methyl 4-(bromomethyl)-2-methoxybenzoate

Product Name: methyl 4-(bromomethyl)-2-methoxybenzoate
CAS No.: 74733-27-0
Chemical Name: methyl 4-(bromomethyl)-2-methoxybenzoate
Synonyms: )-2-methoxybenzoate;Oxirane, 2-[7-(phenylMethoxy)ethyl]-;methyl 4-(bromomethyl)-2-methoxybenzoate;Methyl 2-Methoxy-4-(bromomethyl)benzoate;4-broMoMethyl-2-Methoxy benzoic acid Methyl ester;2-Methoxy-4-(broMoMethyl)benzoic acid Methyl ester;Benzoic acid, 4-(bromomethyl)-2-methoxy-, methyl ester
CBNumber: CB21561317
Molecular Formula: C10H11BrO3
Formula Weight: 259.1
MOL File: 74733-27-0.mol

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methyl 4-(bromomethyl)-2-methoxybenzoate Property

Boiling point:: 142-146 °C(Press: 1.8 Torr)
Density: 1.432±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: White to off-white Solid
InChI: InChI=1S/C10H11BrO3/c1-13-9-5-7(6-11)3-4-8(9)10(12)14-2/h3-5H,6H2,1-2H3
InChIKey: DCXFLSHDURQRML-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C(CBr)C=C1OC

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M296535
Product name: Methyl4-(Bromomethyl)-2-methoxybenzoate
Packaging: 50mg
Price: $60
Updated: 2021/12/16

AK Scientific

Product number: W8234
Product name: Methyl4-(bromomethyl)-2-methoxybenzoate
Packaging: 1g
Price: $124
Updated: 2021/12/16

Matrix Scientific

Product number: 119176
Product name: Methyl 4-(bromomethyl)-2-methoxybenzoate
Purity: 95+%
Packaging: 1g
Price: $143
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0048921
Product name: METHYL 4-(BROMOMETHYL)-2-METHOXYBENZOATE
Purity: 95.00%
Packaging: 1G
Price: $195.3
Updated: 2021/12/16

Matrix Scientific

Product number: 119176
Product name: Methyl 4-(bromomethyl)-2-methoxybenzoate
Purity: 95+%
Packaging: 5g
Price: $571
Updated: 2021/12/16

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methyl 4-(bromomethyl)-2-methoxybenzoate Chemical Properties,Usage,Production

Synthesis

81245-24-1

74733-27-0

General procedure for the synthesis of methyl 4-bromomethyl-2-methoxybenzoate from methyl 2-methoxy-4-methylbenzoate: over a period of 1.5 h, bromine (6.19 mL, 120 mmol) was slowly added dropwise over a period of 1.5 h to a reflux mixture of methyl 2-methoxy-4-methylbenzoate (21.625 g, 120 mmol) in carbon tetrachloride (240 mL) dissolved in a carbon tetrachloride (75 mL). During the dropwise addition, the reaction mixture was irradiated using a 250W tungsten lamp. After dropwise addition, the reaction was continued at reflux for 15 minutes. Upon completion of the reaction, the mixture was concentrated and the solvent was removed under vacuum to afford methyl 4-bromomethyl-2-methoxybenzoate as an oily product (29.864 g, 96% yield). The product was confirmed by NMR hydrogen spectrum (400 MHz, CDCl3): δ 2.40 (s, 3H), 3.87 (s, 3H), 3.91 (s, 3H), 4.44 (s, 2H). Mass spectrometry (FIA-MS) showed the molecular ion peak m/e: 259 ([M+1]+).

References

[1] Patent: WO2004/108677, 2004, A1. Location in patent: Page 199
[2] Synlett, 2014, vol. 25, # 17, p. 2485 - 2487
[3] Patent: US2009/209586, 2009, A1. Location in patent: Page/Page column 13
[4] Patent: KR2016/20674, 2016, A. Location in patent: Paragraph 0053; 0115; 0116
[5] Bulletin de la Societe Chimique de France, 1962, p. 2255 - 2261

methyl 4-(bromomethyl)-2-methoxybenzoate Preparation Products And Raw materials

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View Lastest Price from methyl 4-(bromomethyl)-2-methoxybenzoate manufacturers

Huida Pharmaceutical Technology (Shanghai) Co., Ltd.

Product: methyl 4-(bromomethyl)-2-methoxybenzoate 74733-27-0
Price: US $0.00-0.00/kg
Min. Order: 0.1kg
Purity: 98%+
Supply Ability: 100kg
Release date: 2023-03-01

Huida Pharmaceutical Technology (Shanghai) Co., Ltd.

Product: methyl 4-(bromomethyl)-2-methoxybenzoate 74733-27-0
Price: US $0.00-0.00/kg
Min. Order: 0.10000000149011612kg
Purity: 98%
Supply Ability: 100kg
Release date: 2023-03-02

Career Henan Chemical Co

Product: methyl 4-(bromomethyl)-2-methoxybenzoate 74733-27-0
Price: US $6.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg, 10kg ,50kg
Release date: 2020-03-09

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74733-27-0