ChemicalBook > CAS DataBase List > BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE

BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE

Product Name
BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE
CAS No.
38857-88-4
Chemical Name
BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE
Synonyms
Bis(2,2,2-trichloroethyl) azodicarboxyle;BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE;Bis(2,2,2-trichloroethyl) azodicarboxylate;BEAZ Bis(2,2,2-trichloroethyl) azodicarboxylate;BIS(2,2,2-TRICHLOROETHYL) AZODI-CARBOXYL ATE, 97+%;AZODICARBOXYLIC ACID BIS(2,2,2-TRICHLOROETHYL) ESTER;1,2-Diazenedicarboxylic acid, 1,2-bis(2,2,2-trichloroethyl) ester
CBNumber
CB2149725
Molecular Formula
C6H4Cl6N2O4
Formula Weight
380.83
MOL File
38857-88-4.mol
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BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE Property

Melting point:
109-111 °C (lit.)
Boiling point:
380.7±42.0 °C(Predicted)
Density 
1.78±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
solubility 
sol in a wide range of organic solvents.
color 
slightly yellow
BRN 
2141527
CAS DataBase Reference
38857-88-4
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
291536
Product name
Bis(2,2,2-trichloroethyl) azodicarboxylate
Purity
≥97%
Packaging
5g
Price
$209
Updated
2023/01/07
TRC
Product number
B119293
Product name
BEAZBis(2,2,2-trichloroethyl)azodicarboxylate
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
B119293
Product name
BEAZBis(2,2,2-trichloroethyl)azodicarboxylate
Packaging
500mg
Price
$110
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB01254
Product name
Bis(2,2,2-trichloroethyl) azodicarboxylate
Packaging
5G
Price
$135
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB01254
Product name
Bis(2,2,2-trichloroethyl) azodicarboxylate
Packaging
2g
Price
$60
Updated
2021/12/16
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BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE Chemical Properties,Usage,Production

Chemical Properties

Yellow powder or crystals

Uses

Bis(2,2,2-trichloroethyl) azodicarboxylate has been used:

  • in the asymmetric synthesis of substituted cycloalkyl[b]indoles
  • as amination reagent during the aza-ene reaction of different alkenes to yield the corresponding allyl amines
  • in para-directed amination of C2-alkyl substituted anisole
  • in the synthesis of acid- and base-sensitive azo compounds and in Diels-Alder cycloadditions

General Description

Thermal inverse-type hetero-Diels-Alder reaction of O-silyl-protected lactal and bis(2,2,2-trichloroethyl) azodicarboxylate has been reported.

storage

Bis(2,2,2-trichloroethyl) azodicarboxylate is same as with all azo compounds, caution should be exercised to avoid exposure of the material to heat. Store in a brown bottle.

BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE Suppliers

China 47 Germany 2 Japan 1 Switzerland 1 United Kingdom 4 United States 5 Global 60
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38857-88-4, BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATERelated Search:

AZODICARBOXYLIC ACID DIMETHYL ESTER 1,1,1-Trichloroethane BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE Chloroform Diethyl azodicarboxylate Trichloroethanol AMMONIUM CARBAMATE 4-METHOXYBENZENESULFONAMIDE

  • BIS(2,2,2-TRICHLOROETHYL) AZODI-CARBOXYL ATE, 97+%
  • AZODICARBOXYLIC ACID BIS(2,2,2-TRICHLOROETHYL) ESTER
  • BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE
  • Bis(2,2,2-trichloroethyl) azodicarboxyle
  • BEAZ Bis(2,2,2-trichloroethyl) azodicarboxylate
  • 1,2-Diazenedicarboxylic acid, 1,2-bis(2,2,2-trichloroethyl) ester
  • Bis(2,2,2-<WBR>trichloroethyl) azodicarboxylate
  • 38857-88-4
  • C6H4Cl6N2O
  • C6H4Cl6N2O4
  • CCl3CH2OCONNCOOCH2CCl3
  • Building Blocks
  • Azo/Diazo Compounds
  • C-X Bond Formation (Non-Halogen)
  • Mitsunobu
  • Organic Building Blocks
  • Nitrogen Compounds
  • Synthetic Reagents