2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE

Product Name: 2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE
CAS No.: 13676-47-6
Chemical Name: 2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE
Synonyms: APBOA;2-(4-AMinophenyl)benzo[d]oxazol-5-aMine;5ABO;AKOS BB-8278;ASISCHEM Y80324;ART-CHEM-BB B025308;TIMTEC-BB SBB009788;2-(4-aminophenyl)-1,3-ben;2-(4-Aminophenyl)benzoxazol-5-amine;2-(4-Aminophenyl)-5-aminobenzoxazole
CBNumber: CB2177018
Molecular Formula: C13H11N3O
Formula Weight: 225.25
MOL File: 13676-47-6.mol

More

Less

2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE Property

Melting point:: 231-233°C
Boiling point:: 435.2±25.0 °C(Predicted)
Density: 1.329
storage temp.: Keep in dark place,Sealed in dry,2-8°C
solubility: DMSO, Methanol
form: Solid
pka: 7.49±0.10(Predicted)
color: Off-White to Tan
λmax: 310(Heptan) nm
Sensitive: Air Sensitive
InChI: InChI=1S/C13H11N3O/c14-9-3-1-8(2-4-9)13-16-11-7-10(15)5-6-12(11)17-13/h1-7H,14-15H2
InChIKey: UMGYJGHIMRFYSP-UHFFFAOYSA-N
SMILES: O1C2=CC=C(N)C=C2N=C1C1=CC=C(N)C=C1
CAS DataBase Reference: 13676-47-6

More

Less

Safety

HS Code: 2934.99.4400

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H341Suspected of causing genetic defects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P405Store locked up.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

TCI Chemical

Product number: A3300
Product name: 2-(4-Aminophenyl)benzoxazol-5-amine
Packaging: 5G
Price: $87
Updated: 2025/07/31

TCI Chemical

Product number: A3300
Product name: 2-(4-Aminophenyl)benzoxazol-5-amine
Packaging: 25G
Price: $261
Updated: 2025/07/31

TRC

Product number: A581945
Product name: 5-Amino-2-(4-aminophenyl)benzoxazole
Packaging: 100mg
Price: $130
Updated: 2021/12/16

TRC

Product number: A581945
Product name: 5-Amino-2-(4-aminophenyl)benzoxazole
Packaging: 500mg
Price: $585
Updated: 2021/12/16

TRC

Product number: A581945
Product name: 5-Amino-2-(4-aminophenyl)benzoxazole
Packaging: 1g
Price: $990
Updated: 2021/12/16

More

Less

2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE Chemical Properties,Usage,Production

Chemical Properties

Off-White to Tan Solid

Uses

2-(3-Amino-phenyl)-benzooxazol-5-ylamine can be used to prepare high-strength flexible transparent polyimide materials.

Application

2-(3-Amino-phenyl)-benzooxazol-5-ylamine is primarily used as an intermediate in organic synthesis, particularly in polymer materials and medicinal chemistry. Specifically, it can be used as a monomer in high-temperature-resistant polymers such as polyimide (PI) to prepare high-performance polymers. Furthermore, its structural properties make it useful as a reagent in biochemical research, enabling the exploration of biological processes.

Synthesis

1037-39-4

13676-47-6

General procedure for the synthesis of 2-(4-aminophenyl)-5-aminobenzo[d]oxazole from 2-(4-nitrophenyl)-5-nitrobenzo[d]oxazole: 2-(4-nitrophenyl)-5-nitrobenzo[d]oxazole (3.22 g, 0.01 mol) was added to a 100 mL single-necked flask followed by the addition of 50 mL of water at room temperature. The pH of the reaction system was adjusted with phosphoric acid to 1. Then, sodium thiosulfate solid (8.5 g, 0.06 mol) was added and the reaction system was warmed up to 100 °C for 16 h. The reaction was completed by adding a solid sodium thiosulfate (8.5 g, 0.06 mol). After completion of the reaction, it was cooled to room temperature and filtered. To the filtrate, 25% by weight of aqueous sodium carbonate was added and neutralized to pH 7. At this point, the product 2-(4-aminophenyl)-5-aminobenzo[d]oxazole was precipitated from the reaction system, and after filtration, several washes, and drying, 2.14 g of the target product was obtained (95% yield, HPLC purity >99.9%).

