ChemicalBook > CAS DataBase List > 2-amino-6-bromobenzonitrile

2-amino-6-bromobenzonitrile

Product Name
2-amino-6-bromobenzonitrile
CAS No.
77326-62-6
Chemical Name
2-amino-6-bromobenzonitrile
Synonyms
3-Bromo-2-cyanoaniline;Bromo-6-amino-benzonitrile;2-AMINO-6-BROMOBENZONITRILE;Benzonitrile, 2-amino-6-bromo-;2-Amino-6-bromobenzonitrile,95%;2-Amino-6-bromobenzonitrile 97%
CBNumber
CB11483018
Molecular Formula
C7H5BrN2
Formula Weight
197.03
MOL File
77326-62-6.mol
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2-amino-6-bromobenzonitrile Property

Melting point:
152-154℃
Boiling point:
343.3±32.0 °C(Predicted)
Density 
1.68
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
0.74±0.10(Predicted)
form 
Powder
color 
Off-white
CAS DataBase Reference
77326-62-6
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Safety

HazardClass 
IRRITANT
HazardClass 
6.1
HS Code 
2926907090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
H61927
Product name
2-Amino-6-bromobenzonitrile, 95%
Packaging
1g
Price
$80.2
Updated
2021/12/16
Alfa Aesar
Product number
H61927
Product name
2-Amino-6-bromobenzonitrile, 95%
Packaging
5g
Price
$319
Updated
2021/12/16
Alfa Aesar
Product number
H61927
Product name
2-Amino-6-bromobenzonitrile, 95%
Packaging
250mg
Price
$27
Updated
2021/12/16
TRC
Product number
A578790
Product name
2-Amino-6-bromobenzonitrile
Packaging
5g
Price
$130
Updated
2021/12/16
Matrix Scientific
Product number
066622
Product name
2-Amino-6-bromobenzonitrile
Purity
98%
Packaging
1g
Price
$17
Updated
2021/12/16
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2-amino-6-bromobenzonitrile Chemical Properties,Usage,Production

Uses

2-amino-6-bromobenzonitrile is a versatile building block that can be used to create a range of compounds, such as 4'-methoxy-3-(phenylethynyl)-[1,1'-biphenyl]-2-carbonitrile, etc.
Substituted phenylboronic acid (6 mmol), 2-amino-6-bromobenzonitrile (5 mmol), PdCl2(PPh3)2 (35.0 mg, 0.05 mmol) and Cs2CO3 (4.89 g, 15.0 mmol) were added in CH3CN (20 mL) and H2O (1.6 mL). The reaction mixture was stirred at 80 she℃ under an argon atmosphere for 12 h. After the reaction, the mixture was cooled to room temperature and extracted with EtOAc (40 × 3 mL). The combined organic phase was washed with brine (40 mL), and dried over anhydrous MgSO4. The solvent was removed under vacuum to give the crude product C without further purification.

References

[1] Zhou, Nengneng et al. “TBPB-initiated cascade cyclization of 3-arylethynyl-[1,1′-biphenyl]-2-carbonitriles with sulfinic acids: access to sulfone-containing cyclopenta[gh]phenanthridines?.” Organic & Biomolecular Chemistry 9 (2020): 1733–1737.

2-amino-6-bromobenzonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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2-amino-6-bromobenzonitrile Suppliers

Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
India
ProdList
6905
Advantage
58
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
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View Lastest Price from 2-amino-6-bromobenzonitrile manufacturers

Honest Joy Holdings Limited
Product
2-Amino-6-bromobenzonitrile 77326-62-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99.3%
Supply Ability
100 tons
Release date
2022-01-14
Career Henan Chemical Co
Product
2-AMINO-6-BROMOBENZONITRILE 77326-62-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11

77326-62-6, 2-amino-6-bromobenzonitrileRelated Search:


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