SILVER PERCHLORATE

Description References

Product Name: SILVER PERCHLORATE
CAS No.: 7783-93-9
Chemical Name: SILVER PERCHLORATE
Synonyms: SILVER PERCHLORATE;SILVER (I) PERCHLORATE;SILVER PERCHLORATE 99.9%;Perchloricacid,silver(1+)salt;Silver(I)perchlorate,anhydrous;perchloricacid,silver(1++)salt;Hyperchloric acid silver(I) salt;SILVER PERCHLORATE, ANHYDROUS, 97%;Silverperchlorate,anhydrous,min.97%;SILVER PERCHLORATE, ANHYDROUS REAGENT
CBNumber: CB2180173
Molecular Formula: AgClO4
Formula Weight: 207.32
MOL File: 7783-93-9.mol

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SILVER PERCHLORATE Property

Melting point:: 486°C
Density: 2.8 g/mL at 25 °C(lit.)
solubility: benzene: slightly soluble(lit.)
form: Crystals
color: White
Specific Gravity: 2.806
Water Solubility: Soluble in water and many organic solvents (benzene, toluene, pyridine)Soluble in water, benzene and toluene.
Sensitive: Hygroscopic
Merck: 14,8523
Exposure limits: ACGIH: TWA 0.01 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.01 mg/m3
Stability:: hygroscopic
InChIKey: YDHABVNRCBNRNZ-UHFFFAOYSA-M
CAS DataBase Reference: 7783-93-9(CAS DataBase Reference)
EPA Substance Registry System: Perchloric acid, silver(1+) salt (7783-93-9)

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Safety

Hazard Codes: O,C
Risk Statements: 8-34
Safety Statements: 17-26-27-36/37/39
RIDADR: UN 1481 5.1/PG 2
WGK Germany: 3
F: 3-8-10
TSCA: Yes
HazardClass: 5.1
PackingGroup: II

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H272May intensify fire; oxidizer

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 674583
Product name: Silver perchlorate
Purity: anhydrous, 97%
Packaging: 5g
Price: $70.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 674583
Product name: Silver perchlorate
Purity: anhydrous, 97%
Packaging: 25g
Price: $249
Updated: 2024/03/01

Alfa Aesar

Product number: 042209
Product name: Silver perchlorate, anhydrous
Packaging: 5g
Price: $61.2
Updated: 2024/03/01

Alfa Aesar

Product number: 042209
Product name: Silver perchlorate, anhydrous
Packaging: 25g
Price: $223
Updated: 2024/03/01

Strem Chemicals

Product number: 93-4722
Product name: Silver perchlorate, anhydrous, min. 97%
Packaging: 5g
Price: $63
Updated: 2024/03/01

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SILVER PERCHLORATE Chemical Properties,Usage,Production

Description

Silver perchlorate (chemical formula: AgClO4) is a silver salt of perchloric acid as both a useful source of the Ag+ ion and a catalyst in the organic chemistry. It should be noted that due to the high instability and explosiveness of the anion perchlorate contained in it, it is limited for usage in industry. It is a kind of strong oxidizer and can be used to promoting the oxidation reaction in the organic synthesis. It can also be used as a catalyst for which it can be used to replace a halide with perchlorates to form intermediate in synthesis. It can be manufactured through the heating reaction of the mixture of perchloric acid with silver nitrate, the reaction between barium perchlorate and silver sulfate, or the reaction of perchloric acid with silver oxide.

References

https://en.wikipedia.org/wiki/Silver_perchlorate
http://www.softschools.com/formulas/chemistry/silver_perchlorate_formula/393/

Chemical Properties

The silver perchlorate salt, is deliquescent and forms a light-sensitive monohydrate that can be dehydrated at 43 °C and is soluble in a variety of organic solvents. Explosions of silver perchlorate have been reported.

Chemical Properties

Colorless crystals. Soluble in water; reacts with explosive violence with many organic sol- vents; explodes on grinding.

Uses

In the explosives industry.

Uses

Silver perchlorate is used as a catalyst in organic chemistry. It is an effective reagent for replacing halides ligands with perchlorate. It is also used in the manufacturing of explosives.

Purification Methods

Reflux it with *benzene (6mL/g) in a flask fitted with a Dean and Stark trap until all the water is removed azeotropically (ca 4hours). The solution is cooled and diluted with dry pentane (4mL/g of AgClO4). The precipitated AgClO4 is filtered off and dried in a desiccator over P2O5 at 1mm for 24hours [Radell et al. J Am Chem Soc 83 3958 1961]. It has also been recrystallised from perchloric acid. [Caution due to its EXPLOSIVE nature in the presence of organic matter.] Store it in the dark.

SILVER PERCHLORATE Preparation Products And Raw materials

Raw materials

Silver chloride

Preparation Products

polypyrrole synthesized by electrolytic polymerization

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SILVER PERCHLORATE Suppliers

China 48 Germany 2 India 3 Japan 4 Switzerland 1 United Kingdom 1 United States 18 Global 77

HBCChem, Inc.

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Redox Scientific

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D.F. Goldsmith Chemical & Metal Corporation (DFG)

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Strem Chemicals, Inc.

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Combi-Blocks Inc.

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GFS Chemicals Inc

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Riedel-de Haen AG

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HBCChem Inc.

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Alfa Aesar

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HONEST JOY HOLDINGS LIMITED

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City Chemical LLC

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D.F. Goldsmith Chemical & Metal Corp.

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MP Biomedicals, Inc.

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Aithaca Chemical Corp.

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City Chemicals Corporation

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Pfaltz & Bauer, Inc.

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GFS Chemicals

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7783-93-9, SILVER PERCHLORATERelated Search:

Silver chloride Silver fluoride Silver sulfate SILVER BROMIDE SILVER CHLORATE hypochlorous acid CHLORIC ACID Chlorite-group minerals Silver Chlorine dioxide PERCHLORIC ACID Sodium chlorate SILVER PERCHLORATE HYDRATE SILVER PERCHLORATE Ag(I){9,10-bisdiphenylphosphinoethylanthracene} ClO4 Ag2(ClO4)2[2,6-bis(N-benzylamino)-3,5-bis(N-diphosphino)pyridine]2 [Ag(I){9,10-bisdiphenylphosphinomethyl(N-propaminomethyl)anthracene}ClO4]2 Anthraceno-Diphosphine-Silver(I) Complex

SILVER (I) PERCHLORATE

SILVER PERCHLORATE

Perchloricacid,silver(1+)salt

perchloricacid,silver(1++)salt

SILVER PERCHLORATE, ANHYDROUS, 97%

SILVER PERCHLORATE 99.9%

Silver(I)perchlorate,anhydrous

SILVER PERCHLORATE, ANHYDROUS REAGENT

Silverperchlorate,anhydrous,min.97%

SILVER(I) PERCHLORATE, ANHYDROUS, REAGENT: (SILBERGEHALT: 48%)

SilverIperchlorateanhydrousreagentSilbergehalt

Silver perchlorate, anhydrous, min. 97%

Hyperchloric acid silver(I) salt

Silver(I) perchlorate, anhydrous, reagent

SILVER PERCHLORATE, ANHYDROUS, REAGENTSILVER PERCHLORATE, ANHYDROUS, REAGENTSILVER PERCHLORATE, ANHYDROUS, REAGENT

7783-93-9

Synthetic Reagents

Perchlorates

Oxidation

Catalysis and Inorganic Chemistry

Gold Catalysis

Silver AdditivesMetal and Ceramic Science

Silver Salts

Salts

metal perchlorate salt