃ under an argon atmosphere for 12 h. After the reaction, the mixture was cooled to room temperature and extracted with EtOAc (40 × 3 mL). The combined organic phase was washed with brine (40 mL), and dried over anhydrous MgSO4. The solvent was removed under vacuum to give the crude product C without further purification.
References
[1] Zhou, Nengneng et al. “TBPB-initiated cascade cyclization of 3-arylethynyl-[1,1′-biphenyl]-2-carbonitriles with sulfinic acids: access to sulfone-containing cyclopenta[gh]phenanthridines?.” Organic & Biomolecular Chemistry 9 (2020): 1733–1737.
2-amino-6-bromobenzonitrile Preparation Products And Raw materials
Raw materials
Preparation Products
2-amino-6-bromobenzonitrile Suppliers
- Tel
- --
- Fax
- --
- contact@achemica.com
- Country
- Switzerland
- ProdList
- 6155
- Advantage
- 50
View Lastest Price from 2-amino-6-bromobenzonitrile manufacturers
- Product
- 2-Amino-6-bromobenzonitrile 77326-62-6
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99.3%
- Supply Ability
- 100 tons
- Release date
- 2022-01-14
- Product
- 2-AMINO-6-BROMOBENZONITRILE 77326-62-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-11