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(3S,4S)-1-Benzylpyrrolidine-3,4-diol

Product Name
(3S,4S)-1-Benzylpyrrolidine-3,4-diol
CAS No.
90365-74-5
Chemical Name
(3S,4S)-1-Benzylpyrrolidine-3,4-diol
Synonyms
(3S;EOS-62152;(3S,4S)-Benzylpyrrolidine-3,4-diol;(3S,4S)-1-BENZYL-PYRROLIDINE-3,4-DIOL;(3S,4S)-(+)-1-BENZYL-3,4-PYRROLIDINDIOL;(3S,4S)-(+)-1-BENZYL-3,4-PYRROLIDINEDIOL;(3S,4S)-1-benzyl-3,4-dihydroxy-pyrrolidine;(3S,4S)-(+)-1-Benzyl-3,4-pyrrolidindiol 97%;(3S,4S)-(+)-1-Benzyl-3,4-pyrrolidindiol,97%;(3S,4S)-1-(phenylMethyl)-3,4-Pyrrolidinediol
CBNumber
CB2187071
Molecular Formula
C11H15NO2
Formula Weight
193.24
MOL File
90365-74-5.mol
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(3S,4S)-1-Benzylpyrrolidine-3,4-diol Property

Melting point:
94-100 °C
alpha 
33.6 º (c=1.05% in methanol)
Boiling point:
329.46°C (rough estimate)
Density 
1.0945 (rough estimate)
refractive index 
1.5041 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Powder, Crystals, and/or Chunks
pka
13.99±0.40(Predicted)
color 
Off-white to yellow to light brown
optical activity
[α]20/D +33.6±3°, c = 1.05% in methanol
BRN 
4992458
InChIKey
QJRIUWQPJVPYSO-QWRGUYRKSA-N
CAS DataBase Reference
90365-74-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
F 
10-34
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
52057
Product name
(3S,4S)-(+)-1-Benzyl-3,4-pyrrolidinediol
Purity
≥97.0% (sum of enantiomers, HPLC)
Packaging
500mg
Price
$283
Updated
2023/01/07
Usbiological
Product number
268020
Product name
[3S-
Packaging
1mg
Price
$569
Updated
2021/12/16
Apolloscientific
Product number
OR322413
Product name
(3S,4S)-(+)-1-Benzyl-3,4-pyrrolidindiol
Purity
97%
Packaging
25g
Price
$696
Updated
2021/12/16
Matrix Scientific
Product number
074463
Product name
(3S,4S)-(+)-1-Benzyl-3,4-pyrrolidindiol
Purity
95+%
Packaging
5g
Price
$825
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0004639
Product name
(3S,4S)-(+)-1-BENZYL-3,4-PYRROLIDINDIOL
Purity
95.00%
Packaging
1G
Price
$984.06
Updated
2021/12/16
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(3S,4S)-1-Benzylpyrrolidine-3,4-diol Chemical Properties,Usage,Production

Chemical Properties

off-white to light brown powder or needles

Uses

(3S,4S)-(+)-1-Benzyl-3,4-pyrrolidinediol can be used:

  • As a building block for the preparation of novel chiral crown ethers.
  • As an intermediate in the synthesis of (3R,4R)1-benzyl-4-fluoropyrrolidin-3- amine.
  • As an intermediate in the preparation of 3-hydroxy-4-pyrrolidinyl analogs of nucleobases.

(3S,4S)-1-Benzylpyrrolidine-3,4-diol Preparation Products And Raw materials

Raw materials

Preparation Products

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(3S,4S)-1-Benzylpyrrolidine-3,4-diol Suppliers

Belgium 1 China 107 Europe 1 Germany 2 India 2 Italy 1 Japan 1 Switzerland 1 United Kingdom 3 United States 19 Global 138
Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
MOLEKULA Ltd.
Tel
--
Fax
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Email
kevinbanks@molekula.com
Country
United Kingdom
ProdList
6140
Advantage
66

90365-74-5, (3S,4S)-1-Benzylpyrrolidine-3,4-diolRelated Search:

Povidone iodine Benzoyl peroxide Benzyl alcohol Benzyl acetate Benzyl chloride Pyrrolidine Benzyl benzoate Polyvinylpyrrolidone N-Methyl-2-pyrrolidone N-Vinyl-2-pyrrolidone 1-BENZYLPYRROLE Benzyl METHYL-2-PYRROLIDONE (3S,4S)-1-Benzylpyrrolidine-3,4-diol

  • (3S,4S)-(+)-1-Benzyl-3,4-pyrrolidindiol,97%
  • (3S,4S)-1-(phenylMethyl)-3,4-Pyrrolidinediol
  • (3S,4S)-1-benzyl-3,4-dihydroxy-pyrrolidine
  • (3S,4S)-1-BENZYL-PYRROLIDINE-3,4-DIOL
  • (3S,4S)-(+)-1-BENZYL-3,4-PYRROLIDINDIOL
  • (3S,4S)-(+)-1-BENZYL-3,4-PYRROLIDINEDIOL
  • (3S
  • (3S,4S)-(+)-1-Benzyl-3,4-pyrrolidindiol, GC 97%
  • (3S,4S)-1-(Phenylmethyl)-3,4-pyrrolidinediol,99%e.e.
  • EOS-62152
  • (3S,4S)-(+)-1-Benzyl-3,4-pyrrolidindiol 97%
  • (3S,4S)-Benzylpyrrolidine-3,4-diol
  • 3,4-Pyrrolidinediol, 1-(phenylmethyl)-, (3S,4S)-
  • 90365-74-5
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