References

[1] Patent: CN108558770, 2018, A. Location in patent: Paragraph 0082; 0083; 0084
[2] Chemical Biology and Drug Design, 2012, vol. 79, # 6, p. 1018 - 1024
[3] Patent: TWI558696, 2016, B. Location in patent: Paragraph 0035; 0040-0041

2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE Suppliers

Americas 1 Canada 1 China 125 Europe 1 Germany 2 India 3 Japan 1 Russia 1 United Kingdom 4 United States 10 Global 149

Shanghai Yihe Biological Technology Co., Ltd.

Tel: 021-68882955 17721395025
Fax: 021-68882955
Email: 2423903095@qq.com
Country: China
ProdList: 4991
Advantage: 58

CHINATECH(TIANJIN) CHEMICAL CO.,LTD.

Tel: +86-022-83726202 18222223751
Fax: 022-83726200
Email: sales@chinatechem.com
Country: China
ProdList: 96
Advantage: 58

Hangzhou Beishengyuan Biotechnology Co., Ltd

Tel: 0571-15068777134 15068777134
Email: 1289372011@qq.com
Country: China
ProdList: 4568
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
Email: 3bsc@sina.com
Country: China
ProdList: 15838
Advantage: 69

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32321
Advantage: 50

Hunan Hui Bai Shi Biotechnology Co., Ltd.

Tel: 0731-85526065 13308475853
Email: ivy@hnhbsj.com
Country: China
ProdList: 7247
Advantage: 62

Shanghai T&W Pharmaceutical Co., Ltd.

Tel: +86 21 61551611
Fax: +86 21 50676805
Country: China
ProdList: 9891
Advantage: 58

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

More

Less

View Lastest Price from 2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: 2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE 13676-47-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-10-10

Hebei Yanxi Chemical Co., Ltd.

Product: 2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE 13676-47-6
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2023-03-09

Hebei Chuanghai Biotechnology Co,.LTD

Product: 2-(4-aminophenyl)-1,3-benzoxazol-5-amine 13676-47-6
Price: US $5.00-2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-19

13676-47-6, 2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINERelated Search:

2-(4-AMINO-PHENYL)-BENZOOXAZOL-4-YLAMINE 2-(2-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE 2-(4-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE 2-(4-AMINO-PHENYL)-BENZOOXAZOL-6-YLAMINE 2-(4-DIMETHYLAMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE 2-(4-AMINO-3-METHYL-PHENYL)-BENZOOXAZOL-5-YLAMINE 3,5-DICHLORO-N-{2-[4-(DIMETHYLAMINO)PHENYL]-1,3-BENZOXAZOL-5-YL}-4-METHOXYBENZAMIDE 2-(4-AMINO-2-CHLOROPHENYL)-1,3-BENZOXAZOL-5-AMINE [2-(4-DIMETHYLAMINO-PHENYL)-BENZOOXAZOL-5-YL]-(4-NITRO-BENZYLIDENE)-AMINE 2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE 2-([2-(4-DIMETHYLAMINO-PHENYL)-BENZOOXAZOL-5-YL-IMINO]-METHYL)-4-NITRO-PHENOL 2-(4-CHLORO-2-METHYLPHENOXY)-N-{2-[4-(DIMETHYLAMINO)PHENYL]-1,3-BENZOXAZOL-5-YL}ACETAMIDE

ASISCHEM Y80324

ART-CHEM-BB B025308

AKOS BB-8278

2-(3-AMINO-PHENYL)-BENZOOXAZOL-5-YLAMINE

TIMTEC-BB SBB009788

5-Amino-2-(4-aminophenyl)benzoxazole

5-Amino-2-(p-aminophenyl)benzoxazole

5-BenzoxazolaMine,2-(4-aMinophenyl)-

2-(4-Aminophenyl)-5-aminobenzoxazole

2-(4-AMinophenyl)benzo[d]oxazol-5-aMine

2-(4-AMINOPHENYL)-1,3-BENZOXAZOL-5-AMINE

2-(4-aminophenyl)-1,3-ben

5ABO

APBOA

2-(4-Aminophenyl)benzoxazol-5-amine

2-(4-minophenyl)-1,3-benzoxazol-5-amine (APBOA)

2-(4-minophenyl)-1,3-benzoxazol-5-amine

2-(4'- aminopheny)-5-aminobenzoxazole (BOA)

2-(4-Aminophenyl)-5-Aminobenzoxazole (APBOA)

13676-47-6

13767-47-6

Chemical Amines

Amines

Aromatics

Heterocycles

13676-47-6